水性膨胀型防火涂料的现状和应用

钢结构是现代建筑工程中较普遍的结构形式之一,具备重量轻、机械性能好、可承受较大的荷载及制作和安装机械化程度高的特点。随着城市规模的发展,钢结构在我国建筑业具有非常广阔的应用前景。但由于其自身抗火能力差,在火灾高温作用下,其力学性能如屈服强度、弹性模量等会随温度升高而降低,一般在15min左右即丧失承重能力而垮塌,需采取保护措施使其温度不超过临界点才能在火灾中保持稳定性。涂敷钢结构防火涂料,施工简单、重量轻、耐火时间长且不受钢结构几何形状的制约,具有良好的经济性和实用性。随着环保意识的增强,国内外越来越多的建筑提倡绿色环保理念,参与三星或LEED认证体系的评级认证。水性膨胀型防火涂料凭借其优异的环保、施工安全和防火性能,开始逐渐受到众多业主和设计师的青睐。本文从防火原理、技术特点、防火领域的国内外认证、施工和质量管理的角度,浅谈水性膨胀型防火涂料的性能和发展现状,同时也讨论了目前防火涂料存在的一些问题。     

Technologically enhanced 210Pb and 210Po in iron and steel industry

Iron and steel manufacture has been ranked as the largest industrial source of environmental contamination in the USA; the wastes generated in their production processes contain heavy elements that can be a source of contamination, and natural radionuclides that can produce an occupational and/or public radiological impact. In this work the potential occupational effective dose rate (μSv/y) due to inhalation in four integrated steel-making factories from Egypt has been evaluated, by assuming a well defined scenario and with basis in the ²¹⁰Pb and ²¹⁰Po activity concentrations determined in ore and wastes collected in the aforementioned factories. Activity concentrations, in Bq/kg, of ²¹⁰Pb and ²¹⁰Po, and leachable Pb and Fe were measured using gamma-ray spectrometry based on HPGe detector, alpha particle spectrometry based on PIPS detector, and inductively coupled plasma-mass spectrometry (ICP-MS). Levels of ²¹⁰Pb and ²¹⁰Po in the range of <DL-4238 and 1-5660 Bq/kg, respectively, were found. According to the assumed scenarios, the occupational exposures by inhalation are much lower than the recommended annual effective dose limit, although the environmental impact due to waste storage and/or use should be considered based on case by case evaluation.     

SO2在碳钢初期大气腐蚀中的作用

通过自建的模拟大气腐蚀系统,借助金相显微镜、扫描电镜(SEM/EDX)、X-射线衍射(XRD)和x-射线光电子能谱(XPS),研究了SO2对碳钢初期大气腐蚀行为的影响,并进一步用原子力显微镜从更微观的角度观察了在SO2环境中初期阶段腐蚀形貌变化.研究结果表明:在SO2污染大气环境中,随SO2浓度的升高碳钢腐蚀加快.在体积分数为5×10(-6)SO2的大气环境中,碳钢和耐候钢表面腐蚀主要以条状物生长,随着SO2浓度的升高,腐蚀产物的形貌发生改变,在体积分数为5×10(-5)SO2的大气环境中,条状锈和胞状锈同时生长.在锈层中S元素以FeSO4·4H2O的形式存在,腐蚀产物中还有γ-FeOOH.SO2在初期阶段加速了碳钢的腐蚀,降低了碳钢的耐蚀性.     

湖北省某钢铁厂工业区及周边铅污染调查

为了解湖北省某钢铁厂周边铅污染的现状,通过对钢铁厂工业区及其周边乡村的土壤、蔬菜、居民体内和排污渠污泥中铅元素含量的研究,其结果表明:钢铁厂周围的土壤、蔬菜、居民均受到了一定程度的铅等重金属元素的污染,其含量高于国家标准或正常范围;钢铁厂工业区周边土壤铅污染主要由于工业废气(烟尘)扩散沉降和废水灌溉引起;污染区人体尿样中铅元素含量(116～160 ng/mL)普遍超标,头发样(2.09～12.04 μg/g)基本正常,尿样比头发样更能显示铅等重金属元素在人体内的分布特征.     

塑烧管除尘器在冶金精轧线的应用

冶金精轧线烟气烟尘含油含水，采用传统的布袋除尘等方式难以治理。塑烧管具有刚性结构、高过滤效率、压降稳定、疏水疏油性、防静电等特性，适合于治理含油含水的烟气。塑烧管除尘器在冶金精轧线的应用取得了良好的效果。     

天然黏土材料附着纳米TiO2对 电解锰渣中锰的吸附固定

采用机械球磨法对膨润土、硅藻土、高岭土3种天然黏土材料进行预处理,通过超声法将纳米TiO_2附着于其上制得复合材料,考察了不同复合材料加入量及养护时间条件下复合材料对电解锰渣中Mn的吸附固定效果。3种天然黏土材料中,硅藻土的平均粒径最小,比表面积和总孔隙度最大,对水中Mn的吸附量也最大。黏土材料附着纳米TiO_2后对电解锰渣中Mn的吸附固定效果较单纯黏土材料有明显改善。在养护时间为12 d、硅藻土附着纳米Ti O_2复合材料加入量为10%(w)的最佳条件下,Mn的TCLP浸出量较原电解锰渣下降了83.04%。     

MANGANESE IN LACUSTRINE ECOSYSTEMS: A REVIEW1

This paper serves as a literature review of manganese in fresh water. The major aspects of manganese occurrence discussed are: (1) sources, (2) geochemistry, (3) manganese-iron relationships, (4) effects on the fauna and flora and (5) detection.     

我国废钢铁资源的可持续利用政策

本文概述了我国废钢铁资源回收利用的现状以及钢铁工业对废钢铁资源的需求现状，用三种不同的模型预测了未来钢铁工业的发展对废钢铁资源的需求，提出了废钢铁资源可持续利用存在的问题和政策建议。     

Exposure Programme on Atmospheric Corrosion Effects of Acidifying Pollutants in Tropical and Subtropical Climates

Many national exposure programmes have been performed in tropical and subtropical climates during the last 50 years. However, ambitious programmes involving more than a few countries are scarce. In this paper a recently formed network of test sites is described involving 12 test sites in Asia (India, Vietnam, Thailand, Malaysia and China including Hong Kong) and four test sites in Africa (South Africa, Zambia and Zimbabwe). This effort is part of the 2001–2004 Swedish International Development Agency (SIDA) funded Programme on Regional Air Pollution in Developing Countries (RAPIDC). Corrosion attack after one (2002–2003) year of exposure (carbon steel, zinc, copper, limestone and paint coated steel) are presented together with environmental data (SO₂, NO₂, HNO₃, O₃, particles, amount and pH of precipitation, temperature and relative humidity) for all the test sites. The obtained corrosion values are substantially higher than expected for limestone, higher than expected for carbon steel and lower than expected for zinc compared to values calculated using the best available dose–response functions.     

节能减排 实现钢铁企业可持续发展

通过对钢铁行业消耗水资源及产生污染情况进行分析，阐述了目前钢铁行业为节能减排而采取的管理、技术、污染治理措施，以达到减少废水外排量、降低污染物浓度、降低新水消耗的目的，对钢铁行业废水回用中尚存和潜在的工艺、设计问题进行了讨论，同时提出了通过清洁生产、优化工艺结构来解决问题的措施和建议，确立了企业近期和长期的节能减排任务目标。