首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2126篇
  免费   245篇
  国内免费   670篇
安全科学   74篇
废物处理   35篇
环保管理   249篇
综合类   1111篇
基础理论   1144篇
污染及防治   179篇
评价与监测   77篇
社会与环境   162篇
灾害及防治   10篇
  2024年   8篇
  2023年   61篇
  2022年   105篇
  2021年   107篇
  2020年   137篇
  2019年   100篇
  2018年   88篇
  2017年   105篇
  2016年   115篇
  2015年   141篇
  2014年   123篇
  2013年   186篇
  2012年   163篇
  2011年   196篇
  2010年   148篇
  2009年   146篇
  2008年   142篇
  2007年   182篇
  2006年   118篇
  2005年   119篇
  2004年   88篇
  2003年   77篇
  2002年   56篇
  2001年   46篇
  2000年   47篇
  1999年   32篇
  1998年   31篇
  1997年   30篇
  1996年   30篇
  1995年   22篇
  1994年   21篇
  1993年   17篇
  1992年   12篇
  1991年   6篇
  1990年   7篇
  1989年   4篇
  1988年   4篇
  1987年   4篇
  1986年   5篇
  1984年   6篇
  1982年   2篇
  1981年   1篇
  1976年   1篇
  1973年   1篇
  1972年   1篇
排序方式: 共有3041条查询结果,搜索用时 31 毫秒
241.
The ecotypic structure of two grayling species in Eurasia is considered. Based on original and published data, the development of ecological forms in water bodies of different kinds is analyzed. Parallelism in the emergence of highly similar forms in different sites of the ranges is demonstrated. Distinctive features of ecotypes and their internal structure are described. The causes and rate of establishment of forms with a short life cycle are discussed.  相似文献   
242.
Abstract: Anthropogenic disturbances such as fragmentation are rapidly altering biodiversity, yet a lack of attention to species traits and abundance patterns has made the results of most studies difficult to generalize. We determined traits of extinction‐prone species and present a novel strategy for classifying species according to their population‐level response to a gradient of disturbance intensity. We examined the effects of forest fragmentation on dung beetle communities in an archipelago of 33 islands recently created by flooding in Venezuela. Species richness, density, and biomass all declined sharply with decreasing island area and increasing island isolation. Species richness was highly nested, indicating that local extinctions occurred nonrandomly. The most sensitive dung beetle species appeared to require at least 85 ha of forest, more than many large vertebrates. Extinction‐prone species were either large‐bodied, forest specialists, or uncommon. These explanatory variables were unrelated, suggesting at least 3 underlying causes of extirpation. Large species showed high wing loading (body mass/wing area) and a distinct flight strategy that may increase their area requirements. Although forest specificity made most species sensitive to fragmentation, a few persistent habitat generalists dispersed across the matrix. Density functions classified species into 4 response groups on the basis of their change in density with decreasing species richness. Sensitive and persistent species both declined with increasing fragmentation intensity, but persistent species occurred on more islands, which may be due to their higher baseline densities. Compensatory species increased in abundance following the initial loss of sensitive species, but rapidly declined with increasing fragmentation. Supertramp species (widespread habitat generalists) may be poor competitors but strong dispersers; their abundance peaked following the decline of the other 3 groups. Nevertheless, even the least sensitive species were extirpated or rare on the smallest and most isolated islands.  相似文献   
243.
Abstract:  Effective detection of population trend is crucial for managing threatened species. Little theory exists, however, to assist managers in choosing the most cost-effective monitoring techniques for diagnosing trend. We present a framework for determining the optimal monitoring strategy by simulating a manager collecting data on a declining species, the Chestnut-rumped Hylacola ( Hylacola pyrrhopygia parkeri ), to determine whether the species should be listed under the IUCN (World Conservation Union) Red List. We compared the efficiencies of two strategies for detecting trend, abundance, and presence–absence surveys, under financial constraints. One might expect the abundance surveys to be superior under all circumstances because more information is collected at each site. Nevertheless, the presence–absence data can be collected at more sites because the surveyor is not obliged to spend a fixed amount of time at each site. The optimal strategy for monitoring was very dependent on the budget available. Under some circumstances, presence–absence surveys outperformed abundance surveys for diagnosing the IUCN Red List categories cost-effectively. Abundance surveys were best if the species was expected to be recorded more than 16 times/year; otherwise, presence–absence surveys were best. The relationship between the strategies we investigated is likely to be relevant for many comparisons of presence–absence or abundance data. Managers of any cryptic or low-density species who hope to maximize their success of estimating trend should find an application for our results.  相似文献   
244.
四环素类抗生素对不同蔬菜生长的影响及其富集转运特征   总被引:11,自引:5,他引:6  
本研究探讨了四环素类抗生素(TCs)对两种蔬菜生长的影响及其在蔬菜体内的富集和转运特征,以期为四环素类抗生素的植物毒性和对人体健康的风险评价提供理论基础.采用土培试验研究了不同水平(0、50和150 mg·kg-1)的四环素类抗生素(四环素TC、土霉素OTC、金霉素CTC)对生菜和小白菜生长、抗生素含量及其富集转运特征的影响.结果表明,TCs总体上抑制了生菜的生长,地上部和地下部鲜重分别较CK降低了1.56%~26.84%和17.36%~51.04%,小白菜地上部和地下部鲜重反而较对照提高了3.7%~7.3%和3.1%~82.2%.TCs在一定程度上增加了生菜和小白菜的气孔导度(Gs)和蒸腾速率(Tr),抑制了生菜的净光合速率(Pn),Pn在TCs为150 mg·kg-1时较CK降低了32.43%~82.43%.TCs还抑制了生菜和小白菜的SOD活性,较CK降低了29.17%~223.12%,以OTC的抑制作用最强.生菜和小白菜的MDA含量在TCs为150mg·kg-1时达到最大值(生菜地上部除外).小白菜地上部和地下部TCs的含量均高于生菜,以CTC处理的小白菜和生菜TCs含量较高.种植生菜的土壤TCs残留量高于小白菜土壤,以OTC处理的土壤TCs残留量最高.小白菜对TCs的富集系数和转运系数分别是生菜的1.07~7.35倍和1.15~2.25倍.3种四环素类抗生素中以OTC和CTC的生态风险较大.  相似文献   
245.
为探讨共生细菌对盐生小球藻(Chlorella salina)亚砷酸盐(As(III))富集和形态转化的影响,从C.salina培养液中分离培养出一株共生细菌,并采用抗生素处理C.salina获得无菌藻,设置0,75,150,300,750 μg/LAs(III)溶液处理带菌和无菌的C.salina,7d后测定C.salina对As(III)的吸收、吸附和富集量,以及培养液和藻细胞内As的形态,计算带菌和无菌C.salina对As(III)的氧化率和去除率;使用不同浓度的As(III)处理共生细菌7d,并以300μg/L的As(III)处理共生细菌不同时间,计算两种情况下共生细菌对培养液中As(III)的氧化率和去除率.结果表明:C.salina的共生细菌为根癌农杆菌(Agrobacterium tumefaciens WB-1);与无菌C.salina相比,带菌C.salina生长更快、对As(III)的耐性更强.带菌C.salina对As(III)的富集量为103.10~448.12mg/kg、氧化率为78.93%~96.88%、去除率为18.92%~55.21%,显著高于无菌C.salina的富集量(11.68~91.39mg/kg)、氧化率(14.46%~26.39%)和去除率(12.82%~29.15%),也高于A.tumefaciens WB-1对As(III)的氧化率(4.51%~30.61%)和去除率(1.86%~16.19%).此外,带菌C.salina胞内还检测到少量的As(III)和甲基砷,而在无菌C.salina胞内没有甲基砷存在.共生细菌促进了盐生小球藻对As(III)的富集和形态转化.  相似文献   
246.
刘平养  李东轩 《中国环境科学》2019,39(11):4921-4928
电子商务在农村农业领域的快速发展带动了农民收入的增加,但是其作用路径和环境效应有待检验.以上海市青浦区为典型案例,利用264份新型农业经营主体的问卷调查数据,采用IV-ordered Probit模型和夏普利值分解法,研究了"电子商务+农业"模式的经济效应和环境效应.结果表明:电子商务的引入具有显著的农民增收效应,但主要以产量扩大型传导机制为主,反而加剧了农业生产的环境负效应.电子商务并非农民增收的关键因素,其贡献率仅为12%;发挥决定性作用的是新技术、新方法的应用带来的效率提升,以及生产规模扩大带来的规模经济效应,相应的夏普利分解贡献了达到31%和25%.这表明当前的"电子商务+农业"模式仍处于初级发展阶段,需要加强相应的规制和引导,实现从产量驱动阶段向质量驱动阶段转型.  相似文献   
247.
Low organic matter content and high heavy metal levels severely inhibit the anaerobic digestion (AD) of sewage sludge. In this study, the effect of added manganese oxide-modified biochar composite (MBC) on methane production and heavy metal fractionation during sewage sludge AD was examined. The MBC could increase the buffering capacity, enhance the methane production and degradation of intermediate acids, buffer the pH of the culture, and stabilize the sewage sludge AD process. The application of MBC positively impacted methane production and the cumulative methane yield increased up to 121.97%, as compared with the control. The MBC addition can improve metal stabilization in the digestate. An optimum MBC dose of 2.36?g was recommended, which would produce up to 121.1?L/kg volatile solids of methane. After the AD process, even though most of the metals accumulated in the residual solids, they could be transformation from the bio-available fractions to a more stable fraction. The total organic- and sulfide-bound and residual fraction content at a 3?g dose of MBC that is 0.12?g/g dry matter were 51.06% and 35.11% higher than the control, respectively. The results indicated that the application of MBC could improve the performance of AD and promote stabilization of heavy metals in sewage sludge post the AD process.  相似文献   
248.
中国土地市场对城乡融合发展的影响   总被引:9,自引:2,他引:7  
城乡融合发展是实现乡村振兴与推进新型城镇化建设的关键举措,土地市场则是实现城乡要素流通的重要渠道,也是连接城乡发展的关键纽带。本文阐释了城乡融合发展的科学内涵与本质特征,探究了土地市场对城乡融合发展的作用机理,在此基础上,量化分析了中国273个地级及以上行政单元土地市场与城乡融合发展的演进规律,并运用面板数据模型对土地市场与城乡融合关系进行了实证检验,以期从土地市场视角为城乡融合发展提供一条可实现路径。结论如下:(1)城乡融合发展是城乡价值重塑的过程,旨在消除阻碍城乡发展的因素,推动城乡要素自由流动与平等交换,实现城乡发展要素回报趋同,本质是通过城乡互动互补实现城乡地域功能的整体优化。(2)土地市场对城乡融合的作用是利弊双轨的权衡,作用方向取决于土地市场是否是良性市场。城乡二元分配体制与社会融入受阻背景下,扭曲土地市场掣肘城乡融合发展。(3)2005-2013年中国土地市场稳步发展,城乡融合发展水平略低,土地市场规模、土地市场价格与土地市场化程度分别提升113.66%、274.09%与37.07%,59.34%城市的城乡融合发展水平下滑,二者反差明显,且均具时空分异特征。(4)现阶段,土地市场对城乡融合发展更多体现为滞碍作用,但土地市场对城乡融合存在“低水平陷阱”,突破88.64%的抑制拐点,即可发挥土地市场对城乡融合的促进作用。重塑土地市场发展价值取向,加快推进土地市场化改革,探索人口—土地挂钩机制是后续工作的重要方向。  相似文献   
249.
分析讨论了安徽铜陵水木冲S和SP剖面尾矿砂的理化指标、硫形态变化和硫酸根硫同位素组成与分布特征.结果显示:S和SP剖面整体呈酸性,pH值为2.59~6.12和3.50~6.27,由下而上有明显的降低趋势;Eh随剖面由下至上明显升高,范围为66~457和-37~307mV;酸可挥发性硫(AVS)含量为0~62.36和0~3.44mg/g,黄铁矿硫(CRS)含量为0.70~32.30mg/g和0.17~5.39mg/g;AVS与CRS的变化趋势基本一致,随剖面自下而上减少,且AVS先于CRS被氧化.2个剖面元素硫(ES)含量为0~8.83和0~3.62mg/g,随深度变化无明显规律.硫酸根硫(SO42--S)含量为8.44~66.34和8.48~29.87mg/g,自下而上呈降低趋势,且分别在剖面的氢氧化物薄膜层(11.5~16.5cm和18~54cm)出现高值区.2个剖面总硫(TS)含量为9.18~109.69和12.38~37.72mg/g,表层由于淋滤含量较低,底层变化则不大.位于斜坡上的SP剖面TS及各形态硫含量均低于S剖面,表明淋滤对硫含量影响更明显.硫酸根硫同位素δ34S为-3.32‰~13.43‰和-3.08‰~1.80‰,S-9硫酸根δ34S为13.43‰,指示其来自于伴生硬石膏,其余层位δ34S偏负且变幅较小,指示其硫酸根主要来源于硫化物的氧化.  相似文献   
250.
CuFe-SSZ-13 catalyst showed excellent performance in the selective catalytic reduction of NOx with NH3 (NH3-SCR) for diesel engine exhaust purification. To investigate the effect of preparation methods on NH3-SCR performance, Fe was loaded into one-pot synthesized Cu-SSZ-13 catalysts through solid-state ion-exchange (SSIE), homogeneous deposition precipitation (HDP) and liquid ion-exchange (IE), respectively. Three CuFe-SSZ-13 catalysts showed similar SO2 resistance, which was better than that of Cu-SSZ-13. The improvement was attributed to the protection of Fe species. Hydrothermal stability of three CuFe-SSZ-13 catalysts was significantly different, which was attributed to the state of active species caused by different preparation methods. Compared with the other two catalysts, more active species existed inside the zeolite pores of CuFe-SSZ-13SSIE. During hydrothermal aging, the aggregation of these active species in the pores caused the collapse of catalyst structure, ultimately leading to the deactivation of CuFe-SSZ-13SSIE. In contrast, Fe species was dispersed better on the surface over CuFe-SSZ-13IE, enhancing the hydrothermal stability of catalysts. Consequently, Fe loading effectively improved the resistance of SO2 and H2O over Cu-SSZ-13. For CuFe-SSZ-13, large amounts of active species located inside the zeolite pores are not beneficial for the hydrothermal stability.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号