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941.
利用固相萃取前处理方法,净化和富集海水中的16种磺胺类抗生素,采用超高压液相色谱-串联质谱法进行定性和定量检测,建立了完整的海水中磺胺类抗生素的检测方法,并对质谱条件、液相条件和固相萃取条件进行了优化。实验结果表明,16种磺胺类抗生素在0.1~100μg/L质量浓度范围内线性良好,相关系数均可以达到0.996以上,方法检出限为0.3~1.1 ng/L。对水样进行高、中、低3个质量浓度的加标回收实验,回收率分别为82.3%~125.7%,73.3%~125.1%和75.2%~119.2%,相对标准偏差为2.4%~12.0%。该方法具有操作简便、重现性好、灵敏度高的优点,可用于海水中磺胺类抗生素的监测分析。 相似文献
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944.
通过对在同一种原煤上使用液体节煤固硫添加剂前、后锅炉废气的对比测试,分析了加入添加剂后锅炉排放废气中烟尘粒径、烟尘浓度、二氧化硫、氮氧化物浓度等变化的原因及趋势。结果表明,在使用液体节煤固硫添加剂后,锅炉排放废气中烟尘、二氧化硫浓度均有显著降低,氮氧化物浓度基本不变,排放烟尘粒径呈现由较大向较小转化的趋势。 相似文献
945.
Twelve samples each of soil and ground water were collected from paddy-wheat, paddy-cotton, sugarcane fields and tube wells
from same or near by fields around Hisar, Haryana, India during 2002–2003 to monitor pesticide residues. Residues were estimated
by GC-ECD and GC-NPD systems equipped with capillary columns for organochlorine, synthetic pyrethroid and organophosphate
insecticides. In soil, HCH (0.002–0.051 μg g−1), DDT (0.001–0.066 μg g−1), endosulfan (0.002–0.039 μg g−1) and chlordane (0.0002–0.019 μg g−1) among organochlorines, cypermethrin (0.001–0.035 μg g−1) and fenvalerate (0.001–0.022 μg g−1) among synthetic pyrethroids and chlorpyriphos (0.002–0.172 μg g−1), malathion (0.002–0.008 μg g−1), quinalphos (0.001–0.010 μg g−1) among organophosphates were detected. Dominant contaminants were DDT, cypermethrin and chlorpyriphos from the respective
groups. In water samples, HCH, DDT, endosulfan and cypermethrin residues were observed frequently. Only chlorpyriphos among
organophosphates was detected in 10 samples. On consideration of tube well water for drinking purpose, about 80% samples were
found to contain residues above the regulatory limits. 相似文献
946.
高效液相色谱法测定环境水样中嘧磺隆 总被引:2,自引:0,他引:2
环境水体中的嘧磺隆在pH=2-3的H2SO4介质中用二氯甲烷萃取富集,然后用高压液相色谱法分离和紫外光(254nm)检测器检测,外标法定量。用此方法测定了井水和生产单位排放的综合污水中的嘧磺隆,结果满意,最大相对标准偏差为5%,样品加标回收率在93~107%之间,最低检测限量为2ng,最低检出浓度为0.004mg/L。 相似文献
947.
Takahiro Yamaguchi Masahiro Okihashi Yoshimasa Konishi Kotaro Uchida Mai Hoang Ngoc Do 《Journal of environmental science and health. Part. B》2017,52(6):430-433
The residual levels of antibiotics in Vietnamese eggs were monitored from 2014 to 2015. A total of 111 egg packages, distributed by 11 different companies, were collected from supermarkets in Ho Chi Minh City and the levels of 28 antibiotics were analyzed using liquid chromatography-tandem mass spectrometry (LC-MS/MS) screening method. Sixteen samples tested positive for antibiotics; a total of eight compounds (enrofloxacin, ciprofloxacin, norfloxacin, sulfadimethoxine, sulfamethazine, sulfamonomethoxine, tilmicosin and trimethoprim) were detected. Enrofloxacin was detected in eight samples, with two samples exhibiting concentrations exceeding 1,000 µg kg?1. Tilmicosin was detected in three samples at a range of 49–568 µg kg?1. We observed that two of the 11 companies frequently sold antibiotic-contaminated eggs (detection rates of 56 and 60%), suggesting that a number of companies do not regulate the use of antibiotics in egg-laying hens. Our findings indicate that livestock farmers require instruction regarding antibiotic use and that continual antibiotic monitoring is essential in Vietnam. 相似文献
948.
Camino-Sánchez FJ Zafra-Gómez A Pérez-Trujillo JP Conde-González JE Marques JC Vílchez JL 《Chemosphere》2011,84(7):869-881
A multiresidue method for the analysis of 86 persistent pollutants in marine sediments at ultra-trace level has been developed and validated using pressurized liquid extraction (PLE) and stir-bar sorptive extraction (SBSE) coupled with thermal desorption and gas chromatography-triple quadrupole mass spectrometry (TD-GC-MS/MS QqQ). The compounds analyzed belong to various families such as polychlorinated biphenyls, polycyclic aromatic hydrocarbons, polybrominated diphenylethers, organophosphorus and organochlorine pesticides and other pesticides such as urons, and triazines. The analytes have very different polarities and log Kow values, which is an important parameter in the optimization of a SBSE method. Due to PLE high efficiency and throughput rates, along with the proven ability for multiresidue analysis and excellent sensitivity of SBSE, we present an efficient method. The limits of quantification obtained ranged from 0.014 to 1.0 ng g−1, with detection limits below pg g−1 levels. In order to validate the proposed methodology, quality parameters such as recovery, linearity and reproducibility were studied. Recoveries ranged from 63% to 119%, reproducibility (in terms of Relative Standard Deviation for ten determinations) was lower than 35% in all cases, and determination coefficients higher than 0.990 for all analytes. The main factors that affect PLE, SBSE and GC-MS/MS procedures were optimized. The method was applied to the analysis of nine marine sediments obtained from the nine main submarine wastewater discharge points (emissaries) presents along the coast of Tenerife Island (Canary Islands, Spain). 相似文献
949.
Assessing the feasibility of wastewater recycling and treatment efficiency of wastewater treatment units 总被引:1,自引:0,他引:1
Wastewater reuse can significantly reduce environmental pollution and save the water sources. The study selected Cheng-Ching
Lake water treatment plant in southern Taiwan to discuss the feasibility of wastewater recycling and treatment efficiency
of wastewater treatment units. The treatment units of this plant include wastewater basin, sedimentation basin, sludge thickener
and sludge dewatering facility. In this study, the treatment efficiency of SS and turbidity were 48.35–99.68% and 24.15–99.36%,
respectively, showing the significant removal efficiency of the wastewater process. However, the removal efficiencies of NH3–N, total organic carbon (TOC) and chemical oxygen demand (COD) are limited by wastewater treatment processes. Because NH3–N, TOC and COD of the mixing supernatant and raw water are regulated raw water quality standards, supernatant reuse is feasible
and workable during wastewater processes at this plant. Overall, analytical results indicated that supernatant reuse is feasible. 相似文献
950.
固相萃取-高效液相色谱法测定饮用水中酚类化合物 总被引:2,自引:0,他引:2
采用固相萃取-高效液相色谱法测定饮用水中酚类化合物,优化了试验条件。方法在0 mg/L~40.0 mg/L范围内线性良好,14种酚类化合物的检出限为0.6μg/L~2.6μg/L,水样平行测定的RSD为0.2%~2.7%,加标回收率为96.3%~99.9%。 相似文献