Fingerprinting and Groundwater Model Application to Evaluate Hydraulic Barrier Efficiency (Italy)

Remediation actions at contaminated sites are based on multiple numerical model scenarios considering different parameter distributions, source positions and contaminant transport paths. In some cases the excess of scenarios is due to uncertainties in the conceptual model as a result of the spread of contamination through heterogeneities in the physical system. Reduction of project hypotheses and conceptual model uncertainty is therefore needed. This result can be achieved by coupling hydrogeological investigations with environmental forensic techniques, better localization of the source and understanding of contamination history. In this respect, in the present study, compositional fingerprinting and groundwater flow modeling were applied to a former oil storage facility where, even though a hydraulic barrier had been built to stop the hydrocarbon plume, the presence of some hydrocarbons was still found in downgradient monitoring wells. The final aim was to evaluate the efficacy of the hydraulic barrier and identify of the source of pollution. Fingerprinting results indicated pollution with a gasoline-diesel mixture much altered by water washing and/or biodegradation. Comparison of seven groundwater samples collected in wells and monitoring wells was performed by analyzing the volatile fraction (BTEX) and the total ion chromatogram (TIC), focusing attention on: n-alkanes (m/z 85), alkylcyclohexanes (m/z 83), isoprenoids (m/z 113), C4-alkylbenzenes (m/z 134), C3-C6 alkylbenzenes and polycyclic aromatic hydrocarbons (PAHs). The most probable scenario was then identified by combining the results of fingerprinting with different contaminant paths obtained using the numerical model.     

浓缩液回灌出水电导率与离子浓度的灰色关联度研究

研究渗滤液浓缩液回灌出水电导率与离子浓度的关系对完善渗滤液浓缩液回灌体系具有重要的意义。采用成都某垃圾填埋场的渗滤液浓缩液,在实验室矿化垃圾填埋柱中开展了回灌实验,分别得到了回灌出水中电导率和8种离子浓度的变化规律。基于灰色关联模型,对电导率与离子浓度的灰色关联度进行了分析,结果表明,电导率与K+的关联系数最大,其次是NO-3、Na+和Cl-。因此在回灌出水中这4种离子与电导率的关联性较大、可将其作为回灌体系中优先控制的离子。     

页岩气开采水力压裂返排水中化学污染物的组成特征

伴随全球页岩气规模化开发,相关的区域环境问题引起了学界和公众的持续关注.页岩气开采与区域水资源息息相关,水力压裂不仅消耗大量水资源,而且产生返排废水,成分复杂,含数以千计的化学物质.因此,有关返排水中有机单体的相关研究越来越受关注.本文系统总结了近年来的相关文献和成果,重点论述了压裂返排水中有机污染物的来源、种类、浓度...     

Influence of compost amendment rate and level of compaction on the hydraulic functioning of soils

There has been widespread interest in using compost to improve the hydrologic functions of degraded soils at construction sites for reducing runoff and increasing infiltration. The objective of this study was to determine the effects of compost amendment rate on saturated hydraulic conductivity (K_s) and water retention in order to identify target compost rates for enhancing soil hydrologic functions. Samples were prepared with three soil textures (sandy loam, silt loam, and sandy clay loam), amended with compost at 0%, 10%, 20%, 30%, 40%, and 50%. All soils were tested at a porosity of 0.5 m³/m³, and the sandy loam was further tested at high (0.55 m³/m³) and low (0.4 m³/m³) porosities. The K_s and water retention data were then used to model infiltration with HYDRUS-1D. With increasing compost amendment rate, K_s and water retention of the mixtures generally increased at the medium porosity level, with more compost needed in heavier soils. As porosity decreased in the sandy loam soil, the amount of compost needed to improve K_s rose from 20% to 50%. Water distribution in pore fractions (gravitational, plant-available, and unavailable water) depended on texture, with only the highest compost rates increasing plant-available water in one soil. Results suggest soil texture should be taken into consideration when choosing a compost rate in order to achieve soil improvement goals. Hydrologic benefits may be limited even at a high rate of compost amendment if soil is compacted.     

污水快速渗滤处理系统水力负荷周期的设计

水力负荷周期是污水快速渗滤处理系统中最关键的运行参数。本研究在面积为８０ｍ＾２啤酒废水现场中试验中,分别得出了淹水期入渗速率递减曲线和落干期入渗速率恢复曲线,它们分别用指数方程和对数方程来表达。据此提出了一种以追了大水力负荷为目标时水力负荷周期的定量设计方法。将其应用于该次试验后得出的结果为１．７８ｄ淹水,２．７７ｄ落干。计算结果与实测结果比较表明,该方法是可行的。     

生物流化床反应器水力混合特性研究

分别以活性炭和陶粒作为载体,在无回流条件下研究了不同上升流速时,反应器的离散数D/μL和串联数N的变化规律.试验结果表明,上升流速,固体混合特性以及载体性质均对反应器离散程度产生影响.只要反应器达到一定的膨胀率,反应器的流态就比较接近完全混合型.活性炭为载体时,上升流速为0.29cm/s,膨胀率为9.5％,串联数N为2.17.说明用完全混合型反应器模拟生物流化床反应器是可行的.     

中空玻璃微珠/氮化硼填充硅橡胶复合材料的介电、导热和阻燃性能研究

为满足5G电子封装材料的性能需求,将一定量的改性中空玻璃微珠(f-HGM)和氮化硼(f-BN)添加进加成型液体硅橡胶中制备了低介电、高导热且阻燃的硅橡胶复合材料。测试结果表明,添加了10份f-HGM和15份f-BN的复合材料的介电常数为2.68,介电损耗为0.008 16,显著低于纯硅橡胶,热导率为0.518 W/m·K,是纯硅橡胶的2.25倍。此外,复合材料的热稳定性得到了提升,pHRR和THR分别下降了55.3%和37.7%。通过气相和凝聚相分析发现,复合材料的气相热解产物浓度大幅降低,残炭的致密性和连续性得到显著提升。     

唐古拉冬克玛底冰川流域pH值和电导率分析

2005-05-11～2005-09-27,在青藏高原唐古拉段冬克玛底冰川流域对融水径流和草地径流分别进行采样.对样品的pH值和电导率进行了分析.结果表明,研究区环境受人类活动影响很小.借助电导率水量来源模型对冬克玛底河流量进行划分,暖季径流主要以冰川冰融水补给为主,占总流量的62%以上,其次是积雪融水和降雨补给,其中,第1、3阶段的积雪融水补给分别占31%和37%,第2阶段的降雨补给占17%左右;土壤冻结水消融对径流贡献很小,占2%以下.     

中小型肉类加工企业污水处理工程的设计和运行

列举了肉类加工行业的几种常见污水处理工艺,并对各种工艺的优缺点进行了详细分析.以一个肉类加工污水处理的实际工程为例,进行详细的工艺单元设计和工程运行问题分析.案例主工艺为水力筛脱毛、预沉隔油、预曝调节、折板厌氧池、接触氧化池、沉淀,工程投资为1　525元/t,污水处理成本为0.592元/t,系统出水可以稳定达到行业相关标准(一级).      

新型移动床生物膜反应器水力特性的研究

新型移动床生物膜反应器是在普通移动床生物膜反应器中引入导流板,使填料在全池循环移动,消除了普遍移动床生物膜的死角问题,改进了它的结构和运行方式,提高了反应器的效能。通过清水实验对反应器的水力特性进行了研究,确定了反应器构造、填料填充比,考察了曝气充氧性能,研究结果认为该反应器内的水流状态大致符合理想全混合反应器的流态,并具有较好的节能效果。