首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   470篇
  免费   37篇
  国内免费   232篇
安全科学   7篇
废物处理   16篇
环保管理   44篇
综合类   309篇
基础理论   187篇
污染及防治   96篇
评价与监测   39篇
社会与环境   28篇
灾害及防治   13篇
  2024年   1篇
  2023年   7篇
  2022年   16篇
  2021年   11篇
  2020年   11篇
  2019年   15篇
  2018年   20篇
  2017年   22篇
  2016年   17篇
  2015年   28篇
  2014年   28篇
  2013年   58篇
  2012年   34篇
  2011年   48篇
  2010年   33篇
  2009年   36篇
  2008年   41篇
  2007年   56篇
  2006年   37篇
  2005年   32篇
  2004年   21篇
  2003年   27篇
  2002年   20篇
  2001年   19篇
  2000年   24篇
  1999年   8篇
  1998年   15篇
  1997年   11篇
  1996年   11篇
  1995年   4篇
  1994年   7篇
  1993年   5篇
  1992年   5篇
  1991年   2篇
  1990年   2篇
  1989年   1篇
  1987年   1篇
  1983年   1篇
  1980年   2篇
  1979年   1篇
  1972年   1篇
排序方式: 共有739条查询结果,搜索用时 218 毫秒
591.
南方高产茶园土壤养分特性   总被引:1,自引:0,他引:1  
本文对南方高产获园土壤养分特性进行研究.结果表明,高产茶园土壤表层碱解N100.3mg/kg、全N1.38g/kg.有机质31.0g/kg,均按丰富;茶叶产量与上壤碱解N呈显著正相关.由于重施磷肥,磷素在土壤中趋于积累.土壤表层全磷含量比相应的荒地土壤平均高0.47g/kg.由于少施钾肥.老茶园土壤比荒地土壤全钾含量明显下降,下降率最高达30.25%,平均达25.60%.高产茶园土壤具有独特的熟化层(20-40cm).红壤茶园土壤肥力最高,赤红壤和砖红壤茶园相近.根据研究结果,建议采用‘控氮、降磷、增钾”的施肥原则.  相似文献   
592.
裂隙是孔隙的一类。文章利用土壤切片的数字图像,采用目视分离的方法,比较研究了裂隙与其它类型的孔隙在结构上的差异、选择的土样研究结果表明,目视分离裂隙的方法是可行的,土体中的裂隙直径分布曲线是不规则的,而其它类型的孔隙直径分布曲线则类似对数正态分布;土壤总孔隙中直径较大的部分主要由裂隙构成,直径较小的部分则由其它类型孔隙和裂隙共同构成;土壤表面裂隙与土体内部裂隙在结构上可能具有一定差异。  相似文献   
593.
Two primary lead smelters and one secondary lead smelter have been active in the Socorro, New Mexico (USA) area in the last 110 years: the Billing smelter from 1883 to 1894, the Cuba Road smelter from 1881 to 1900, and Cal West from 1979 to 1984. Samples of plants and surface soil under each plant from all three sites were analysed for lead. The plants consisted of sparse grasses, cacti, creosote bush, snakeweed, mesquite and fourwing saltbush. Lead levels in the plants increased (2-440 g g–1) as the lead in the alkaline soils (25-10000 ng g–1) increased. However, the BAC (biological absorption coefficient), which is the ratio of lead content in the plant to the lead content in the soil, a measure of relative accumulation, decreased by one to two orders of magnitude, except for grasses and snakeweed. At background lead levels, there was little difference between lead in rootsversus foliage. At high lead levels, there was higher lead in roots versus foliage at the Billing and Cuba Road sites. The reverse was noted at Cal West. Because this is a recent operation, the higher lead in foliage may be due to foliar uptake. Plant growth at all sites appeared healthy.  相似文献   
594.
Phosphorus-enriched agriculture runoff is believed to be the leading cause of ecosystem changes of Everglades wetlands. To study this effect, it is necessary to estimate the area of the affected region. In this study, Bayesian kriging and universal kriging were used to estimate the area by analysing the data collected by Reddy et al. (1991). The background level of the soil's total phosphorus concentration is usedto determine whether the region is affected by the agriculture runoff, through an indicator function. The area of the affected region was represented by the integration of the indicator function over the entire wetland. The expected value of the affected area was calculated using the results derived from Bayesian and universal kriging. The outcome indicates that universal kriging is sensitive to specification of thecovariance model. It was observed that universal kriging and Bayesian kriging yield comparable results, if the specified covariance structures are of similar nature.  相似文献   
595.
土壤理化特性对稻田CH4排放的影响   总被引:8,自引:1,他引:8  
为了研究土壤理化特性对稻田CH4 排放的影响 ,室外盆栽试验于 2 0 0 0年水稻生长季在南京农业大学实施 ,1 8个供试水稻土分别取自江苏宜兴、江宁、六合、仪征及宝应等地 .所有供试土壤的季节性CH4 平均排放通量为 6 42± 2 70mg·(m2 ·h) - 1,最低和最高值分别为 1 96mg·(m2 ·h) - 1和 1 1 0 6mg·(m2 ·h) - 1,两者相差约 5 6倍 .单相关分析结果表明 :影响CH4 排放的主要土壤参数为质地、氮素状况及铜含量 .CH4 排放与土壤砂粒含量呈正相关 (r =0 5 2 8,p =0 0 2 4) ,与粘粒含量呈负相关 (r =-0 484,p =0 0 42 ) .氮素含量高的土壤CH4 排放较低 ,CH4 排放与土壤全氮、速效氮和铵态氮含量的线性相关系数分别为 -0 449(p =0 0 62 )、-0 61 1 (p =0 0 0 7)和 -0 649(p =0 0 0 4) .土壤铜含量直接影响CH4 的排放 ,CH4 排放与有效态铜和全铜含量的线性相关系数分别为 -0 5 94(p =0 0 0 9)和 -0 5 47(p =0 0 1 9) .本研究并未观测到CH4 排放与土壤有机碳含量有相关关系 ,这与前人报道的实验室培养测定结果及稻田CH4 排放随土壤有机质含量提高而增加的假设完全不同 .逐步回归分析表明 ,不同土壤间CH4 排放的变异性有 75 5 %可由土壤有效态铜含量、镁 (全量 )含量及有效铁含量与全量铁之  相似文献   
596.
Agricultural sources of atmospheric methane include flooded rice (Oryza sativa L.) paddies. However, certain soil nutrient management and cultural practices offer opportunities to reduce methane emissions. The effect of application of ammonium thiosulphate, a potential source of nitrogen and sulphur and also an inhibitor of nitrification and urease on methane production and emission from flooded alluvial (Typic Haplaquept) rice soil in India, was examined. Methane production and emission from control and urea-amended soil samples were almost identical. Application of ammonium thiosulphate to laboratory-incubated flooded soil (30 and 60 μg N g−1 soil) and flooded rice fields (45.6 and 60 kg N ha−1) effected a distinct inhibition of methane production and emission. Ammonium thiosulphate stimulated the population of sulphate-reducing bacteria (SRB) to a greater extent at 60 μg N g−1 soil than at 30 μg N g−1 soil. In ammonium thiosulphate-applied rice field plots, mean methane efflux decreased by about 38 and 60% at 45.6 and 60 kg N ha−1, respectively, over that of control. Inhibition of methane production by ammonium thiosulphate is, at least in part, due to the stimulation of SRB. Results suggest the mitigation potential of ammonium thiosulphate on methane emission from flooded rice paddies.  相似文献   
597.
Miretzky P  Bisinoti MC  Jardim WF 《Chemosphere》2005,60(11):1583-1589
The sorption of Hg (II) onto four different types of Amazon soils from the A-horizon was investigated by means of column experiments under saturation conditions and controlled metal load. Higher organic matter contents in the soil resulted in higher Hg (II) adsorptions, reaching values as high as 3.8 mg Hg g−1 soil. The amount of mercury adsorbed on a soil column (Q) shows a very poor correlation with soil clay content (r2 = 0.2527), indicating that Hg sorption in these topsoil samples is chiefly governed by the organic matter content. Desorption experiments using Negro River (Amazon) waters were conducted using soil saturated with Hg (II) in order to better understand the metal leaching mechanism. The amount of Hg (II) released from soils was around 30% of the total sorbed mercury upon saturation, suggesting that mercury sorption in the soils present in the catchment area of the Negro River basin is not a reversible process.  相似文献   
598.
Pyrene and phenanthrene degradation was examined in both single and binary slurry systems for three different natural soils. It was found that the amount of total expandable clays (smectite and vermiculite) was in a good agreement with the achieved rate and extent of biodegradation. For instance, the intrinsic phenanthrene biodegradation rate was 626 microg/L/day for the soil with the largest expandable clay and 3203 microg/L/day for the soil with the least. Similarly, the smallest total pyrene biodegradation (65%) was found for the soil rich in expandable clays, compared to an 82% pyrene reduction in the soil that had the lowest amount. Mass transfer limitation after compound sorption to the clays was more pronounced for the more hydrophobic pyrene. In the presence of phenanthrene, total pyrene biodegradation increased by 2 to 7% due to cometabolism, while the total phenanthrene biodegradation was only enhanced by 0.5 to 5% in the binary system. This research demonstrated that expandable clays might govern the substrate availability to microorganisms and microbial accessibility to substrates. Therefore, the contribution of organic matter and expandable clays to sorption, desorption and biodegradation should be taken equally into account in order to better understand complex bioremediation issues.  相似文献   
599.
The method used to produce a critical load map of acidity for soils in Great Britain is described. Critical loads were assigned to the dominant soil in each 1 km grid square of the UK national grid. Mineral soils were assigned a critical load based on mineralogy and chemistry, using approaches appropriate to UK conditions. Critical loads for peat soils are based primarily on a maximum acceptable reduction of peat pH, and results from laboratory equilibration studies. The map shows that soils with small critical loads (<0.5 kmolc ha−1 year−1) i.e. highly sensitive to acidic deposition, dominate in the north and west of Britain; the south and east are dominated by soils with large critical loads, with small areas of more sensitive soils associated with sandy soil-forming materials. A modified critical load map illustrates the potential impact of agricultural liming on soil critical loads.  相似文献   
600.
Copper adsorption by vineyard soils of the Geneva canton was evaluated by batch equilibration experiments in a pH range from 4 to 6. The adsorption curves fit significantly to Freundlich function log q = n log C + log Kf, where q is adsorbed Cu concentration on the solid phase and C is solution Cu concentration at the end of the equilibration time. Moreover, we found that Freundlich parameters n and log Kf are moderately correlated to pH, yielding the following equations: log Kf = 0.23 pH + 0.51 (R 2 0.59) and n = –0.12 pH + 1.06 (R 2 0.59). Such equations may be useful to predict Cu mobility for risk assessment studies.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号