浅谈我国环境标准在环境管理中的作用

简述了我国环境标准的现状,体系和分类,分析了环境标准在环境管理中的作用。指出环境标准是制定环境规划的重要依据;是各级环保部门行使管理职能的基本依据;是企业污染治理是否达标的限定值;是推动环保科技进步的动力;是环境评价的准绳;是开展环境保护工作的基础;是环境保护法规的重要组成部分;具有投资导向作用。     

重铬酸钾法测定水中化学需氧量的不确定度评定

力求全面分析重铬酸钾法测定水中化学需氧量测量不确定度的来源,并以实例演示了化学需氧量测量不确定度的评定全过程。     

亚甲基蓝分光光度法测定空气中硫化氢不确定度评定

通过对亚甲基蓝分光光度法测定环境空气中硫化氢方法中不确定度来源进行了分析,对各个分量进行详细量化,计算处该分析方法的合成不确定度,给出结果的扩展不确定度。     

生态补偿机制及模式研究进展

详细综述了生态补偿机制概念、理论基础、补偿标准、补偿模式及国内外生态补偿实践经验等方面的研究进展。发现外部性的内部化是生态补偿的关键和环境经济学基础,其核心问题包括：谁补偿谁,补偿多少以及如何补偿。通过回顾美国、欧洲发达国家与中国、拉丁美洲发展中国家在实施生态补偿过程中采取的各种措施,发现生态学与经济学理论已经逐渐融入生态补偿的研究之中。在此基础上,指出了国内生态补偿的科研和实践中有待解决的问题,最后提出了包括补偿的法律机制、补偿经济标准、政策制定等方面的建议。     

采用火焰原子吸收分光光度法测定水样中镍含量的不确定度评定

采用火焰原子吸收分光光度法对水样中镍的含量进行测定,分析测量过程中不确定度来源及各不确定度分量对总不确定度的影响,确定测定结果的置信区间。给出本实验室测定水样中镍含量的扩展不确定度为0．062mg／L（k=2）。     

Maximizing Returns from Payments for Water‐Based Ecosystem Services: Incorporating Externality Effects of Land Management

Given the expansion of payments for water‐based ecosystem services (PWES) worldwide, two relevant issues are as follows: (1) determination of efficient allocations of payments among land managers, and (2) how this might change when paying one manager to implement a best management practice (BMP) to enhance an ecosystem service impacts the cost‐effectiveness of BMPs considered by other land managers not currently involved in PWES. Such externalities may be negative if diminishing returns dominate, or positive if mechanisms such as “social diffusion” dominate. We analyze how a planner should optimally allocate payments, depending on whether the expected externalities are negligible, negative, or positive. We employ (1) an optimal control model to gain insights on the problem’s dynamics, and (2) stochastic dynamic programming to determine optimal funding strategies using a specific application. The study contributes to the literature by identifying dynamically optimal PWES payment patterns, and illustrates how they should change when one accounts for externalities induced by the program. Because such impacts have not been addressed previously in a rigorous way, this treatment provides useful value added for PWES design and implementation.     

Fate and transport of the β-adrenergic agonist ractopamine hydrochloride in soil–water systems

The feed additive ractopamine hydrochloride was fortified at four concentrations into batch vials containing soils that differed in both biological activity and organic matter(OM).Sampling of the liquid layer for 14 days demonstrated that ractopamine rapidly dissipated from the liquid layer. Less than 20% of the fortified dose remained in the liquid layer after 4 hr,and recoveries of dosed ractopamine ranged from 8 to 18% in the liquid layer at 336 hr. Sorption to soil was the major fate for ractopamine in soil:water systems, i.e., 42%–51% of the dose at14 days. The major portion of the sorbed fraction was comprised of non-extractables; a smaller fraction of the sorbed dose was extracted into water and acetone, portions which would be potentially mobile in the environment. Partitioning coefficients for all soils suggested strong sorption of ractopamine to soil which is governed by hydrophobic interactions and cation exchange complexes within the soil OM. Ractopamine degradation was observed, but to mostly non-polar compounds which had a higher potential than ractopamine to sorb to soil. The formation of volatiles was also suggested. Therefore, despite rapid and extensive soil sorption,these studies indicated a portion of ractopamine, present in manures used to fertilize soils,may be mobile in the environment via water-borne events.     

回归模型法推导油菜田土壤Cd限值的不确定性

为研究土壤-作物迁移模型推导农田土壤环境基准的不确定性,以油菜为例,通过贵州省4种典型微酸性土壤——红壤、黄壤、石灰土和黄棕壤进行Cd盐添加的盆栽试验,除全量Cd外,选择5种有效态提取剂,分别与油菜籽w(Cd)建立土壤-作物迁移模型. 参照GB 13078—2001《饲料卫生标准》w(Cd)限值(0.5 mg/kg),采用模型预测中位值和95%预测上限进行土壤Cd限值推导并分析模型的不确定性. 结果表明:全量和各提取态Cd质量分数与油菜籽w(Cd)均能建立极显著的一元(R2为0.907~0.946)或多元(考虑pH)回归模型(R2为0.875~0.962). 5.550(以多元模型中位值推导的农田安全种植油菜的Cd限值)随pH的升高从0.93 mg/kg增至1.45 mg/kg,HNO₃提取态、HCl提取态、DTPA提取态的Cd的质量分数也分别从0.81、0.97、0.73 mg/kg升至1.39、1.79、1.66 mg/kg. 基于CaCl₂提取态Cd的一元模型对pH不敏感,SEQS₅₀不受其影响. 对所有模型而言,SEQS₅₀是SEQS₉₅(基于模型95%的预测上限推导的限值)的1.1倍左右. 其中,CaCl₂提取态Cd的SEQS₅₀和SEQS₉₅分别为0.052和0.049 mg/kg,小于福建省CaCl₂提取态Cd标准限值(0.15 mg/kg). 为降低不确定性,需要选择合适的提取剂,使用全量Cd,HNO₃、HCl或DTPA 3种提取态Cd建模时须兼顾pH的影响. 研究显示,SEQS₉₅能够降低土壤Cd限值达标而作物Cd含量超标的可能性.      

结构可靠性的概率设计法综述

摘 要：【目的】概率设计法是结构可靠性设计法的核心。【方法】结构可靠性设计法按其提出时基于的表述方式可以分为非概率设计法,概率设计法。【结果】概率设计法具备可靠高效地满足工程实际需求的能力,因而倍受研究人员青睐。【结论】综述了目前国际上结构可靠性设计法领域现有的概率设计法,讨论了具有代表性的概率设计法的形式、优缺点和适用范围,展望了概率设计法的发展趋势。     

A~2/O-MBR工艺在农村生活污水处理中的示范

A2/O-MBR工艺因其稳定的出水水质和良好的脱氮除磷效果,在我国城镇早已得到规模化应用。但在农村由于受各种条件制约,使该工艺的应用受到限制。通过A2/O-MBR工艺在四川农村地区散户的小规模示范,分析了其在污染物去除、建设、运行维护等方面的特点以及需注意的问题,为该技术在农村地区的推广应用做出积极的探索。