基于中性盐提取的土壤重金属固液分配与自由态金属离子浓度测定

采用0.01mol·L-1CaCl2、0.002mol·L-1Ca(NO3)2和纯水(UPW)3种常用提取剂对我国南方两种典型农田重金属污染土壤进行提取试验.同时,应用土壤重金属固液分配多表面模型来预测提取液中重金属含量,结合道南膜技术(DMT)测定Ca(NO3)2提取液中自由态金属离子浓度,并与ECOSAT模型计算值进行比较.结果表明,提取剂中Ca2+浓度增加能显著提高土壤重金属溶出率,而提取液pH、溶解态有机碳(DOC)浓度却随溶液Ca2+浓度增加而降低.多表面模型(Multi-SurfaceModel)对大部分提取液金属浓度有较好的预测效果,部分土样提取液Cu、Pb、Zn浓度的预测效果较差.DMT测定的Ca(NO3)2提取液自由态重金属浓度与模型计算值较为一致,能够较准确地测定土壤溶液自由态重金属离子浓度.     

A型导流片在静电除尘器中的应用

静电除尘器内气流分布是影响其脱尘效率的主要因素之一。为提高静电除尘器的除尘效率,国内外学者及工程师利用试验与计算机模拟的方式对如何调节除尘器内的气流分布进行了大量的研究。无论是早期提到的均匀气流法,还是近年来提到的斜气流理论,都提及了使用多孔板调节静电除尘器内气流的方法。但是针对某些静电除尘器及其设计要求来说,单纯的使用孔板进行调节气流已无法满足设计方提出的气流分布指标。在这里A型导流板结合孔板被用来调节静电除尘器气流进口罩内的气流,用以达到优化集尘区气流分布的目的。通过使用数值模拟的方法计算了静电除尘器内三维气流分布状况,对比了针对某静电除尘器项目单独使用多孔板调节气流的分布与使用多孔板与A型导流片相结合调节气流的方法,提出A型导流片在调节静电除尘器气流的优势,及较好的工程应用前景。     

Material flows of end-of-life home appliances in Japan

In Japan, the Law for the Recycling of Specified Kinds of Home Appliances came into effect in April 2001. This law aims to introduce appropriate waste treatment and promote the efficient use of resources so that we can achieve a sound material-cycle society. The law introduces a new framework for recycling that places obligations principally on the manufacturers and retailers of home appliances. Material flow analysis of this new framework is essential for evaluation of the system and for finding any problems that may exist. We therefore analyzed the material flows in facilities that recycle electrical home appliances. The mass balances in the recycling facilities were appropriately estimated. Then the potential destinations were surveyed and analyzed, even though the legal framework does not include flows after the recycling facilities. The potential destination after the facilities varies and depends on both the economy and the related regulations. Currently, considerable amounts of recovered materials are exported and recycled. However, the sustainability of these trades is unknown. Therefore, we should keep a close eye on the situation and make sure that our recycling system is adaptable to meet any future changes.     

旋流场超细颗粒聚集实验研究

不同粒径分布和浓度的催化裂化(FCC)三旋回收超细催化剂颗粒在旋流场中经过50 h循环回流,颗粒中值粒径变化明显。物料中分散相越多、颗粒粒径越小时,颗粒碰撞越频繁,其聚集趋势越明显。颗粒聚集体在旋流场内不够稳定,通过对比不同进料速率下的旋流场聚集效果,得到最适合颗粒聚集的旋流场雷诺数为20 000。颗粒聚集体存在聚集极限粒径,其最佳聚集时间约为40 h,颗粒聚集后的旋流分离效率提高近5%。     

综放采空区防灭火注氮数值模拟与参数确定

用有限元数值方法,求解了综放开采采空区注氮情况下的漏风渗流方程和氧浓度渗流耗散方程;结合计算机图形技术,直观展示了注氮前后采空区流场、流态和氧浓度分布动态变化;模拟了在不同注氮量下注氮控制区边界的变化过程,得到控制区边界位置与注氮流量呈负指数关系;重点探讨了用数值模拟方法确定合理注氮参数(注氮流量、注氮位置和注氮时间)的新方法.     

企业物流与安全

按照物流的作用范围,可分为社会物流和企业物流.随着物流活动在我国各生产领域不断地推进,企业物流合理化、科学化对提高企业的竞争力及促进企业的发展具有重要意义.笔者论述了企业物流与安全生产之间的关系,强调企业物流系统在进行设计和改善的同时必须进行安全设计,提出了企业物流系统中装卸搬运和仓储两个重要环节的安全技术,同时,又指出从事安全管理的人员,可以通过改善企业物流系统来改善企业安全现状.     

矿井瓦斯爆炸高速气流的破坏和伤害特性研究

针对煤矿瓦斯爆炸事故频发现状,基于爆炸动力学、流体动力学理论对巷道受限空间瓦斯爆炸冲击波波阵面后高速气流的传播特性进行分析,建立高速气流压力和速度关系的数学模型.结合在实验巷道中瓦斯爆炸高速气流压力实验数据,拟合瓦斯爆炸高速气流速度和传播距离的计算公式,其结果表明,井下瓦斯爆炸事故高速气流的传播速度随传播距离的增加而减小.依据我国陆地地面风力等级划分标准比照可得瓦斯爆炸高速气流的等级为飓风级,对井下人员伤害巨大.该研究成果为控制和预防瓦斯爆炸破坏和伤害事故扩大及事故应急救援提供了理论依据.     

Numerical analysis of the effects of fluctuations of discharge capacity on transient flow field in gas well relief line

Transient gas flow in relief line is computed to determine the effects of fluctuations of discharge capacity on flow field. Based on the theories of computational fluid dynamics and aerodynamics, the solution and the analysis were carried out using finite volume CFD solver FLUENT 13.0. Flow fields in seven working conditions were simulated in the numerical investigation and their results were compared. The results showed that the fluctuations of discharge capacity, including extent and period, exert obvious effects on transient gas flow field in relief line. The larger the fluctuation extent and the shorter the fluctuation period, the more significant is the effect. The application method of simulation results is provided to guide the laying and fixing of pipelines, which is verified by filed measurement.