全文获取类型
收费全文 | 4949篇 |
免费 | 678篇 |
国内免费 | 3439篇 |
专业分类
安全科学 | 189篇 |
废物处理 | 358篇 |
环保管理 | 425篇 |
综合类 | 5276篇 |
基础理论 | 1145篇 |
污染及防治 | 1225篇 |
评价与监测 | 317篇 |
社会与环境 | 121篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 25篇 |
2023年 | 157篇 |
2022年 | 280篇 |
2021年 | 304篇 |
2020年 | 331篇 |
2019年 | 310篇 |
2018年 | 318篇 |
2017年 | 280篇 |
2016年 | 388篇 |
2015年 | 359篇 |
2014年 | 391篇 |
2013年 | 686篇 |
2012年 | 537篇 |
2011年 | 546篇 |
2010年 | 415篇 |
2009年 | 393篇 |
2008年 | 343篇 |
2007年 | 443篇 |
2006年 | 421篇 |
2005年 | 318篇 |
2004年 | 285篇 |
2003年 | 303篇 |
2002年 | 225篇 |
2001年 | 172篇 |
2000年 | 162篇 |
1999年 | 146篇 |
1998年 | 104篇 |
1997年 | 97篇 |
1996年 | 75篇 |
1995年 | 62篇 |
1994年 | 54篇 |
1993年 | 50篇 |
1992年 | 24篇 |
1991年 | 18篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1986年 | 8篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1981年 | 2篇 |
1977年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有9066条查询结果,搜索用时 31 毫秒
101.
木质素降解酶及其调控机理研究的进展 总被引:11,自引:0,他引:11
近年来有关木质素降解微生物和木质素降解酶的产与调控机理的研究表明,腐霉和细菌在木质自然降解中起着重要作用,腐霉的降解作用发生在次级代谢阶段,而细菌发生在初级代谢阶段,影响木质素降解酶的产生酶活力高低的因素有碳氮的选择与限制;诱导物的添加;表面活性剂的使用;某些金属离子浓度水平的改变;菌丝的固定化,温度和摇床转速的变换等。 相似文献
102.
InterfacialefectsofsuspendedparticlesonbiodegradationofN(2,4dimethylphenyl)N’methylformamidinehydrochlorideanddibutylphth... 相似文献
103.
典型北方高碱度微污染水体强化混凝的示范研究 总被引:5,自引:0,他引:5
以高碱度、受有机物污染的典型北方水体为例,探索适宜的强化混凝技术.在水质调查的基础上,提出适合水质特征的强化混凝目标.研究了高碱度水体强化混凝技术方法.研究表明,可以通过3条技术途径提高水体中有机物的去除效率.其一在混凝前优化pH,促进絮凝剂水解形成中聚体,AlCl3在pH 6左右,FeCl3在pH 5左右时,有机物去除率可以提高一倍左右;其二是强化沉淀软化;其三是絮凝剂优化.结合我国实际情况,通过对传统絮凝剂进行改性,研制出了适合我国北方水质特征的高效絮凝剂,能较传统絮凝剂将有机物去除率提高30%以上. 相似文献
104.
Richard Louis Edmonds 《环境科学学报(英文版)》1989,1(1):1-14
Environmental problems in China can be divided into two large classes: pollution and destruction of natural environment. Environmental degradation is particularly serious in areas with rapid population growth. In this paper, some of China's major environmental problems, particularly those concerned with land, forests, and continental waters are introduced in order to see how population growth and management have affected these resources over the past few decades. It is also explained how the Chinese plan to cope and eventually solve these problems. 相似文献
105.
为研究南京北郊大气PM_(2.5)中水溶性有机碳(WSOC)的浓度及来源特点,在冬、夏季分别采集PM_(2.5)样品,还同步收集臭氧(O_3)浓度与相对湿度(RH)数据,分析了PM_(2.5)、有机碳(OC)、水溶性有机碳(WSOC)浓度特征,并对WSOC冬、夏季来源及其二次来源差异进行了探讨.结果显示,南京北郊冬季大气污染水平明显高于夏季且来源更复杂,与冬季静稳的天气条件及化石燃料和生物质燃烧排放较严重有关.冬季PM_(2.5)平均值为(136.7±42.4)μg·m~(-3),OC、WSOC浓度分别为(13.4±4.4)、(8.5±3.1)μg·m~(-3);夏季PM_(2.5)、OC、WSOC平均浓度分别为(61.5±14.6)、(6.7±2.1)、(4.6±1.7)μg·m~(-3).冬、夏季WSOC/OC值分别为67%±20%、69%±13%,且二次有机碳(SOC)与WSOC显著正相关,说明二次来源对WSOC有显著影响.冬季WSOC与O_3的负相关性不显著,与RH显著正相关;而夏季WSOC与O_3、RH的相关性正好与冬季相反,说明冬、夏季二次WSOC形成途径存在差异.冬季二次WSOC可能主要来自液相氧化,夏季可能主要来自光化学氧化.通过主成分因子分析法进一步确定南京北郊冬、夏季WSOC分别主要来源于二次来源和生物质燃烧、汽车尾气和扬尘. 相似文献
106.
《环境科学学报(英文版)》2023,35(3):309-318
Accurate quantification of dissolved organic nitrogen (DON) has been a challenge due to the cumulative analytical errors in the conventional method via subtracting dissolved inorganic nitrogen species (DIN) from total dissolved nitrogen (TDN). Size exclusion chromatography coupled with an organic nitrogen detector (SEC-OND) has been developed as a direct method for quantification and characterization of DON. However, the applications of SEC-OND method still subject to poor separations between DON and DIN species and unsatisfied N recoveries of macromolecules. In this study, we packed a series of SEC columns with different lengths and resin materials for separation of different N species and designed an independent vacuum ultraviolet (VUV) oxidation device for complete oxidation converting N species to nitrate. To guarantee sufficient N recoveries, the operation conditions were optimized as oxidation time ≥ 30 min, injection mass (sample concentration × injection volume) < 1000 µL × mg-N/L for macromolecular proteins, and neutral pH mobile eluent. The dissolved O2 concentration in SEC mobile phase determined the upper limit of VUV oxidation at a specific oxidation time. Compared to conventional HW50S column (20 × 250 mm), HW40S column (20 × 350 mm) with mobile phase comprising of 1.5 g/L Na2HPO4·2H2O + 2.5 g/L KH2PO4 (pH = 6.85) could achieve a better separation of DON, nitrite, nitrate, and ammonia. When applied to river water, lake water, wastewater effluent, groundwater, and landfill leachate, the SEC-OND method could quantify DON as well as DIN species accurately and conveniently even the DIN/TDN ratio reached 0.98. 相似文献
107.
Yang Zhang Tianyi Zhao Yu Yan Bian Zhou Xuezhen Zhong Xiaoyu Hu Lijia Zhang Peng Huo Kang Xiao Yuanxun Zhang 《环境科学学报(英文版)》2023,35(2):835-845
Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future. 相似文献
108.
零价铁还原降解2,4-二硝基甲苯研究 总被引:7,自引:0,他引:7
研究了零价铁对2,4-二硝基甲苯(2,4-DNT)的还原降解情况。实验结果表明,2,4-DNT的还原降解率与溶液初始pH值、初始浓度、溶解氧含量和铁粉投加量等因素有关。2,4-DNT在还原过程中先生成2-氨基-4-硝基甲苯(2A4NT)和4-氨基-2-硝基甲苯(4A2NT),最后被还原成2,4-二氨基甲苯(2,4-DAT)。 相似文献
109.
Degradation of Populus euphratica community in the lower reaches of the Tarim River, Xinjiang, China 总被引:8,自引:0,他引:8
IntroductionRiparian systems are aquatic-terrestrial ecotones withunique biotic , biophysical and landscape characteristics(Gregory, 1991 ; Naiman, 1997 ; Wiens , 2002) and areshaped by fluvial geomorphic processes . Riparian plantcommunities perform an i… 相似文献
110.