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71.
Feng Gao Guo X. Zhao Hui C. Zhang Ping Wang Jian P. Wang 《Journal of environmental science and health. Part. B》2013,48(2):92-100
The objective of this study was to produce a generic monoclonal antibody for multi-determination of the residues of tetracycline drugs in bovine muscle and milk. Two new immunogens of doxycycline were prepared that were used to produce the monoclonal antibodies. Results showed the obtained antibodies simultaneously recognized seven tetracycline drugs (doxycycline, tetracycline, chlortetracycline, oxytetracycline, minocycline, methacycline, demeclocycline). The obtained antibodies and three coating antigens were arranged into six combinations to optimize the reagents combination. After comparison of the performances of these combinations, a heterologous indirect competitive ELISA was then used to determine the seven tetracyclines in bovine muscle and milk. The crossreactivities to the seven analytes were in the range of 47%–102% and the limits of detection were in the range of 1.5–6.9 ng/mL depending on the compound. The recoveries of the seven drugs from fortified blank samples were in the range of 75.3%–106.8% with coefficients of variation lower than 10.9%. Therefore, this method could be used as a multi-analytes screen tool for routine monitoring of the residues of these tetracycline drugs in bovine muscle and milk. 相似文献
72.
Pâmela C. Oliveira Elizabete M. Maximiano Poliane A. Oliveira Junior S. Camargo Antonio R. Fiorucci 《Journal of environmental science and health. Part. B》2013,48(12):817-823
AbstractThis paper describes a simple, inexpensive, highly sensitive, selective, and efficient electrochemical method to determine glyphosate (GLY) in samples of milk, orange juice, and agricultural formulation. The oxidation reaction on the electrode surface was electrochemically characterised by cyclic voltammetry (CV) and square wave voltammetry (SWV). The investigation of GLY at carbon paste electrode revealed a non-reversible oxidation peak at +0.95 V versus Ag/AgCl, which was used for electrochemical detection of GLY. The operating parameters (pH, frequency, step potential, and amplitude) were optimised in relation to the peak current intensity, and a calibration curve was set up in a concentration range of 4.40?×?10?8–2.80?×?10?6 mol L?1, with a detection limit of 2?×?10?9 mol L?1. After calibration curve was plotted, the developed procedure was applied to determine GLY in previously contaminated samples: milk and orange juice, and in a commercial formulation, obtaining recovery values between 98.31% and 103.75%. These results show that the proposed method can be used for GLY quantification in different samples with high sensitivity, specificity, stability, and reproducibility. 相似文献
73.
Gérard?CoureaudEmail author Dominique?Langlois Guy?Perrier Benoist?Schaal 《Chemoecology》2003,13(4):187-192
Summary. In the rabbit, lactating females emit a volatile
compound in milk, the mammary pheromone (MP), that
triggers rooting for the nipple and its grasping in pups.
Previous studies have shown that the MP seems to act selectively,
in terms both of intensity and quality. Here, we aimed
to add new evidence to these properties of the MP. Newborn
rabbits (n=825) were submitted to an oral activation test
allowing to measure their searching/grasping responses
towards different stimuli. In Experiment 1 we assessed
whether pups respond to the MP in an intensity-dependent
manner. In Experiment 2 we assessed the activity of 20
volatiles previously identified in rabbit milk, other than the
MP, which were never systematically tested for intensitydependence.
The assays showed that a) neonatal responses
are released by the MP only for a limited range of concentrations;
b) the 20 other odorants from milk are inactive at
any concentration. Thus, the MP appears to be the single
volatile from rabbit milk that releases searching/grasping
behaviour in pups. 相似文献
74.
75.
Major and trace element in seven different kinds of milk powder were studied. The concentration of 24 elements were determined by ICP-OES method, from these elements 9 elements determined by INAA. The determination of trace element contents of foodstuffs, especially milk as daily drink for all peoples age which being a complex food has great importance. The elemental analysis of milk is important both as an indicator of environmental contamination and because milk is a significant pathway for toxic metal intake and a source of essential nutrients for humans. The major elements are Ca, K, Mg, Na, P and S. While trace element are B, Ba, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, Sb, Se,Sn, Sr, V, W and Zn.ICP-OES technique is shown to be a powerful tool for trace determinations in powder samples. This is shown by its use for analysis of aseries of the milk powders mentioned and comparative results of other direct technique such as instrumental neutron activation analysis. Analysis of both standard reference material A-Ⅱ milk powder and NBS Orchard leaves for quality accurance had been completed, and used for a relative method calculate. The importance of the major and trace elements to human health was discussed 相似文献
76.
Levels of dechlorane plus and polybrominated diphenylethers in human milk in two Canadian cities 总被引:1,自引:0,他引:1
Siddique S Xian Q Abdelouahab N Takser L Phillips SP Feng YL Wang B Zhu J 《Environment international》2012,39(1):50-55
Flame retardant dechlorane plus (DP) and several polybrominated diphenylether (PBDE) congeners have been measured in 87 human milk samples collected in two Canadian cities: Kingston and Sherbrooke. The levels of PBDEs in human milk (mean (median), ng g− 1 lipid weight = 10 (5.9), 4.1 (2.8), 3.0 (1.6), 5.12 (1.6), and 15 (ND) for BDE-47, BDE-99, BDE-100, BDE-153, and BDE-209, respectively) were comparable to those reported in Europe, U.S.A. and China. The levels of DP, with a mean value of 0.98 ng g− 1 and a median value of 0.60 ng g− 1 (lipid weight), were two to ten times lower than those of concurrently measured major PBDEs including BDE-209. While there is little difference in the levels of measured contaminants in milk samples collected from the two cities, the contaminants levels in human milk show, indicated by Principal Components Analysis, that DP, deca-BDE, and penta-BDE come from three distinct sources. The mean and median isomer ratio values of DP in milk were 0.67 and 0.69, respectively, very similar to that of DP commercial products. 相似文献
77.
Persistent organic pollutants (POP) in human milk originating from various sources are used as environmental exposure markers. Further, mothersmilk is a predominant pathway for human exposure for suckling infants to POP. The aim of present study was to provide baseline and time trend information on human milk POP concentrations in the Republic of Moldova. A pooled sample of breast milk was analyzed in 2009 and 2015 and health risk evaluated by comparing reference values of humans' daily intake with estimated daily intake (EDI). Results showed decreases for concentrations of dichlorodiphenyltrichloroethane, hexachlorobenzene, dieldrin, heptachlor, α and β-hexachlorocyclohexane, polychlorinated biphenyls, dioxin-like polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins and dibenzofurans between sampling periods. Regardless of the decrease, EDI was higher than reference values for dioxins toxic equivalents, polychlorinated biphenyls and β-hexachlorocyclohexane in both phases. However, increased levels were detected for polybrominated diphenyl ethers (twofold) and hexabromocyclododecane (threefold) from 2009 to 2015, but the EDI in both phases is much lower than the reference. The decline in certain POP levels may be attributed to coordinated efforts undertaken by national and international entities to regulate these compounds. The basis for the elevated levels of polybrominated diphenyl ethers and hexabromocyclododecane remains unknown but raises concerns regarding lactational exposure. 相似文献
78.
Human breast milk samples collected from mothers (n = 110) who lived in Chengdu, Sichuan Province, southwestern China in 2009 were analyzed to determine the concentrations of 13 musk compounds. Possible relationships between musk concentrations and some personal characteristics were also studied. Only five target analytes were detected in the milk samples analyzed, with median concentration values of 16.5, 11.5, 7.85, <1.5 and <1.4 ng g−1 lipid weight for AHTN (7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene), HHCB (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[γ]-2-benzopyran), HHCB-lactone (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[γ]-2-benzopyran-1-one), OTNE ([1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethylnaphthalen-2yl]ethan-1-one) and musk ketone (4-tert-butyl-2,6-dimethyl-3,5-dinitroacetophenone, MK), respectively. Mothers who reported high use of hand-cleaning agents, body-cleaning agents, shampoo and hair conditioners, hair dyes and hair gels had significantly elevated milk concentrations of HHCB whereas elevated milk concentrations of AHTN were observed among mothers reporting high use of body-cleaning agents, body lotions, shampoos, hair dyes and hair gels. Younger age showed a significantly positive effect on milk concentrations of both HHCB and AHTN whereas BMI after delivery, the number of children nursed and place of residence (urban or rural) had no significant effect. The estimated median daily intakes of synthetic musks for breast-fed infants were considerably lower than the current provisional tolerable daily intake amounts suggested for adults. 相似文献
79.
Levels of synthetic musk fragrances in human milk from three cities in the
Yangtze River Delta in Eastern China 总被引:2,自引:0,他引:2
Xiaolan Zhang Gaofeng Liang Xiangying Zeng Jing Zhou Guoying Sheng Jiamo Fu 《环境科学学报(英文版)》2011,23(6):983-990
Synthetic musks are used as additives in many household products. After absorption into the human body, they accumulate and
their concentrations in human milk reflect both the mother and her infant’s exposure level. Concentrations of four synthetic musks,
musk xylene (1-tert-butyl-2,6-dimethyl-2,4,6-trinitrobenzene, MX), musk ketone (4-tert-butyl-2,6-dimethyl-3,5-dinitroacetophenone,
MK), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[
]-2-benzopyran (HHCB) and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-
tetrahydronaphthalene (AHTN), were determined in human milk samples collected from Shanghai, Wuxi, and Shaoxing in Eastern
China. The four synthetic musks were found in most samples analyzed, with HHCB the dominant component followed by MX. The
median (mean) values for HHCB, AHTN, MX and MK concentrations were 63 (82), 5 (12), 17 (24) and 4 (9) ng/g lipid weight,
respectively. These data suggested the total synthetic musk contamination was low, and the distribution percentage was HHCB > MX
> AHTN MK. The relative high ratio of nitro to polycylic musk indicated that nitro musks were still widely used. The musk
concentrations in these cities were not significantly different from each other (p > 0.05). Principal components score plots were
obtained, which showed similar exposure sources. The amount of total synthetic musks in human milk were not associated with
mother’s age, although HHCB was significantly correlated with AHTN (p < 0.05). Daily ingestion of HHCB, AHTN, MX and MK for
infants from human milk were estimated as (2526 2926), (370 524), (7391 832), and (277 462) ng/day, respectively. Those
doses were 1–2 orders of magnitude below the provisional tolerable daily intakes. 相似文献
80.
Polybrominated diphenyl ethers(PBDEs) can be transferred to infants through the ingestion of breast milk, resulting in potential health risk. In this study, PBDEs, hydroxylated polybrominated diphenyl ethers(OH-PBDEs) and 2,2′,4,4′,5,6′-hexachlorobiphenyl(CB-153)in human milk from women living adjacent to e-waste recycling sites of Wenling,China, were investigated. The median level of PBDEs in samples from residents living in the e-waste recycling environment 20 years(R_20group, 19.5 ng/g lipid weight(lw))was significantly higher than that for residents living in Wenling 3 years(R_3group,3.88 ng/g lw)(p 0.05), likely ascribable to specific exposure to PBDEs from e-waste recycling activities. In the R_20 group, most congeners(except for BDE-209) were correlated with each other(p 0.05). Moreover, CB-153 showed significant association with most PBDE congeners, rather than BDE-209. The relationship indicated that most BDE congeners other than BDE-209 shared common sources and/or pathways with CB-153, e.g., dietary ingestion. The correlations between BDE-209 and other congeners were different in the two groups, likely suggesting their different exposure sources and/or pathways for PBDEs.Although estimated dietary intake of PBDEs for infants via breast milk was lower than the minimum value affecting human health, the PBDE exposure of infants should be of great concern because of their potential effect on the development of neonates over long-term exposure. OH-PBDEs were not detected in the collected samples, which is in accordance with reports in published literature, likely indicating that they were not apt to be accumulated in human milk. 相似文献