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881.
CS2 removal was Obtained by coupling catalytic hyidation on bi-functional catalyst.On the hydrolysis active sites,CS2 is hydrolyzed to H2S,while on the oxidation active sites,H2S is oxidized to elemental S or sulfuric acid deposited on the porous support.The above process can be expressed as followsCS2→H2O COS →H2O H2S→O2 S/SO2- 4.H2S oxidation eliminates its prohibition on CS2 hydrolysis so that the rate of coupling removal CS2 is 5 times higher than that of CS2 hydrolysis.The same active energy of hydrolysis and coupling reaction also indicates that H2S oxidation does not change the reaction mechanism of CS2 hydrolysis.Temperature has obvious effect on the process while the mole ratio of O2 concentration to CS2 concentration (O/S) does not,especially in excess of 2.5.The formation of sulfuric acid on the catalyst surface poisons hydrolysis active sites and causes the decrease of left OH-1 concentration on the catalysts surface.Lower temperature is suggested for this bi-functional catalyst owing to the low yield ratio of S/SO4 2-. 相似文献
882.
Geological emission of methane from the Yakela condensed oil/gas field in
Talimu Basin, Xinjiang, China 总被引:1,自引:0,他引:1
A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and p... 相似文献
883.
以活性嫩黄K-4G染料模拟废水为处理对象,探讨了多维电极系统处理活性染料废水时色度、COD降解的效果和机理。结果表明,活性炭多维电极法对染料废水的处理效果优于单纯电解法和单纯活性炭吸附法;氧化和还原作用对染料的色度和COD去除效果相差不大;增大处理系统中溶液的循环流量可显著改善活性炭多维电极系统对COD和色度的去除效果。 相似文献
884.
两种类型的活性炭对Zn(Ⅱ)的吸附作用研究 总被引:1,自引:0,他引:1
分别用木炭和煤炭作为吸附剂,对Zn(Ⅱ)进行了吸附试验。虽然木炭的比表面积小于煤炭,但其对Zn(Ⅱ)的吸附作用明显优于煤炭。同时,溶液的pH对活性炭的吸附作用也有很大影响。在pH<7时,活性炭对Zn(Ⅱ)的吸附作用随着pH的增加而增加。 相似文献
885.
886.
以自制多维电极体系对模拟染料废水CODcr及色度去除进行研究,同时考察反应器电压、电解时间、主电极极间距、电流密度等因素对去除效果的影响。试验结果表明,在最佳反应条件下,印染废水经电解后,脱色率达90%以上,CODcr去除率达81%以上,为难降解染料废水的处理提供了一种新方法。 相似文献
887.
888.
某针织印染厂年产3000吨针织高档服装布料,排放的生产废水中含有大量的有机物,COD、BOD5、色度浓度比较高。该厂选择了"厌氧水解酸化+接触氧化法+活性炭吸附"处理工艺。该工艺采用厌氧水解酸化处理工艺进行前期处理,去除大部分有机物,减轻了后续接触氧化处理工艺的压力,同时通过活性碳过滤进行脱色,达到较好的处理效果。运行结果表明,经该工艺处理后,废水中的COD、BOD5、色度等指标均能达标排放,有利于企业的可持续发展。 相似文献
889.
《International Journal of Sustainable Engineering》2013,6(1):24-36
This research work focuses on the application of life-cycle assessment methodology to determine the carbon footprint of different players involved in a supply chain of the textile sector. A case study of a product by a textile leader company was carried out. This study demonstrates that, in the textile chain, the main contribution to the greenhouse effect is provided by the electrical and thermal energy used and by the transportation (since different production phases are delocalised in a wide range that goes from South Africa, Italy, Romania and all around the world, from the distribution centre to the stores). The Monte Carlo analysis has been used in order to obtain, for each calculated impact, not only the average value but also the distribution curve of the results characterised by uncertainty parameters. Moreover, a sensitivity analysis was carried out to evaluate the impact of management choices such as: ??a change in the transportation modality, from aeroplane to boat; ??a combination of road and rail transportation; and ??a selection among suppliers that allows the firm to cut environmental impacts. 相似文献
890.
《International Journal of Sustainable Engineering》2013,6(4):232-240
A Carbon Emission Signature (CES) and a Carbon Emission Label have been proposed for manufactured products in previous CIRP (Collège International pour la Recherche en Productique) annals. This paper considers two things: (1) an example of a CES calculation for assembly with CO2 emissions and (2) the need for a transparent method of calculation. In comparing carbon footprint calculations for 17 websites, the results are found to vary more than threefold depending upon the site used and even more between different methods illustrating the need for standardisation in emission calculations for carbon accounting. 相似文献