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991.
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993.
Hydrogen (H2) explosion effects recently examined, are confirming the devastating loss scenarios to humans, environment, assets, and associated business interruption. H2 production is a core process in refineries used in further process steps. Steam reforming of natural gas or a mix with naphtha or LPG is a common hydrogen production technique, where the latest technologies have adopted enhanced metallurgies to minimize explosion risk and the associated maintenance cost following plant degradation owing to corrosion effects. However, corrosion rates are still high in specific areas of piping and process equipment. The aim of this paper is to present a methodology based on semi-quantitative RBI modeling according to regulations by API and recent EN standards, adopting a family of linear regression forecasting models that depict the yearly corrosion rate (per corrosion loop) of a hydrogen production steam reforming unit; this is done under different operating conditions (e.g., temperature, pressure, and fluid speed), metallurgy and other related physicochemical variables. The model is based on the examination of both ultrasonic wall thinning measurements and the examination of quantitative crosslinking total corrosion effects along with the physicochemical properties prevailing in different plant corrosion loops. The outcome of the regression analysis is an expansive family of multivariable equations describing, with a defined accuracy, the yearly corrosion rate and associated lifespan forecast per corrosion loop, and per examined part. These equations were further utilized in a custom-made database that can be used as an additional loss prevention tool by the hydrogen production unit management team. Evaluation results regarding the tool efficiency are presented in the following of this paper. 相似文献
994.
Accidental releases of hazardous gases in chemical industries can pose great threats to public security. The computational fluid dynamics (CFD) model is commonly applied to predict gas dispersion in complex structured areas. It can provide good accuracy but it is too time-consuming to be used in emergency response. To reduce computation time while keep acceptable accuracy, this paper proposes several fused CFD-interpolation models which combine CFD model with different interpolation methods. Spline, linear and nearest interpolation methods are used. A CFD simulations database is created ahead of time which can be quickly recalled for emergency usage and unknown situations can be predicted instantly by interpolation methods instead of time-consuming CFD model. Fused models were applied to a case study involving a hypothetical propane release with varying conditions and validated against CFD model. The validation shows that prediction accuracy of these fusion models is acceptable. Among these models, CFD-Spline interpolation model performs best. It is faster than CFD model by a factor of 75 and is potentially a good method to be applied to real-time prediction. 相似文献
995.
Corrosion in seawater is simultaneously influenced by multiple environmental factors including dissolved oxygen (DO), temperature, salinity, pH, and so on. These factors vary along with time and are different in different locations. The spatial-temporal variation of the actual marine environment cannot be ignored in corrosion prediction models. This paper proposes a new method for corrosion prediction in the actual time-varying marine environment which includes the design of experiments, calibration of acceleration models, and the modeling of marine environment. Acceleration models capture the effects of environmental factors and acts as the link between the environment and the corrosion process. The marine environment is described with the Kriging spatial-temporal model. Then the proposed method is used to give corrosion predictions for metals in different locations and vessels travel in different waters. This method could be helpful for corrosion resistance evaluation and environment corrosivity assessment. 相似文献
996.
为研究分支管道位置对丙烷爆炸火焰传播的影响规律,通过多组数值模拟与已有实验数据对比,分析不同工况下三通管内火焰传播形态变化特征及温度变化。结果表明:向右传播的爆炸气流在支管左侧形成湍流旋涡,火焰受到拖拽及壁面制约,贴支管右侧壁面呈尖刀状传播;封闭管道中,火焰传播受主管道高速前驱压力波回波影响更显著,垂直支管中火焰与高温风险更大;实验支管位置距离点火源5.6 m时岔口处监测点温度高达2 214.08 K,支管位置增加至5.71 m时,支管处湍流旋涡拖拽火焰,使火焰出现中断,支管移至5.825 m后高温火焰无法传播至支管口,支管中的爆炸风险显著降低。研究结果为工业生产三通管支管位置的选择和支管内二次爆炸风险预测提供科学参考。 相似文献
997.
Preparedness of emergency evacuation for the leakage of toxic substances in chemical plants is very important in order to reduce damage. In order to implement an emergency evacuation properly, it is necessary to comprehensively and concretely determine the conditions of the leakage and atmospheric conditions and predict the consequences of the dispersed gases. Repeated training for emergencies is also essential. In order to realize effective evacuation, a prediction model of the evacuation area that anyone can use to obtain the same results both accurately and promptly is developed in the present study. The prediction model is designed such that the wind speed and atmospheric conditions are automatically set, and the leakage rate is the only input parameter, so that anyone can use the model easily. In addition, the model can also predict the atmospheric parameters for up to 3 h and can calculate the evacuation distance so that smooth evacuation can be achieved for changing atmospheric conditions. Finally, the evacuation area is defined by statistically analysed wind fluctuations, and a series of emergency evacuation measures is implemented. 相似文献
998.
腔室火流动特性是影响腔室火灾蔓延与通风状况的重要因素。通过一系列小尺度腔室火实验,研究了火源位置变化对腔室火流动特性的影响。实验结果表明,随着火源沿腔室底部从壁面向开口方向移动,在开口中性面以上,同一高度处压差与流速增大,中性面高度和烟气层高度均降低,并导致开口质量流率增大。与火源强度相比,火源位置变化对烟气层高度的影响更为显著。火源位置对中性面高度及烟气层高度的影响在壁面处及开口处更为显著,腔室中部位置变化的影响相对较小。火源由壁面向开口移动,会造成火焰高度降低和水平伸长量增加。基于实验数据,给出了考虑耦合火源位置的腔室内火焰水平伸长量的表达式。研究结果可为相关场景下的腔室火灾理论模型提供实验结果支撑。 相似文献
999.
为更科学规划消防站选址,实现有限资源下应急资源的合理配置,提高消防站联动效率,根据“不同火灾风险等级的需求点应得到主管消防站和不同数量增援消防站服务”的原则,提出1种消防站分级覆盖选址模型,同时使用覆盖衰减函数表示消防站对需求点的覆盖度;基于遗传算法设计消防站分级覆盖选址模型的求解流程;以济南市区为例,基于POI和火灾数据,使用核密度分析法进行城市火灾风险分级,进而对选址模型进行验证。结果表明:以覆盖火灾风险值为评价指标,分级覆盖选址模型的选址结果优于现状消防站、广义最大覆盖模型、P-中位模型和P-中心模型。 相似文献
1000.
Feng Wang 《中国人口.资源与环境(英文版)》2018,16(1):49-58
In order to make further steps in dealing with climate change, China proposed to peak carbon dioxide emissions by about 2030 and to make best efforts for the peaking early. The carbon emission peak target (CEPT) must result in a forcing mechanism on China’s economic transition. This paper, by following the logical order from “research on carbon emission history” to “carbon emission trend prediction,” from “research on paths of realizing peak” to “peak restraint research,” provides a general review of current status and development trend of researches on China’s carbon emission and its peak value. Furthermore, this paper also reviews the basic theories and specific cases of the forcing mechanism. Based on the existing achievements and development trends in this field, the following research directions that can be further expanded are put forward. First, from the perspective of long-term strategy of sustainable development, we should analyze and construct the forcing mechanism of CEPT in a reverse thinking way. Second, economic transition paths under the forcing mechanism should be systematically studied. Third, by constructing a large-scale policy evaluation model, the emission reduction performance and economic impact of a series of policy measures adopted during the transition process should be quantitatively evaluated. 相似文献