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151.
Arsenic in groundwaters of the Lower Mekong 总被引:1,自引:0,他引:1
Stanger G Truong TV Ngoc KS Luyen TV Thanh TT 《Environmental geochemistry and health》2005,27(4):341-357
Increasing incidence and awareness of arsenic in many alluvial aquifers of South-east Asia has raised concern over possible
arsenic in the Lower Mekong Basin. Here, we have undertaken new research and reviewed many previous small-scale studies to
provide a comprehensive overview of the status of arsenic in aquifers of Cambodia and the Cuu Long Delta of Vietnam. In general
natural arsenic originates from the Upper Mekong basin, rather than from the local geology, and is widespread in soils at
typical concentrations of between 8 and 16 ppm; (dry weight). Industrial and agricultural arsenic is localised and relatively
unimportant compared to the natural alluvial arsenic. Aquifers most typically contain groundwaters of no more than 10 μg L−1, although scattered anomalous areas of 10 to 30 μg L−1 are also quite common. The most serious, but possibly ephemeral arsenic anomalies, of up to 600 μg L−1, are associated with iron and organic-rich flood-plain sediments subject to very large flood-related fluctuations in water
level, resulting in transient arsenopyrite dissolution under oxidizing conditions. In general, however, high-arsenic groundwaters
result from the competing interaction between sorption and dissolution processes, in which arsenic is only released under
reducing and slightly alkaline conditions. High arsenic groundwaters are found both in shallow water-tables, and in deeper
aquifers of between 100 and 120 m depth. There is no evidence of widespread arsenicosis, but there are serious localised health-hazards,
and some risk of low-level arsenic ingestion through indirect pathways, such as through contaminated rice and aquaculture.
An almost ubiquitous presence of arsenic in soils, together with the likelihood of greatly increased groundwater extraction
in the future, will require continuing caution in water resources development throughout the region. 相似文献
152.
Acidification of groundwater in water-filled gravel pits -- a new environmental and geomedical threat 总被引:1,自引:0,他引:1
Swimmers and users of motor boats frequenting old, water-filled gravel pits in Kiiminki, Northern Finland, found in August 1993 that they were suffering from painful irritation of the eyes and that their boats had developed a finely polished surface on their aluminium hulls, evidently due to the corrosive action of the water. Subsequent measurements carried out by the water authority showed that the pH of the water in some of the pits was extremely low, reaching a value of 3.4 at its lowest. To find out the causes of the abnormally low pH values, the present authors began systematic measurements of the pH and determination of the chemical composition (Si, Al, Ca, Mg, K, Na, Fe, Mn, Cu, Pb, Ni, Cd, Cl-, NO3
-, SO4
2-) of the water in 23 gravel pits. In addition, a series of laboratory experiments was carried out to examine the interaction of water with samples of the soil and bedrock of the area to evaluate the role of this process as a possible cause of the acidification. The results show that the reaction of water with the moderately to intensively weathered sulphide and jarosite-bearing black schists, typical of the bedrock of the area, can bring about aqueous solutions similar in pH and sulphate--nitrate ratios to those found naturally in the gravel pits. The contribution of other possible mechanisms, e.g. acidic precipitation as such or combined with enhanced evaporation, the possible use of the pits as dumping sites for acidic waste or the flow or seepage of acidic peat-bog waters into the pits from the surrounding wetlands, cannot be ruled out entirely, but their contribution seems to be of minor importance. Since the concentrations of several heavy metals (notably Pb, Cd, Ni, Fe and Mn) and of sulphate and aluminium has increased in the pit water as a result of the acidification process and exceed the norms laid down in the EU Drinking Water Directive, acidification of water in gravel pits due to the oxidation of sulphides must be regarded as a new, serious environmental and geomedical threat which has so far remained poorly known or unrecognised. 相似文献
153.
运用SCI-GROW模型预测农药对地下水的污染风险 总被引:6,自引:0,他引:6
在对美国环境保护局开发的地下水暴露评价模型进行比较的基础上,选择SCI-GROW模型预测我国福建省甘蔗种植区5种常用农药对地下水的污染风险,并将模型预测结果与该地区地下水中农药的实测结果进行比较,对模型进行验证.结果表明,模型预测结果与实测结果之间具有很好的相关性,SCI-GROW模型能较好地用于我国东南沿海等地下水位较高、降水量较大、土壤砂性等地下水易受污染地区农药的筛选评价.最后,运用SCI-GROW模型预测涕灭威等17种我国常用农药对地下水的污染风险,为这些农药的科学使用提供参考. 相似文献
154.
垃圾填埋场及周边水系中汞污染调查 总被引:6,自引:0,他引:6
对上海老港垃圾填埋场渗滤液、地下水和地表径流水监测分析表明:渗滤液中的汞主要为以颗粒态汞(S-Hg)形式存在,污水处理系统可以使颗粒态汞(S-Hg)随颗粒物沉积到底泥中,但是对可溶态汞(D-Hg)去除没有明显作用;芦苇湿地可以有效地吸附和吸收渗滤液中各种形态汞,使汞浓度降到一个较低的水平;对地下水和地表水的分析结果显示,地下水基本没有受到汞污染,而地表水受到一定程度的污染。 相似文献
155.
松嫩平原含盐碱斑的重度盐化草甸土种稻脱盐过程 总被引:5,自引:0,他引:5
以松嫩平原西部内陆盐碱湿地的重度苏打盐化草甸土与盐土、碱土镶嵌形成的复区为对象,进行了种稻脱盐过程试验。在不采取化学、物理等其他措施的前提下,单纯采用种稻水洗方法,经过5年连续试验,土壤表层平均盐分质量分数由4.5%降至0.15%,水稻产量由第1年的近于零,上升到第4年的4250kg/hm^2,表明运用简单的种稻脱盐方法改良强度苏打盐化草甸土与盐土、碱土复区具有可行性。这一结果对合理利用劣质土壤资源和重建西部严重荒漠化生态景观具有指导意义。 相似文献
156.
土壤和地下水中多环芳烃生物降解研究进展 总被引:5,自引:0,他引:5
多环芳烃是一类普遍存在于环境中的难降解的危险性"三致"有机污染物。受污染的土壤和地下水中的多环芳烃,生物降解是其归宿的主要途径。研究表明,对于土壤中低分子量多环芳烃类化合物,微生物一般以唯一碳源方式代谢;而大多数细菌和真菌对四环或四环以上的多环芳烃的降解作用一般以共代谢方式开始。文章重点论述了多环芳烃的来源、降解多环芳烃的微生物、生物降解机理、影响生物降解的因素以及生物修复方法。认为今后的研究方向是高分子量多环芳烃的降解机理与降解途径,基因工程技术在多环芳烃生物降解方面的应用,以及生物表面活性剂产生的机理及其在实际处理中的应用等。 相似文献
157.
In this study two sites were selected in order to investigate groundwater contamination and spatial relationships among groundwater quality, topography, geology, landuse and pollution sources. One site is the Asan area, an agricultural district where pollution sources are scattered and which is mainly underlain by granite of Cretaceous age. The other site is the Gurogu area of Seoul city, an industrial district where an industrial complex and residential areas are located and which is mainly underlain by gneiss of Precambrian age. Groundwater samples collected from these districts were analysed for chemical constituents. An attribute value files of chemical constituents of groundwater and the spatial data layers were constructed and pollution properties were investigated to establish out spatial relationships between the groundwater constituents and pollution sources using geographic information systems (GIS).Relatively high contents of Si and HCO3
– in the groundwater from the Asan area reflect the effect of water–rock interaction whereas high contents of Cl–, NO3
– and Ca2+ in the groundwater from the Gurogu area are due to the pollution of various sources. The significant seasonal variation of SiO2, HCO2
– and Ca2+ contents, and that of Ca2+ content were observed in the Asan and the Gurogu areas, respectively. Seasonal variation of pollutants such as Cl–, NO3
– and SO4
2– was not observed in either area. Pollution over the critical level of the Korean drinking water standard has been investigated from 15 sampling sites out of 40 in the Asan area, and 33 sampling sites out of 51 in the Gurogu area. Pollution by NO3
–, Cl–, Fe2+, Mn2+, SO4
2– and Zn2+ in the groundwater from the industrial district (Gurogu area) and that of NO3
, SO4
2– and Zn2+ in the groundwater from the agricultural district (Asan area) were observed. The principal pollutant in both areas is NO3
–. Deep groundwater from the Asan area is not yet contaminated with NO3
– except for one site, but most of the shallow groundwater site occurring near the potential point sources is seriously contaminated. From the result of buffering analysis, it seems clear that factories and stock farms are the principal pollution sources in the Asan area. The groundwater from the Gurogu area has already been seriously polluted considering the fact of NO3
– contamination of deep groundwater. Chlorine pollution of shallow groundwater in the Gurogu area was also observed. Spatial relationship between pollution level and its source was clarified in this study by using GIS, which will be applicable to the effective management of groundwater quality. 相似文献
158.
159.
160.
Distribution of atrazine in a crop-soil-groundwater system at Baiyangdian Lake area in China 总被引:1,自引:0,他引:1
IntroductionAtrazine(2chloro4ethylamino6isopropylaminostriazine)isoneofthemostwidelyusedselectivepreandpostemergenceherbicidesforthecontrolofbroadleafandgrassyweeds.ThisherbicideisprimarilyusedincorncroppingsysteminNortheastandNorthofChina,andasoftentim… 相似文献