便携式GC-MS仪快速测定水中硝基苯及其在应急监测中的应用

采用便携式GC-MS仪快速测定水中硝基苯,通过优化水中离子强度和顶空加热时间,使方法在0μg/L^300μg/L范围内线性良好,方法检出限为2.5μg/L。标准溶液6次测定结果的RSD为7.8%~10.9%,实际水样的加标回收率为80.7%~103%。同步测定试验表明,硝基苯与7种苯系物分离良好。与国标方法对比,该方法单个样品测定时间由2 h缩短为15 min。将该方法用于应急监测工作中,及时有效的数据可为污水处理及事故调查提供分析和研判依据。     

基于BP神经网络的受限空间火灾联合探测方法

针对航空受限空间火灾探测高误报的问题,在现有技术成果基础上对多种火灾探测方式进行研讨,并提出1种基于BP神经网络技术的飞机机身内部受限空间火灾联合探测报警方法。该方法结合现有烟雾感应、气体传感器探测等常用火灾探测技术,以红外热成像探测为辅助手段,采用神经网络实现数据融合,对模拟实验舱火灾烟雾进行联合探测,在单一火灾探测方式基础上提高了探测准确率。     

Motorcycle crashes potentially preventable by three crash avoidance technologies on passenger vehicles

Objective: The objective of this study was to identify and quantify the motorcycle crash population that would be potential beneficiaries of 3 crash avoidance technologies recently available on passenger vehicles.

Methods: Two-vehicle crashes between a motorcycle and a passenger vehicle that occurred in the United States during 2011–2015 were classified by type, with consideration of the functionality of 3 classes of passenger vehicle crash avoidance technologies: frontal crash prevention, lane maintenance, and blind spot detection. Results were expressed as the percentage of crashes potentially preventable by each type of technology, based on all known types of 2-vehicle crashes and based on all crashes involving motorcycles.

Results: Frontal crash prevention had the largest potential to prevent 2-vehicle motorcycle crashes with passenger vehicles. The 3 technologies in sum had the potential to prevent 10% of fatal 2-vehicle crashes and 23% of police-reported crashes. However, because 2-vehicle crashes with a passenger vehicle represent fewer than half of all motorcycle crashes, these technologies represent a potential to avoid 4% of all fatal motorcycle crashes and 10% of all police-reported motorcycle crashes.

Discussion: Refining the ability of passenger vehicle crash avoidance systems to detect motorcycles represents an opportunity to improve motorcycle safety. Expanding the capabilities of these technologies represents an even greater opportunity. However, even fully realizing these opportunities can affect only a minority of motorcycle crashes and does not change the need for other motorcycle safety countermeasures such as helmets, universal helmet laws, and antilock braking systems.     

A Monte Carlo study of radon detection in cylindrical diffusion chambers

The functioning of radon diffusion chambers was studied using the Monte Carlo code RAMMX developed here. The alpha particles from radon are assumed randomly produced in the volume of the cylinder, and those from the progeny are assumed to originate randomly at the cylindrical surface. The energy spectrum, the distribution of incident angles, and the distribution of path lengths of the alpha particles on the detector were obtained. These quantities vary depending on input parameters such as initial alpha particle energy, radius and depth of the diffusion chamber, detector size and atmospheric pressure. The calculated energy spectrum for both ²²²Rn and ²²⁰Rn was compared with experiment, permitting the identification of each peak and its origin, and a better understanding of radon monitoring. Three aspects not considered in previous calculations are progeny alphas coming from surfaces of the monitor, taking into account the atmospheric pressure, and including the isotope ²²⁰Rn.     

原子吸收法直接测量土壤中的汞含量

实验采用DMA-80自动测汞仪直接测定土壤中的汞含量,详细介绍了土壤样品中汞分析条件的选择,方法在0．4—400ng范围内,线性良好,其检出限为0．2ug／kg。     

Evaluation and validation of two different chromatographic methods (HPLC and LC-MS/MS) for the determination and confirmation of ochratoxin A in pig tissues

This study was undertaken to compare two different analytical methods for the determination and confirmation of ochratoxin A (OTA) in blood serum, kidney and liver of pigs. Sample clean-up was based on liquid-liquid phase extraction. The detection of OTA was accomplished with high-performance liquid chromatography (HPLC) combined either with fluorescence detection (FL) or electro spray ionization (ESI+) tandem mass spectrometry (MS–MS). Comparative method evaluation was based on the investigation of 90 samples of blood serum, kidney and liver per animal originating from different regions of Serbia. The analytical results are discussed in view of the respective method validation data and the corresponding experimental protocols. In general, analytical data obtained with (LC–MS–MS) liquid chromatography electro spray tandem mass spectro metry detection offered comparable good results at the sub-ppb concentration level. The results indicate that the liquid chromatography electro spray tandem mass spectrometric (LC-MS/MS) method was more specific and sensitive for the analysis and confirmation of ochratoxin A in pig tissues then high pressure liquid chromatography (HPLC) method after methylation of OTA.     

超高效液相色谱法测定生活饮用水中的溴氰菊酯

采用反相超高效液相色谱法测定生活饮用水中的溴氰菊酯,并用于实际样品的分析.该方法用二氯甲烷为萃取剂,以甲醇—水（85 /15,V/V）作为流动相,紫外检测器的检测波长为215 nm.该方法在6 min之内可完成生活饮用水中溴氰菊酯的分离及检测,结果表明,该方法线性范围、精密度、加标回收率均符合相关技术要求,适用于水样中溴氰菊酯的测定.     

乌鲁木齐市电磁辐射污染的调查及分析

报道了乌鲁木剂市电磁辐射污染的调查结果,阐明了乌鲁木齐市电磁污染的现状和分析状况,并依据调查结果对各类污染源的电磁泄漏进行了分析讨论。     

基于PSO-SVM算法的环境监测数据异常检测和缺失补全

针对环境监测数据异常和数据缺失问题,提出了基于支持向量机的粒子群优化数据异常检测和缺失补全算法。利用粒子群优化算法选取较优的支持向量机训练参数组合,以此建立非线性的支持向量机模型,并利用结果模型对测得的真实数据拟合预测。以宁夏回族自治区某污水处理厂的污染物测量数据作为实验数据,结果表明,利用该算法预测数据的准确率可达97.977%,检测异常数据准确度高,缺失数据补全正确。     

CONFLICTING PERSPECTWES ABOUT DETECTION LIMITS AND ABOUT THE CENSORING OF ENVIRONMENTAL DATA1

ABSTRACT: Current conventions for reporting analytical results from environmental samples brings the objectives of laboratory scientists into conflict with those of environmental scientists. The objective of chemical analyses is to provide estimates of the true composition of samples. Reported results must reflect the analytical uncertainty. Current conventions require left-censoring of those results below the Limit of Detection. The objective of statistical interpretation of environmental data is to provide estimates of the characteristics of ecosystems. Such statistical analyses are often confounded by left-censoring of analytical results. We review the different points of view and propose a compromise which recognizes these conflicting perspectives.