粉煤灰对垃圾填埋场黄土垫层的改性试验

通过击实、渗透试验得到粉煤灰改性-黄土的最佳配比为10%。对压实黄土和压实粉煤灰改性-黄土,分别用清水和渗滤液进行室内渗透试验,结果表明:渗滤液在压实粉煤灰改性黄土中的渗透系数≤1.0×10-7cm/s,在压实黄土中的渗透系数≤1.0×10-5cm/s,前者可作为填埋场防渗垫层,后者可作为填埋场防渗保护垫层。对COD、NH3-N的去除效果前者优于后者。     

工业锅炉除尘脱硫废水回用技术及设备的开发

针对工业锅炉除尘脱硫废水设计一套工业化的处理设备,并对其实际的处理性能进行考察和评价。该设备由网格絮凝+复合流沉淀+浅滤层过滤三个单元组成,设备构造合理,系统性能协调。设备正常运行时处理出水浑浊度平均值<10度,最大值<15度,出水浑浊度波动系数为1.8,浑浊度极差10.5度,水质稳定,满足回用水质要求。     

攀钢炼钢厂提钒转炉浊环水水质稳定研究

在对转炉提钒浊环水质状况进行分析化验的基础上提出了水质调整措施,实施后有效地稳定了提钒浊环水质,改善了因提钒浊环酸性水质导致的缺陷,较好地满足了生产需要。     

基于粮食安全的耕地保护区域经济补偿标准测算

论文依据耕地保护的机会成本损失和基于区域粮食安全所折算的耕地赢余或赤字量,测算出耕地保护区域间的经济补偿标准,以矫正耕地保护的外部经济损失。在不同情景模式下的测算结果表明,粮食主产区为主要的补偿对象,黑龙江省所应补偿的金额最高,可获得543.24×10⁸元/年,而东部地区大多为耕地保护外部效益补偿金的主要支付者,上海市需要支付的补偿金最多,最低也应支付421.79×10⁸元/年。为了保障区域内粮食自给,一些地区维护粮食安全的成本会较高。在耕地保护过程中应该打破传统农业自给自足的封闭循环,遵循耕地保护机会成本的区域差异和区域土地利用的比较优势,统筹区域土地利用,使耕地保护成为实现农业区域专门化,取得规模经济效益和集聚效益的手段。     

农业合作生产对华北农牧交错区水资源存量和经济效益的影响

针对华北农牧交错区错季蔬菜生产对水资源消耗的争议,通过试验和调查研究相结合的方法,研究了农业“生产－消费”合作生产背景下区域发展错季蔬菜的耗水效果及其对农民收入、水资源存量的影响。结果表明,错季蔬菜生产田间耗水量为农区粮食作物的31.3%~93.3%,而水资源价值为农区粮食作物的4.2~10.7倍;与区域内粮油作物生产相比,错季蔬菜生产少耗水330~754m³/hm²,且其水资源价值为粮油作物的4.0~13.9倍。通过实施粮－菜交换的市场农业战略,区域能用0.175~0.196m³的水交易获得外区域1 m³的水资源,并且实现了研究区用0.93hm²的菜地解决发展错季蔬菜前需要6.9~13.8hm²耕地才能解决的粮食问题。调查表明,通过高效地输出水资源,区域农民收入仅蔬菜一项比全国同期农村人均收入高出了23%。故华北农牧交错区发展错季蔬菜生产是节约和扩大本区域的水资源存量,促进农村脱贫致富、自我发展的有效途径。     

高氮渗滤液缺氧/厌氧UASB-SBR工艺低温深度脱氮

在低温条件下,采用缺氧/厌氧UASB-SBR组合工艺处理实际垃圾填埋场渗滤液.结果表明,该工艺可实现有机物和氮的同步、深度去除.在进水COD平均为11950.2mg/L,NH4+-N为982.7mg/L的条件下,出水分别为390.1mg/L和2.9mg/L,去除率分别为96.7%和99.7%.同时,缺氧UASB1反应器的最大COD负荷达到13kg/(m3×d),最大COD去除速率为12.39 kg/(m3×d),具有高效缺氧反硝化和高效厌氧降解有机物反应的双重功效, 在SBR反应器的缺氧段和缺氧UASB,反应器内获得了99%以上的反硝化率.对于冬季水温分别为14.9,14.1,13.5,11.05℃的低温条件下,SBR反应器实现了完全硝化和反硝化,出水TN分别为4.1,5.7,14.1,16.5mg/L,达到了深度脱氮的目的.此外,在上述温度范围内,温度对反硝化速率(rN)的影响大于对硝化速率 (rDN)的影响, rN/rDN比值相对恒定.     

基于稳健统计的土壤环境背景值研究及应用

使用稳健统计方法中的位置估计量和尺度估计量对我国某受到人为干扰的地下水水源地C层土壤重金属的背景值进行了研究.结果表明,稳健统计方法对样本中的异常值有较高的耐抗性,计算结果与常规方法相近,因而适用于某些人为干扰地区的土壤环境背景值研究.对该水源地背景值的计算表明,该地区C层土壤Cu,Pb,Cd,Cr,As和Hg的背景值中心分别为21.2,32.5,0.103,60.3,11.0和0.012 mg/kg,其中w(Pb),w(Cd)和w(As)高于山东省平均值. 6种重金属的阈值分别为29.0,43.7,0.143,93.5,21.0和0.080 mg/kg,均小于全国平均上限值,但其中Pb,Cr,As的阈值高于土壤环境质量一级标准. 基于该地区背景值的污染累积指数评价表明,该地区主要重金属污染物为Pb和Hg,主要污染区为污水沟渠周边,污染深度为1～3 m.      

Life-cycle assessment of a waste refinery process for enzymatic treatment of municipal solid waste

Decrease of fossil fuel dependence and resource saving has become increasingly important in recent years. From this perspective, higher recycling rates for valuable materials (e.g. metals) as well as energy recovery from waste streams could play a significant role substituting for virgin material production and saving fossil resources. This is especially important with respect to residual waste (i.e. the remains after source-separation and separate collection) which in Denmark is typically incinerated. In this paper, a life-cycle assessment and energy balance of a pilot-scale waste refinery for the enzymatic treatment of municipal solid waste (MSW) is presented. The refinery produced a liquid (liquefied organic materials and paper) and a solid fraction (non-degradable materials) from the initial waste. A number of scenarios for the energy utilization of the two outputs were assessed. Co-combustion in existing power plants and utilization of the liquid fraction for biogas production were concluded to be the most favourable options with respect to their environmental impacts (particularly global warming) and energy performance. The optimization of the energy and environmental performance of the waste refinery was mainly associated with the opportunity to decrease energy and enzyme consumption.     

Analysis of energy recovery potential using innovative technologies of waste gasification

In this paper, two alternative thermo-chemical processes for waste treatment were analysed: high temperature gasification and gasification associated to plasma process. The two processes were analysed from the thermodynamic point of view, trying to reconstruct two simplified models, using appropriate simulation tools and some support data from existing/planned plants, able to predict the energy recovery performances by process application. In order to carry out a comparative analysis, the same waste stream input was considered as input to the two models and the generated results were compared. The performances were compared with those that can be obtained from conventional combustion with energy recovery process by means of steam turbine cycle. Results are reported in terms of energy recovery performance indicators as overall energy efficiency, specific energy production per unit of mass of entering waste, primary energy source savings, specific carbon dioxide production.     

构建“水-煤-碳”体系 优化煤化工发展

分析了煤化工行业发展的现状及趋势,提出我国现代煤化工发展瓶颈主要是产业发展存在技术风险、产业发展与资源环境的矛盾突出及面临碳减排压力,并提出通过合理构建"水-煤-碳"三大约束指标体系,引导煤化工实现有序发展。