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新疆喀什地区高铁锰地下水严重影响当地供水水质安全及居民身体健康.基于数据收集及水文地质调查基础上,利用171组地下水水样测试数据,借助统计学方法和PHREEQC软件反演对喀什地区地下水铁锰水文地球化学进行研究.结果表明,研究区地下水Fe超标率为39.8%,垂向为深层承压水>浅层承压水>潜水;Mn超标率为60.8%,垂向为浅层承压水>潜水>深层承压水,Mn含量的超标率普遍高于Fe含量的超标率,且分布范围更广,更普遍;高铁锰地下水主要富集于SO4·Cl-Na·Ca·Mg型水、SO4·Cl-Na·Mg型水和SO4·Cl-Na·Ca型水中,高矿化度地下水和蒸发浓缩作用有利于铁锰富集,潜水Fe含量受人为因素影响较大;研究区地下水Fe主要为Fe (Ⅱ),Mn均为Mn (Ⅱ);研究区地下水中铁的来源主要为原生地层中褐铁矿,部分为菱铁矿和其他含铁矿物,锰的来源主要为黑锰矿、软锰矿和部分菱锰矿等含锰矿物;潜水中As参与Fe的阳离子交换作用生成Fe (Ⅱ),承压含水层Mn在高矿化度地下水中持续发生阳离子交换作用,随着含水层深度加大,研究区地下水中的黑锰矿、褐铁矿和软锰矿溶解始终未达到饱和,持续溶解. 相似文献
364.
A polyaluminum containing a high concentration of Al13 polymer and active chlorine (PACC) was successfully synthesized by a new electrochemical reactor using Ti/RuO2-TiO2 anodes. PACC can potentially be used as a dual-function chemical reagent for water treatment. The obtained results indicated that the formation of Al13 polymer and active chlorine, were the most active components in PACC responsible for coagulation and disinfection respectively. These components were significantly influenced by electrolyte temperature, current density, and stirring rate. It was observed that high electrolyte temperature favored the formation of Al13. Increasing current density and stirring rate resulted in high current efficiency of chlorine evolution, thus favoring the generation of Al13 and active chlorine in PACC. When the PACC (AlT = 0.5 mol/L, basicity = 2.3) was prepared at the optimum conditions by electrolysis process, the Al13 polymer and active chlorine in product reached above 70% of AlT and 4000 mg/L, respectively. In the pilot scale experiment with raw polyaluminum chloride used as an electrolyte, PACC was successfully prepared and produced a high content of Al13 and active chlorine products. The pilot scale experiment demonstrated a potential industrial approach of PACC preparation. 相似文献
365.
Arsenic(As) and antimony(Sb) are usually coexistent in mine wastes and pose a great threat to human health. The As immobilization by nano zero-valent iron(n ZVI) is promising, however, the stabilization for co-occurring As and Sb is not known. Herein, the immobilization and transformation of As and Sb in n ZVI-treated sediments were evaluated using complementary leaching experiments and characterization techniques. Raw sediment samples from a gold-antimony deposit revealed the co-existence of ul... 相似文献
366.
海底铁锰氧化还原过程的模拟研究 总被引:5,自引:0,他引:5
本文用室内海水-沉积物平衡箱研究了沉积物间隙水中铁、锰的垂直变化分布和随时间变化的分布,Fe~(2+)随深度、时间的变化幅度大,在六个月的实验期内均是如此,而Mn~(2+)在放置三个月后即趋于稳定;Fe~(2+),Mn~(2+)产生的宏观经验动力学表明:Fe~(2+)受pH影响远比Mn~(2+)大,且随着深度的增加更为明显,Fe~(2+)在较下层产生速率大,而Mn~(2+)反之;Fe~(2+)的扩散转移是上覆海水向沉积物中转移,扩散量为-60.7ug/m~2d,Nn~(2+)转移方向相反,扩散量为1746.2ug/m~2.d。 相似文献
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368.
铁炭内电解-厌氧-好氧工艺处理阿维菌素废水的试验研究 总被引:1,自引:0,他引:1
血清瓶毒性试验表明 ,AVM对厌氧消化产生强烈的抑制作用。AVM废水经铁炭内电解预处理后 ,COD和AVM的去除率分别达到 19.5 %和 6 8.5 % ,可大大降低废水的毒性。预处理出水再经UASB +生物接触氧化反应器进一步处理 ,当生化系统进水COD为 6 0 0 0— 6 5 0 0mg/L时 ,出水COD为 2 5 0— 2 80mg/L ,总COD去除率达到 95 .6 % ,出水达到生物制药行业排放标准 相似文献
369.
铁阳极电凝聚处理活性黑KN-B染料废水 总被引:1,自引:0,他引:1
对铁阳极电凝聚处理活性黑KN-B染料废水过程进行了实验研究.考察了电流密度、染料溶液初始pH值、电介质浓度及种类、温度、染料浓度等因素对脱色效率的影响.结果表明,在一定实验条件下,活性黑KN-B模拟废水的脱色效率达93%;电流强度、染料浓度、电解液初始pH值及电解质的种类对染料溶液脱色效率影响显著,电解液温度、电解质的浓度对脱色效率的影响不明显;以铁为阳极的原位电凝聚处理活性黑KN-B模拟废水混凝过程中主要作用机理以吸附电性中和为主;电凝聚过程中活性黑KN-B在阴极上发生了还原反应. 相似文献
370.
Polybrominated diphenyl ethers (PBDEs) are recognized as a new class of widely-distributed and persistent contaminants for which effective treatment and remediation technologies are needed. In this study, two kinds of commercially available nanoscale Fe0 slurries (Nanofer N25 and N25S), a freeze-dried laboratory-synthesized Fe0 nanoparticle (nZVI), and their palladized forms were used to investigate the effect of particle properties and catalyst on PBDE debromination kinetics and pathways. Nanofers and their palladized forms were found to debrominate PBDEs effectively. The laboratory-synthesized Fe0 nanoparticles also debrominated PBDEs, but were slower due to deactivation by the freeze-drying and stabilization processes in the laboratory synthesis. An organic modifier, polyacrylic acid (PAA), bound on N25S slowed PBDE debromination by a factor of three to four compared to N25. The activity of palladized nZVI (nZVI/Pd) was optimized at 0.3 Pd/Fe wt% in our system. N25 could debrominate selected environmentally-abundant PBDEs, including BDE 209, 183, 153, 99, and 47, to end products di-BDEs, mono-BDEs and diphenyl ether (DE) in one week, while nZVI/Pd (0.3 Pd/Fe wt%) mainly resulted in DE as a final product. Step-wise major PBDE debromination pathways by unamended and palladized Fe0 are described and compared. Surface precursor complex formation is an important limiting factor for palladized Fe0 reduction as demonstrated by PBDE pathways where steric hindrance and rapid sequential debromination of adjacent bromines play an important role. 相似文献