玻璃纸生产废气中CS2和H2S的治理

阐述了玻璃纸生产中CS2和H2S废气产生的原理,介绍了该废气处理的现状,总结了目前普遍采用的冷凝法、活性炭吸附法、活性碳纤维吸附法、改性活性炭吸附法、螯合铁氧化法、吸收-吸附法等处理方法的特点和效果。介绍了一种先采用螯合铁氧化法、再采用冷凝法、最后采用活性炭吸附法的综合处理工艺,可使废气达标排放。     

Low‐concentration hydrogen peroxide decontamination for Bacillus spore contamination in buildings

Remediation and recovery efforts after a release of Bacillus anthracis (anthrax) spores may be difficult and costly. In addition, response and recovery technologies may be focused on critical resources, leaving the small business or homeowner without remediation options. This study evaluates the efficacy of relatively low levels of hydrogen peroxide vapor (HPV) delivered from off‐the‐shelf equipment for the inactivation of Bacillus spores within an indoor environment. Decontamination evaluations were conducted in a house using both Bacillus atrophaeus var. globigii (Bg; as surrogates for B. anthracis) inoculated on the carpet and galvanized metal as coupons and Geobacillus stearothermophilus (Gs) as biological indicators on steel. The total decontamination time ranged from 4 to 7 days. Using the longer exposure times, low concentrations of HPV (average levels below 20 parts per million) effectively inactivated Bg and Gs spores on the materials tested. The HPV was generated with commercial humidifiers and household‐strength hydrogen peroxide solutions. The presence of home furnishings did not have a significant impact on HPV efficacy. This simple, inexpensive, and effective decontamination method could have significant utility for remediation following a B. anthracis spore release, such as following a terrorist attack.     

用生物滴滤床处理H2S和挥发性有机物混合废气

用生物滴滤床（BTF）处理某化工厂污水站的H2S和挥发性有机物（VOCs）混合废气,当废气中H2S质量浓度为120～400mg／m^3、VOCs质量浓度为115～340mg／m^时,运行稳定后H2S和VOCs的去除率为95％和85％。考察了影响BTF运行的循环水水质情况,试验结果表明：加入Na2CO3可使循环水pH控制在3～6;循环水中含盐量、Cl^-质量浓度和SO4^2-质量浓度分别为2200～3300,600～800,1200～1400mg／L,均未达到抑制微生物的水平。     

不同小叶章湿地H2S和COS的排放通量研究

利用静态箱/气相色谱法,观测了小叶章沼泽化草甸和小叶章典型草甸两种湿地类型中H2S和COS在生长季(5-9月)的释放动态,结果表明:在两种小叶章湿地中,H2S和COS的排放通量均具有明显的季节和日变化规律.在小叶章沼泽化草甸中H2S和COS的平均释放通量分别为0.34μg·m-2·h-1和-0.29μg·m-2·h-1;小叶章典型草甸H2S和COS的平均释放通量分别为0.14μg·m-2·h-1和-0.20μg·m-2·h-1;小叶章沼泽化草甸H2S和COS的平均释放通量均高于小叶章典型草甸.在生长季两种小叶章湿地均能向大气释放H2S,对COS则表现为从大气中吸收.小叶章的生长过程对H2S和COS的排放影响显著,在小叶章生长旺盛期,H2S出现排放峰值,COS出现吸收高峰.     

铂载钴钼二元硫化物对H_2S电催化活性研究

为考察溶胶凝胶法制备的Co-Mo二元硫化物对H_2S气体的电催化活性,通过循环伏安法和Tafel曲线分析对铂载不同Co、Mo掺杂比的电催化剂进行表征.结果表明,不同阳极电催化剂交换电流密度J_0由大到小依次为,铂载n(Co):n(Mo)=2:3、铂载n(Co):n(Mo)=2:1、铂载n(Co):n(Mo)=1:1和铂,即铂载n(Co):n(Mo)=2:3阳极电催化剂具有较好的活性,这与循环伏安曲线测试结果一致.电解质溶液pH值为6～7时,随着温度的升高铂载n(co):n(Mo)=2:3阳极电催化剂活性呈现上升的趋势.优化后的Co、Mo掺杂原子比约为0.66,此类电催化剂在操作温度80℃下,交换电流密度为1.318mA/cm~2,表观活化焙值为616.6 kJ/mol .研究表明,铂载钴钼二元硫化物适合作为低温H_2S燃料电池阳极电催化剂,其中Co、Mo掺杂比对电催化活性影响较大.     

N掺杂TiO_2光催化剂的制备及其H_2O_2改性的研究

以钛酸四丁酯为前驱物,采用水解沉淀法制备了N掺杂TiO_2光催化剂和H_2O_2改性的N掺杂TiO_2光催化剂.实验表明,H_2O_2改性的N掺杂TiO_2光催化剂的最佳制备条件为:氨水(质量分数28%)加入量20 mL,焙烧温度500 ℃,H_2O_2(质量分数30%)加入量2.0 mL.日光下,N掺杂TiO_2光催化剂及H_2O_2改性的N掺杂TiO_2光催化剂在反应90 min时的活性红紫去除率达99%,它们对活性红紫的去除率远高于P_(25)TiO_2光催化剂.H_2O_2改性的N掺杂TiO_2光催化剂中N质量分数比改性前明显提高,制备的两种催化剂中不仅含有N元素,同时还含有C和H元素.     

Seasonal Differences in the Levels of Gaseous Air Pollutants in the Vicinity of a Waste Dump

Hydrogen sulphide, ammonia, nitrogen dioxide, mercaptans and sulphur dioxide (H₂S, NH₃, NO₂, R-SH, SO₂) concentrations were measured at the location in the vicinity of the waste dump to determine the air pollution level of these pollutants prior to the operation of the Mobile Thermal Treatment Plant. Samples were collected over one year period. Seasonal differences, and the influence of meteorological parameters (temperature, relative humidity, pressure and wind direction) on the air pollution levels were studied. Results show relatively low concentrations of H₂S, NO₂, R-SH and SO₂, while NH₃ levels were higher compared to the guideline values. Good weather conditions (high air pressure and low relative humidity) are connected to long range transport of NO₂, while higher temperatures result in elevated NH₃ and R-SH concentrations. Because of the predominant northeast wind direction (the same as the waste dump direction), the contribution of air pollution from the direction of the waste dump at the measuring site is significant, but that does not necessarily mean that the pollutants originated from that source.     

微波强化CWPO工艺CuO_x-CeO_2/GAC催化剂的制备及其对二甲亚砜的降解

以颗粒活性炭(GAC)为载体、铜为活性组分、铈为助剂组分、草酸钠为沉淀剂,采用浸渍焙烧法制得CuO_x-CeO_2/GAC催化剂。以H_2O_2为氧化剂,微波强化催化湿式过氧化氢氧化(CWPO)处理二甲亚砜(DMSO)初始质量浓度为1 000 mg/L的废水,处理3 min后DMSO去除率达93.8%。催化剂第7次使用时DMSO去除率仍保持在75%以上。初始废水pH在3~9范围内,DMSO去除率均在85%以上。助剂Ce的加入提高了催化剂表面活性组分的分散性和稳定性,使催化剂的活性稳定性和使用寿命显著提高。     

Techno-economic and environmental analysis of an integrated standalone hybrid solar hydrogen system to supply CCHP loads of a greenhouse in Iran

The techno-economic and environmental performance of hybrid solar hydrogen energy systems was investigated to provide combined cooling, heating and power (CCHP) demands of a standalone greenhouse in Iran to achieve sustainable agriculture based on an optimization procedure. From the environmental point of view, by deploying hybrid energy systems, 83%, to 100% of emissions can be avoided. Also a sensitivity analysis was performed on the hybrid energy systems in order to study the effect of major parameter variation on the systems justification. It was concluded that hybrid solar systems are economically competitive with conventional systems, for high solar intensity locations with high diesel fuel prices and decreased prices for PV and hydrogen storage technology.     

O3-H2O2氧化法处理印染废水

采用O₃-H₂O₂氧化法对印染废水进行氧化处理,比较了O₃氧化法和O₃-H₂O₂氧化法对印染废水的处理效果,考察了初始废水pH、H₂O₂加入量、O₃流量和反应时间对废水的色度去除率和COD去除率的影响。实验结果表明：O₃-H₂O₂氧化法对废水的COD和色度的去除效果比O₃氧化法更好;在初始废水pH为11、H₂O₂加入量为13mmol/L、O₃流量为6g/h、反应时间为60min的最佳工艺条件下,处理后废水COD为61.50mg/L,COD去除率为95.73%,废水色度为5倍,色度去除率为99.75%,TOC为37.84mg/L,TOC去除率为85.10%,BOD₅为22.76mg/L,BOD₅去除率为90.20%,BOD₅/COD为0.37。