黄磷尾气中PH3液相催化净化研究

以Mn（Ⅱ）与Pd（Ⅱ）为催化剂的吸收净化溶液对黄磷尾气中的PH3进行了液相催化氧化研究。考察了混合气中02浓度、温度、入口PH3浓度、气体流量和吸收液pH变化与磷化氢净化效率曲线的关系。实验结果表明：混合气中较佳的氧含量为5％;在20℃至75℃范围内,低温对催化净化有利,较适宜的反应温度为20℃;较低的PH3入口浓度和低气速均有利于对PH3的净化;吸收液较高的pH有利于吸收液中催化剂催化效能的发挥。吸收液对PH3的净化效率可达100％,但因吸收液中的金属离子易与PH3产生的PO4^3-形成沉淀,使金属离子脱离液相催化氧化系统,吸收液失效较快。     

水平管分层流下微孔泄漏特性数值模拟和实验分析

在油气田开发过程中,通常采用气液相混输模式,管道受腐蚀等因素影响容易出现穿孔而发生两相流泄漏。为分析两相流泄漏特性,对管内常见流型分层流下的微孔泄漏特性进行数值和实验分析;采用VOF耦合Level set算法分析了不同影响因素下的气液两相泄漏特性,设计了1种管道泄漏收集装置,进行室内两相流泄漏实验,并验证了数值预测模型的准确性。研究结果表明:气液两相流经过管壁泄漏口时会发生相分离,泄漏特性受小孔方位、管路内外压差、气液相流速影响较大;泄漏口位于管路侧壁时的泄漏特性与其他角度下的泄漏特性有所不同,可用泄漏影响区内的气液分布进行解释;当泄漏口位于管路底部时,存在临界液相分流系数,当液相分流比小于此临界值时,泄漏流体为单相液体。VOF耦合Level set算法的数值方法可为管路泄漏量预测和相分离特性分析提供参考。     

Simultaneous determination of organochlorine and pyrethriod pesticide residues in the Chinese patent medicines by gas chromatography-tandem mass spectrometry

A simple, sensitive, reliable method was developed for the simultaneous determination of organochlorine and pyrethriod pesticide residues in Chinese patent medicines Six ingredient rehmannia pills and Xiaoyao pills. These pesticides were extracted by ethyl acetate. The extraction time and volume of ethyl acetate were optimized. Cleanup of extracts was performed with dispersive-solid phase extraction using graphitized carbon black as the sorbent. The determination of pesticides in the final extracts was carried out by gas chromatography–tandem mass spectrometry in multiple reaction monitoring mode (GC-MS/MS, MRM). The linearity of the calibration curves is good in matrix-matched standard and yields the coefficients of determination (R²) ≥0.99 for all of the target analytes. Under optimized conditions, the average recoveries (five replicates) for most pesticides range from 75.5% to 114.6%, and RSDs are less than 10.0%. The LODs of 18 pesticides in Six ingredient rehmannia pill and Xiaoyao pills are in the range of 0.01–8.82 μg kg^?1. The developed method meets the requirements of pesticide residue analysis and could be effectively used for routine analysis of the organochlorine and pyrethriod pesticide residues in Six ingredient rehmannia pills and Xiaoyao pills.     

环境空气中多种羰基化合物的测定

利用2,4-二硝基苯肼(DNPH)固相萃取在线吸附衍生高效液相色谱-二极管阵列(HPLC-PDA)测定环境空气中的22种羰基化合物,通过试验优化条件,使方法在6.00μg/L~1 800μg/L范围内线性良好,方法检出限为0.025μg/m~3~0.091μg/m~3,加标回收率为93.2%~108%,平行样相对标准偏差10%。     

燃煤电厂排放总气态汞连续自动监测技术的选择

介绍了汞连续排放监测系统和汞吸附管采样系统的主要特点,比较了不同仪器的测定原理、样品处理技术、检出限和测定汞的形态,报道了美国环境保护署认证中心关于两个系统的认证结果.建议将汞连续排放监测系统与汞吸附管监测系统两种技术联合用于我国燃煤电厂排放总气态汞的自动监测.     

金沙江一期工程蓄水前后绥江段鱼类群落多样性特征

为探索流域梯级水电开发对鱼类群落多样性影响,于2011年(蓄水前)和2015年(蓄水后)对金沙江下游绥江断面进行渔业资源调查,分析鱼类群落结构特征。结果表明,绥江段共计采集鱼类60种,隶属于5目12科,其中长江上游特有鱼类12种。蓄水前以瓦氏黄颡鱼(Pelteobagrus vachelli)、圆口铜鱼(Coreius guichenoti)、光泽黄颡鱼(Pelteobagrus nitidus)为优势种类;蓄水后以草鱼(Ctenopharyngodon idellus)、鳙(Aristichthys nobilis)、鲢(Hypophthalmichthys molitrix)为优势种类。与蓄水前相比,鱼类群落Margalef丰富度指数、Shannon-Weiner多样性指数、Pielou均匀度指数均呈现下降趋势,但无显著性差异(P0.05)。根据生态类群分析,静水缓流型鱼类由蓄水前54%增加到蓄水后的71%,河道洄游型鱼类从39%减少到20%,江湖洄游型鱼类蓄水前后变化不大。丰度生物量比较曲线显示,蓄水前绥江段鱼类群落未受到干扰,而蓄水后受到严重干扰。库区蓄水后总生物量有明显增加趋势,但优势种类趋于小型化、种类结构单一化。为科学保护金沙江下游流域鱼类生物多样性,建议成立鱼类保护区、开展梯级生态调度和加强流域环保预警研究等措施。     

Effect of PCM on temperature fluctuation during the door opening of a household refrigerator

Temperature fluctuation inside the cabinet of a household refrigerator significantly affects the quality of preserved food. Phase change material (PCM) is a latent heat storage system that can store and release the heat energy by changing its phase from liquid to solid and solid to liquid respectively. Therefore, use of PCM inside the refrigerator cabinet has the potential for minimizing the temperature fluctuation during the door opening and the power failure. However, very few studies in the literature were dedicated to investigating the role of PCM to reduce the temperature fluctuation. The aim of this work is to experimentally investigate the effects of PCM on temperature fluctuation inside the cabinet of a household refrigerator during the door opening and power failure. The results found that a significantly lower temperature fluctuation can be obtained using PCM. It was found that during the door opening condition the air temperature in the cabinet rose rapidly. However, when a PCM container was used, temperature variation was reduced to 3–5°C. During the power failure, the system with PCM maintained a lower temperature inside the storage chamber for a long period of time (about 2 hours). Moreover, the test results indicate that PCM maintains more stable temperature in the foodstuffs inside the refrigerator. This reduction of temperature fluctuation ultimately improves the quality of preserved food.     

Towards a more effective EIA in transport planning: a literature review to derive interventions and mechanisms to improve knowledge integration

A set of process-related barriers negatively determines the effectiveness of Environmental Impact Assessment (EIA) in transport planning. Recent research highlights the unstructured stakeholder involvement and inefficient public participation in earlier phases of EIA as key bottlenecks. While the academic literature has produced promising theories for addressing these barriers, they have rarely been translated into solutions applicable and testable in practice. In order to bridge this theory–practice gap, we present a systematic literature review of interventions and mechanisms aimed at facilitating the integration of different sources and types of knowledge during the scoping phase of EIA. This review explores if and how interventions and mechanisms have been conducted in practice; if and why they worked or did not work and how relevant they are for EIA in transport planning. Based on this review, we distil a set of three specific interventions and trigger mechanisms applicable in the context of EIA in transport planning.     

Effects of Spatial Distribution of Prairie Vegetation in an Agricultural Landscape on Curve Number Values

The curve number (CN) method is used to calculate runoff in many hydrologic models, including the Soil and Water Assessment Tool (SWAT). The CN method does not account for the spatial distribution of land cover types, an important factor controlling runoff patterns. The objective of this study was to empirically derive CN values that reflect the strategic placement of native prairie vegetation (NPV) within row crop agricultural landscapes. CNs were derived using precipitation and runoff data from a seven‐year period for 14 small watersheds in Iowa. The watersheds were planted with varying amounts of NPV located in different watershed positions. The least squares and asymptotic least squares methods (LSM) were used to derive CNs using an initial abstraction coefficient (λ) of 0.2 and 0.05. The CNs were verified using leave‐one‐out cross‐validation and adjustment for antecedent moisture conditions (AMC) was tested. The asymptotic method produced CN values for watersheds with NPV treatment that were 8.9 and 14.7% lower than watersheds with 100% row crop at λ = 0.2 and λ = 0.05, respectively. The derived CNs produced Nash‐Sutcliffe efficiency values ranging from 0.4 to 0.7 during validation. Our analyses show the CNs verified best for the asymptotic LSM, when using λ of 0.05 and adjusting for AMC. Further, comparison of derived CNs against an area weighted CN indicated that the placement of vegetation does impact the CN value. Editor's note : This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

两相厌氧反应器相分离实验研究

在两相上流式厌氧生物反应器(UASB)动力学启动成功的条件下,选用钼酸盐作为产甲烷菌抑制剂,进行进一步的分相实验。实验前3 d在产酸相反应器进水中投加2.0 mmol/L的钼酸钠溶液,出水不进入产甲烷反应器。然后停止投加钼酸钠溶液,再运行3 d,出水依然不进入产甲烷反应器。6 d后,产酸反应器出水开始进入产甲烷反应器。结果表明:在停止投加钼酸盐后产酸菌便迅速恢复,而钼酸盐对产甲烷菌的作用是杀灭性的;产酸相出水去除效果降低,但是其酸化率由50%左右上升并最终稳定在60%左右,同时两相厌氧反应器整体去除效率提高。