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351.
352.
Jason A. Dittman James B. Shanley George R. Aiken Janet E. Towse 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1953-1956
Stream water samples were collected over a range of hydrologic and seasonal conditions at three forested watersheds in the northeastern USA. Samples were analyzed for dissolved total mercury (THgd), DOC concentration and DOC composition, and UV254 absorbance across the three sites over different seasons and flow conditions. Pooling data from all sites, we found a strong positive correlation of THgd to DOC (r2 = 0.87), but progressively stronger correlations of THgd with the hydrophobic acid fraction (HPOA) of DOC (r2 = 0.91) and with UV254 absorbance (r2 = 0.92). The strength of the UV254 absorbance-THgd relationship suggests that optical properties associated with dissolved organic matter may be excellent proxies for THgd concentration in these streams. Ease of sample collection and analysis, the potential application of in-situ optical sensors, and the possibility for intensive monitoring over the hydrograph make this an effective, inexpensive approach to estimate THgd flux in drainage waters. 相似文献
353.
木棉基活性炭纤维吸附性能的研究 总被引:1,自引:0,他引:1
采用浸渍(NH4)2HPO4化学活化法650℃时制备得到3种新型木棉基活性炭纤维,即只浸渍不预氧化方法处理的AK1(activated kapok),先浸渍后预氧化的AK-2和先预氧化后浸渍的AK-3。利用制备得到的活性炭纤维处理苯酚和亚甲基蓝的模拟废水,AK-2具有苯酚最大吸附量(137.00 mg/g),AK-1具有亚甲基蓝最大吸附量(274.11 mg/g)。吸附苯酚时,在静态平衡实验中,更符合Freundlich吸附等温线;在动力学实验中,更符合准一级反应。吸附亚甲基蓝时,在静态平衡实验中,AK-1更符合Langmuir模型,AK-2 、AK-3更符合Freundlich吸附等温线;在动力学实验中,更符合准二级反应。 相似文献
354.
三氯生在碳纳米管上的吸附 总被引:3,自引:2,他引:1
药品和个人护理用品(PPCPs)已成为一个引起广泛关注的新的环境问题。采用碳纳米管(CNTs)对水溶液中的三氯生进行吸附处理,考察了碳纳米管粒径及用量、温度、pH、振荡时间等因素对三氯生去除率的影响。研究结果表明,碳纳米管能快速吸附水中的三氯生,粒径较小的碳纳米管可获得较高的三氯生去除率;低温有利于吸附反应的进行;pH在6.5~7.0时,三氯生的去除率可达97%。三氯生在碳纳米管上的吸附可以很好地用Langmuir和Freundlich吸附等温方程进行描述。 相似文献
355.
固定化假单胞菌降解油烟废气的研究 总被引:1,自引:0,他引:1
将从受油烟废气污染严重的土壤中分离筛选的具有较强降解油烟能力的假单胞菌利用活性炭为填料吸附固定后制成填料床生物反应器。实验考察了进气浓度、气体流量、气体停留时间、容积负荷等对油烟去除率的影响,初步研究了生物反应器的抗冲击能力。结果表明,活性炭填料对菌体具有良好的吸附能力,当油烟进气浓度小于100 mg/L,气体流速小于8 L/h,停留时间大于30 s,容积负荷为2.6~18.9 g油烟废气/(m3·h),生物反应器的降解效率可达到95%以上,且活性炭填料床反应器具有较强的抗冲击能力。 相似文献
356.
357.
F. Boudrahem F. Aissani-Benissad H. Aït-Amar 《Journal of environmental management》2009,90(10):3031-3039
Lignocellulosic materials are good precursors for the production of activated carbon. In this work, coffee residue has been used as raw material in the preparation of powder activated carbon by the method of chemical activation with zinc chloride for the sorption of Pb(II) from dilute aqueous solutions.The influence of impregnation ratio (ZnCl2/coffee residue) on the physical and chemical properties of the prepared carbons was studied in order to optimize this parameter. The optimum experimental condition for preparing predominantly microporous activated carbons with high pore surface area (890 m2/g) and micropore volume (0.772 cm3/g) is an impregnation ratio of 100%. The developed activated carbon shows substantial capability to sorb lead(II) ions from aqueous solutions and for relative impregnation ratios of 75 and 100%, the maximum uptake is practically the same. Thus, 75% represents the optimal impregnation ratio.Batch experiments were conducted to study the effects of the main parameters such as contact time, initial concentration of Pb(II), solution pH, ionic strength and temperature. The maximum uptake of lead(II) at 25 °C was about 63 mg/g of adsorbent at pH 5.8, initial Pb(II) concentration of 10 mg/L, agitation speed of 200 rpm and ionic strength of 0.005 M. The kinetic data were fitted to the models of pseudo-first order and pseudo-second order, and follow closely the pseudo-second order model. Equilibrium sorption isotherms of Pb(II) were analyzed by the Langmuir, Freundlich and Temkin isotherm models. The Freundlich model gives a better fit than the others.Results from this study suggest that activated carbon produced from coffee residue is an effective adsorbent for the removal of lead from aqueous solutions and that ZnCl2 is a suitable activating agent for the preparation of high-porosity carbons. 相似文献
358.
In this paper, Loofa egyptiaca (LE), an agricultural plant cultivated in Egypt, was used to prepare low-cost activated carbon (LEC1 and LEC2) adsorbents. The adsorbents (LE, LEC1 and LEC2) were evaluated for their ability to remove direct blue 106 dye from aqueous solutions. Batch mode experiments were conducted using various parameters such as pH, contact time, dye concentration and adsorbent concentration. The surface chemistry of LE, LEC1 and LEC2 was analyzed by scanning electron microscopy (SEM). The experimental data were examined using Langmuir, Freundlich, Temkin and Harkins–Jura isotherms. The results showed that the adsorption of direct blue 106 was maximal at the lowest value of pH (pH = 2). Removal efficiency was increased with an increase in dye concentration and a decrease in amount of adsorbent. Maximum adsorption capacity was found to be 57.14, 63.3 and 73.53 mg/g for LE, LEC1 and LEC2 respectively. Kinetics were also investigated using pseudo-first-order, pseudo-second-order and intra-particle diffusion models. The experimental data fitted very well with the pseudo-first-order and pseudo-second-order kinetic models. The results indicate that LE, LEC1 and LEC2 could be employed as adsorbents for the removal of direct blue dye from aqueous solutions. 相似文献
359.
机制设计理论是研究在市场失灵的情况下,如何设计一套机制达到既定社会目标的理论。而环境问题的特殊性质使得单纯依靠市场无法合理有效的解决环境问题,这就需要机制设计这一理论的指导。基于机制设计理论的原理,已探索出很多环境政策,有效的预防并解决了污染问题,使公众利益与社会的总体利益达到了“激励相容”。本文在以排污税、排污权交易等环境政策的设计为例,探讨了机制设计理论在环境政策制定中的应用,同时分析了机制设计理论存在的问题,指出在经济全球化的背景下,依靠机制设计理论解决环境问题遇到的瓶颈,提出了利用机制设计理论制定环境政策未来的可能方向和着力点。 相似文献
360.
金融危机对中国发展碳金融的影响及对策分析 总被引:3,自引:0,他引:3
2007年以来,席卷全球的金融危机已经对世界各国的金融体系造成了或大或小的影响,这对于全球碳金融市场——这个刚刚起步并稍显呈现欣欣向荣之势的市场无疑是一个利空消息。本文总结了国际碳交易市场在金融危机来袭时的表现,着重分析了中国通过清洁发展机制参与国际碳金融市场并受金融危机影响的表现,探讨了在金融危机的大环境中,中国作为发展中国家如何在危机中寻求生存并发展。 相似文献