pH值、硫酸根和温度对钢管管垢中铬释放的影响

以市政供水管网钢管管垢为研究对象,将垢层由外向内分为表层、硬壳层和疏松多孔层.利用SEM、BET、XRD、XPS和分形态提取等技术对预吸附Cr(Ⅵ)前后的各层管垢进行表征和分析,并探究了pH值、SO₄^2-浓度和温度对各层管垢中Cr释放的影响.结果显示,钢管各层管垢的主要成分均为α-FeOOH,吸附性能排序为表层>疏松多孔层>硬壳层,管垢中铁元素大多以三价和二价形式存在,具有一定还原性.Cr(Ⅵ)通过物理和化学吸附富集于管垢,主要以铁锰氧化物结合态存在,表层管垢富集量最大.酸性环境、SO₄^2-浓度和温度的升高均会促进Cr的释放.强酸性条件下表层Cr释放浓度为中性条件下的2.76倍;SO₄^2-浓度增加使各层管垢的Cr释放量增加0.1～0.4倍;温度升高20℃,表层管垢的Cr释放量增加26.74%.     

Residence and place image

Data are presented for a particular population on its perception of English and Welsh local authority areas in terms of desirability for residence. The method employed permits a distinction between positive and negative judgements as well as a measure of the differing degree to which areas figure in the mind at all. It is established that the areas are seen in terms of a sharply differentiated hierarchy of preference and that there is considerable variation in the extent to which areas are “visible”. In aggregate negative judgements predominate and the most frequently expressed attitude is strong dislike. Places in the south‐west are popular as are some places in the north. London Boroughs are unpopular although in varying degrees. The most favoured place is Cornwall and the least favoured is Wolverhampton. It is argued that perceptions studied in the “direct” way used here are important to complement those employing an “oblique” method in which criteria of choice are assumed or established by social survey and then used to create a profile of preference against which places can be measured and ranked.     

Small towns in the united states: a perspective

Small towns are an important part of the rural settlement fabric in the United States, but there is very little substantive research into their capacity to survive or their intrinsic importance. However, recently there has been increasing interest shown by social scientists in these problems. This paper looks at features of this research from the point of view of the population and economic structure of small towns. It concludes by arguing that the problems of small towns are not indigenous to the towns, and calls for a comprehensive national urban policy.     

Twenty-five years of HAZOPs

The HAZOP or hazard and operability study was developed by ICI over 25 years ago and is in wide use today throughout the world. The technique is intended to review, in a formalized manner, the design of a system such as a chemical process production plant to detect potential problems in the operation of the system. The system has been extended for use on all types of production, storage and distribution units. Experience in the use of hazard studies has lead to the development of a phased approach with three distinct design phases.     

SIMULATION OF HERBICIDE CONCENTRATIONS IN STORMFLOW FROM FORESTED WATERSHEDS1

The breakpoint rainfall hydrology and pesticide options of the field scale model CREAMS (Chemicals, Runoff, and Erosion from Agricultural Management Systems) were used to predict average concentrations of hexazinone [3 cyclohexyl-6-(dimethyl-amino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] in stormflow from four forested watersheds in the upper Piedmont region of Georgia. Predicted concentrations were compared with measured concentrations recorded over a 13-month period. CREAMS accurately predicted hexazinone concetrations in the initial stormflow events which also contained the highest concentrations. The model underestimated the hexazinone concentrations in stormflow two months and greater following pesticide application. In a companion study, the daily rainfall option of the CREAMS model was used to evaluate the reltive risk associated with the maximum expected concentration of hexazinone, bromacil (5-bromo-3 sec-butyl-6 methyuracil), picloram (4-amino-3,5,6 trichloropicolinic acid), dicamba (3,6-dichloro-0-anisic acid), and triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} in stormflow from small forested watersheds. The model predicted the following order of potential residue appearance in stormflow: bromacil>triclopyr>hexazinone>picloram>dicamba. Subsurface movement of residues via interflow and deep leaching losses are not simulated by the version of CREAMS used in these studies.     

Results from Three Field Tracer Experiments on the Neighbourhood Scale in the City of Birmingham UK

The physical processes governing flow and pollutantdispersion at the neighbourhood scale, a spatial scaleintermediate between the street scale and the city scale, is notwell understood. Furthermore, it is not clear whether a traditional approach using averaged characteristics such as theaerodynamic roughness length is sufficient to predict the concentration field at this scale. To investigate pollutant dispersion in a real urban area, three field experiments were designed within the UK-URGENT programme sponsored by NERC. Theexperiments were performed in the City of Birmingham using a finite duration release of inert, non-toxic and non-depositingtracers, vis. perfluoromethylcyclohexane (PMCH) and perfluoromethylcyclopentane (PMCP). Measurements were taken using air bag samplers placedin an arc at 3.5 km (first experiment) and 1 km (second andthird experiments) from the source; some trap samplers wereplaced outside the main arc in the outskirts of the city. Measurements were analysed in the laboratory using anovel gas-chromatography technique. Data so obtained werecompared with predictions from a simple steady-state modeland a time-dependent model. The concentration-time serieswere very asymmetrical with a sharp rise, a plateau followedby a relatively slow decrease and finally a long-livedplateau above (or possibly very slow decrease to) thebackground level.     

Reuse of wastewater for industrial needs: the Pontedera case

This paper presents result from an economic and technical point of view evaluation study, which has sought to establish the potential for replacing well-water that is currently used at the Piaggio industrial plant in Pontedera with recycled wastewater. The study is based upon a pilot wastewater treatment plant, which has been used to test wastewater treatment processes and to compare with achieved quality of recycled waters with that of water drawn on-site from physical/chemical pre-treatment and end with a reverse osmosis and air stripping stage. However, after the physical/chemical pre-treatment, the first option uses oxidation with ozone followed by activated carbon filtration, whereas the second method uses ultrafiltration. The first method is more effective at reducing chemical oxygen demand (COD) whereas the second method is more effective in removing bacteria. Nonetheless, both methods deliver water for re-use of a quality comparable with or better than that of well-water. In principle, the reverse osmosis permeate from either process could be re-used in all production phases at the industrial plant. However, the method base upon oxidation with ozone followed by activated carbon filtration is preferred, because, the process is simpler and continuous. The economic analysis of this process gives an estimated cost of Euro 0.55 per m³ for treated water. This compares favorably with other treatment processes and with the cost of other forms of water supply, which are projected to increase in any case.     

可持续发展中合理人口规模的研究：以苏南地区集镇为例

本文在分析农业人口转移数量、经济效益、社会商品销售额、集镇容纳能力的基础上,研究了集镇合理人口规模的界线。     

乡镇工业企业发展与环境,资源协调问题初探

我国乡镇工业企业的发展与环境、资源的协调问题已经成为我国发展与环境、资源关系方面的大问题。实行工农相对分离,组建乡村工业区,是提高乡镇工业企业素质、效益,强化乡镇工业企业优化组合、规模经营的有效途径;是保护环境,实现资源有效利用的基础工作之一;是提高农业劳动生产率,实现农业规模经营的基础工作之一。     

Sensitivity of Ozone Production to the Nmhc Composition, Aerosol Back-Scattering and High Chimney Emission

In this paper, three sensitivity studies are designed to analyze the effect of the NMHC (Non-Methane HydroCarbon) composition, the aerosol back-scattering and the high chimney NO_x emission to the photochemical prodution of ozone by using a one-dimensional photochemistry-diffusion model under a favourable meteorological condition. Measurements of the NMHC composition in Taipei indicated that the percentage of iso-butene, cis-2-butene, trans-2-butene and benzene in a unit volume was much higher than of those observed in other major cities. the high ratio of benzene was directly linked to its high percentage in gasoline. As to the unusually high amount of iso-butene, cis-2-butene and trans-2-butene, more researches are needed to identify their source. Concerns are raised as to how productive is NMHC composition is to the photochemical production of the surface ozone. A rough estimate shows that the total reactivity of the Taipei NMHC composition is about 1.21 × 10^-9 cm³ s^-1 which is 1.6 times that of the Los Angeles (LA) NMHC composition, while the simulated noon peak will be different by 28 ppbv, i.e. 18% more than that simulated with a LA composition.

Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.

In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NO_x from high chimneys cannot be ignored. in this study, NO_x is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NO_x emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated.