Distribution and change of DDT and HCH levels in oysters (Crassostrea rivularis) from coast of Guangdong,China between 2003 and 2007

This investigation was undertaken to understand the temporal trend, the spatial distribution and the residue level of dichloro-diphenyl-trichloroethanes (DDTs) and hexachlorobenzenes(HCHs) in bivalves from the coast of the South China in recent years. Jinjiang oysters (Crassostrea rivularis) were sampled from 15 bays along the coast of Guangdong province, China between 2003 and 2007. Gas chromatography with electron capture detector was used to quantify the contents of HCH isomers (α-, β-, γ-, δ-HCH), DDT isomers (p,p′-, o,p′-DDT), p,p′-DDD and p,p′-DDE in the oyster tissues. The results demonstrate that annual level of DDTs in the tissue increase throughout the study, particularly between 2004 and 2006. The DDTs content in the tissue varied significantly among sampling regions and some sampling sites (p < 0.05). On the other hand, the HCHs content was significantly lower than DDTs content in the tissue (p < 0.01), and remain constant among sampling years, sampling regions and sampling sites (p > 0.10). Predominance of isomer form of DDTs and higher ratio of γ-HCH/HCHs at some sites indicated that recent input of DDT and lindane in the coastal waters of Guangdong, which might be caused by dicofol spraying in crop planting and lacquer painting on fisher boat. In the soft tissues of the oysters, the highest content of HCHs was 1.21 ng/g (wet weight), and DDTs levels ranged from 0.11 ng/g to 76.3 ng/g (wet weight), far below the Maximum Residual Limits in China and many developed nations.     

重庆主城区大气重污染形势的激光雷达探测与分析

2013年1月12日-26日,利用大气超级站ALS300型激光雷达对重庆主城区大气进行了连续探测,分析了重污染形势期间的大气扩散条件及大气颗粒物时空分布等探测结果。分析表明,大气层结持续稳定,扩散条件差使得大气颗粒物浓度居高不下,大气能见度持续恶化;大气重污染期间PBL高度较低,平均为320～350m;大气颗粒物污染带处于100～400m高度范围;全国范围内异常的大气环流形势和重庆主城区独特的地形、气候特征是造成持续大气重污染形势的原因。     

绝缘子表面RTV憎水性与其放电的紫外成像结果关系研究

室温硫化硅橡胶(RTV)涂料在运行过程中会逐渐老化,可采用憎水性测量和理化手段分析其老化程度,但无法对运行中的绝缘子进行评估。通过涂污的方式模拟绝缘子表面RTV憎水性的减弱,对绝缘子串加压并用紫外成像仪记录放电过程,研究憎水性与紫外成像结果的关系。分析放电产生的紫外光子数和光斑面积发现,绝缘子串表面RTV憎水性越差,其发生显著放电的电压越低,相同电压下放电程度越剧烈。研究成果为运行中绝缘子RTV憎水性能的评估提供了一种新思路。     

双室微生物燃料电池型BOD传感器性能

构建了双室微生物燃料电池(MFC),并应用于污水BOD的检测。优化了MFC型BOD传感器的检测条件,分析了传感器进行污水BOD检测的特征。结果表明,以A2/O污水处理工艺中厌氧段污泥进行接种,双室MFC型BOD传感器2周内完成启动,所产电流达到稳定。传感器的最佳检测条件为外接电阻500Ω,添加缓冲溶液并维持待测水样pH为7.0,添加35 mg/L的L-半胱氨酸作为吸氧剂维持阳极室厌氧环境,阴极室富氧水流量为20 mL/min。利用MFC产生的电流峰值准确检测污水水样BOD浓度,传感器检测范围为10~50 mg/L,检测时间小于3 h;利用MFC产生的电荷量准确检测污水水样BOD浓度,检测范围为10~100 mg/L,检测时间小于10 h。利用MFC电流峰值和电荷量检测污水水样BOD浓度,偏差均小于15%,传感器运行稳定,寿命较长。     

基于关联模型的二恶英在线检测研究

为实现二恶英快速检测,指导废物焚烧炉二恶英减排,通过检测生活垃圾焚烧炉烟气中氯苯和二恶英浓度,研究了三氯苯、四氯苯和二恶英之间的关联关系,并利用实验室自行研制的飞行时间质谱仪对烟气样品的三氯苯进行在线检测。结果表明,三氯苯与二恶英毒性当量(I-TEQ)之间存在良好关联性,相关系数(R2)可达到0.89。仪器检测信号强度与三氯苯浓度之间具有良好的线性关系,根据在线检测烟气样品中三氯苯的信号可得到三氯苯浓度,并根据关联模型计算得到二恶英毒性当量值I-TEQ,实现了对烟气样品中二恶英的快速间接测量。     

Trends in Chemical Composition of Wet-only Precipitation at Rural French Monitoring Stations Over the 1990–2003 Period

The long-term monitoring of precipitation and its chemical composition are important for identifying trends in rain quality and for assessing the effectiveness of pollution control strategies. A statistical test has been used to the atmospheric concentrations measured in the French rural monitoring network (MERA) in order to bring out spatio-temporal trends in precipitation quality in France over the period 1990–2003. The non-parametric Mann–Kendall test which has been developed for detecting and estimating monotonic trends in the time series was used and applied in our study at annual values of wet-only precipitation concentrations. The emission data suggest that SO₂ and NO _x emissions decreased (−3.3 and −2.0% year⁻¹, respectively) contrary to NH₃ emissions that increased slightly (+0.2% year⁻¹) over the period 1990–2002 in France. On the national scale, the pH values have a significant decreasing trend of −0.025 ± 0.02 unit pH year⁻¹. and concentrations in precipitation have a significant decreasing trend, −3.0 ± 1.6 and −3.3 ± 0.6% year⁻¹, respectively, corresponding with the downward trends in SO₂ emissions in France (−3.3% year⁻¹). A good correlation (R ² = 0.84) between SO₂ emissions and concentrations was obtained. The decreasing trend of was more significant (−5.4 ± 5.2% year⁻¹) than that of (−1.3 ± 2.4% year⁻¹). Globally, the concentration of the major ions showed a clear downward trend including marine and alkaline ions. In addition, the relative contribution of HNO₃ to acidity precipitation increased by 51% over the studied period.     

Monitoring of the Endangered Pinna nobilis Linné, 1758 in the Mar Grande of Taranto (Ionian Sea, Italy)

Two methods were used to calculate the meteorologically adjusted ground level ozone trends in southern Taiwan. The first method utilized is a robust linear regression method. The second approach uses a multilayer perceptron (MLP) artificial neural network (ANN) method. The observations obtained from 16 monitoring stations were analyzed and divided into six groups by hierarchical divisive clustering procedure. The daily maximum 1 and 8 h ozone concentrations for each group are then calculated. The meteorologically adjusted trends obtained by linear regression and MLP methods are smaller than the unadjusted trends for all groups and average time. It indicts that the meteorological conditions in Taiwan tend to increase ambient ozone concentrations in recent years.     

基于对象的高分辨率遥感图像滑坡检测方法

滑坡遥感检测对于灾害调查和制图具有重要意义,面向对象是高分辨率遥感图像信息提取的重要思路。以高植被覆盖的热带雨林地区为例,在对试验区滑坡遥感图像特征进行分析的基础上,提出了基于对象的高分辨率遥感图像滑坡检测方法。通过多期遥感图像的多尺度、多层次分割,确定了图像对象变化检测的基本单元,构建了滑坡检测多级对象层次网络;依靠图像对象特征、上下文关系和拓扑关系等,构建了适于该实验区的滑坡检测知识规则,从而将滑坡检测整个过程包含在图像对象分析之中,并最后实现了高分辨率遥感图像的滑坡检测。实例证明,基于对象的滑坡检测方法适于热带雨林地区的信息提取,这对于其它地理环境类似地区的灾害调查与制图工作具有一定的参考价值。     

汽车辅助制动装置发展综述

平均行驶速度和载重量的增加,要求车辆具有更大的制动效能,为了有效分流制动负荷常采用辅助制动系统.介绍国内外制动法规的发展和现状,排气辅助制动装置、发动机缓速器、电涡流缓速器和液力缓速器的结构、工作原理及各辅助制动装置的制动性能;比较各辅助制动装置的优缺点,有利于汽车制动技术的发展,全面提高汽车行驶安全性能;展望未来汽车辅助制动装置的两大发展趋势,一是电子控制技术在汽车制动上的应用,二是多种辅助制动装置的联合制动.     

水中隐孢子虫的检测技术

本文着重评述了水中隐孢子虫卵囊的检测技术,具体介绍了EPA1622法和1623法、流式细胞计、荧光原位杂交、SPR生物传感器以及PCR等方法,并对其操作技术、检测周期、回收率、检测限、可靠性、敏感性、稳定性以及能否种类鉴别等方面进行了比较。笔者认为我国应致力于开展快速检测卵囊活性与传染性的研究;随着IMS、细胞分类法等纯化手段不断完善,PCR技术对研究水中隐孢子虫的检测将会有更广阔的发展空间。