TiO2,ZnO光催化降解庚烷的活性研究

采用XRD，SPS，XPS，BET技术对TiO2和ZnO超细粉进行了结构、性能测试、考察了不同粒径的超细粉和普通商品（体相）TiO2、ZnO对庚烷的气相光催化反应，结果表明，TiO2（锐钛矿型）光催化活性大于ZnO，锐钛矿型TiO2光催化活性较金红石型TiO2好，对于同一结构的粒子来说，粒径愈小，表面羟基含量愈高，光催化活性愈高，通过反应产物的分析，探讨了反应机理。     

绿化树种对大气SO2、铅复合污染的反应

依据植物对大气污染的反应方式来选择城市绿化树种是减轻大气污染物的重要途径和手段。通过观察污染地区绿化树种叶片的受害症状来判断植物对SO2、铅复合污染物的抗性程度，根据植物对SO2、铅复合污染物的反应特性划分植物对大气污染物的抗性等级，从而筛选出对SO2、铅复合污染物的抗性植物种类和敏感监测植物种类。研究结果表明：抗性树种有：花曲柳、桑树、皂角、山桃、黄檗、臭椿、紫丁香、忍冬、柽柳、桧柏、枸杞、水蜡、刺槐、色赤杨、加拿大杨、黄刺枚、玫瑰、白榆、茶条槭；敏感监测树种有：连翘、榆叶梅、锦带花、风箱果、云杉、油松、樟子松、山槐。     

Size distribution in ultraphytoplankton: A comparative analysis of counting methods

Water samples taken at three depth layers from the offshore oligotrophic Cretan Sea were analyzed for ultraphytoplankton size fractionation using different methods: (a) sequential filtration on filters of pore size 5, 1 and 0.2 m, (b) separate filtration using filters 5 and 0.2 m as well as 1 and 0.2 m and (c) direct filtration on 0.2 m filters after staining of the samples with DAPI. Total abundance of photosynthetic organisms as well as the abundance of different groups such as flagellates and cyanobacteria measured by means of sizing after DAPI staining were significantly higher than those obtained by the other methods. This indicates that although there were no significant differences between the estimates provided by the separate and sequential filtration, both these methods underestimated total abundance by at least 25–50%. The estimates for the size fractions were also found to range from relatively imprecise to completely unreliable depending on the group and the size range. Although size fractionation through direct observation after staining largely depends on the expertise of the observer, this study suggests that it may provide more informative estimates than the other two methods. Although it is difficult to generalize the results of this study in a global context, the paper provides strong indications on the limitations of the sequential and separate methods for size fractionation of photosynthetic organisms and implies that their results are likely to be less accurate than is presently believed.     

Mechanochemical removal of organo-chlorinated compounds by inorganic components of soil

The purpose of this work is to evaluate the catalytic efficiency of two metal oxides, ferrihydrite and birnessite and of a ferruginous smectite, towards organic molecules such as 4-chloroaniline (4-CA), pentachlorophenol (PCP), and five polychlorinated biphenyls (PCBs) characterised by different number and position of chlorine atoms. Mechanochemical dry contacts with light grinding between catalytic surfaces and pollutants have been carried out.

The efficiency of the mechanochemical removal was compared with batch experiments for the soluble compounds (PCP and 4-CA). The removal of 4-CA and PCP by the mechanochemical procedure resulted more effective than by batch contact in the presence of birnessite and ferrihydrite, particularly at higher pH (100% removal of 4-CA by birnessite in 30 min at pH 8.6 after the mechanochemical contact compared to 20% removal using the batch interaction at the same pH).

The mechanochemical contact of PCBs and birnessite produced a removal of pollutant that was a function of the number of chlorine atoms (complete removal of 2,2^′-dichlorobiphenyl in 10 days and a removal of 30% and 20% of 2^′,3,4-trichlorobiphenyl and 3,3^′,4,4^′-tetrachlorobiphenyl, respectively in 90 days) and of the position of chlorine atoms about the biphenyl rings (100% of 2,2^′-dichlorobiphenyl in 10 days, 84% of 3,3^′-dichlorobiphenyl in 15 days and 40% of 4,4^′-dichlorobiphenyl in 27 days).     

A study into the parameters affecting selected reaction monitoring of 2,3,7,8-TCDD

The use of high resolution (10,000 resolving power) coupled gas chromatography - mass spectrometry is a well established technique in the analysis of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) but in the case of heavily contaminated stack samples interferences can still occur. A complementary technique that offers high specificity is selected reaction monitoring (SRM).A study has been made into the effects that affect the metastable dissociation of 2,3,7,8-TCDD in the first field free region (FFR1) of a magnetic sector mass spectrometer, and monitored using SRM.Monatomic, diatomic and polyatomic gases have been investigated in the collision chamber of the mass spectrometer, as have the effects of electron energy, source temperature and trap current on the dissociation, and optima conditions determined for them.     

汞的超高灵敏显色反应及其应用

对Ｈｇ（Ⅱ）－ｍｅｓｏ－４－（４－ＴＭＡＰ）Ｐ－ＤＤＭＡＡ－Ｔｗｅｅｎ８０超高灵敏显色体系的特性进行了研究。该显色体系在ＰＨ８．５～１０．５的硼酸－氢氧化钠介质最为适宜，显色体系最大吸收波长为４５０ｎｍ处，摩尔吸光系数ε４５０＝４．８×１０＾５Ｌ／ｍｏｌ．ｃｍ，试剂空白在４５０ｎｍ处时等于零。在ＤＤＭＡＡ，Ｔｗｅｅｎ８０条件下，Ｈｇ＾２＋与Ｍｅｓｏ－４（４－ＴＭＡＰ）Ｐ的组成比为１：１。在０～１０     

Exclusion of β-thalassaemia by biopsy and DNA amplification in mouse pre-embryos

Exclusion of β-thalassaemia in mice was undertaken by pre-implantation DNA diagnosis. Biopsies of approximately five cells were obtained from mouse pre-embryos. DNA prepared from this material was amplified by the polymerase chain reaction (PCR), enabling identification of the normal β-major globin gene in 11 out of 20 cases where it was known to be present. The expected negative result was obtained in 14 out of 16 homozygous thalassaemic embryos, with two false positives. Results are promptly available following PCR, thereby facilitating re-implantation of embryos which have had homozygous β-thalassaemia excluded. The mouse model illustrates a useful approach to pre-implantation diagnosis of genetic disease in the human.     

造纸中段废水强氧化深度处理技术原理及应用

针对造纸废水的特点,应用水解酸化＋氧化沟生物处理＋强氧化深度处理的治理工艺对造纸中段废水进行处理。对实际运行效果的检测表明,经处理后的中段废水可达标排放,实现中段水的循环利用,具有较大的环境效益、经济效益和社会效益。     

自由基反应与理论研究

自由基反应作为一类重要的化学反应,已经得到了大量广泛的研究。本文对自由基反应的反应物、产物、中间物（INT）及过渡态（TS）的构型参数及所有驻点能量的理论研究方法进行了简单的总结,并对自由基反应在废水污染物降解方面的动力学研究进行了综述。