溶胶凝胶法制备铜催化剂及其稳定性的研究

介绍了利用溶胶凝胶方法制备铜系催化剂，并考察了制备过程中各个工艺参数对铜系催化剂稳定性的影响。通过优化催化剂的设计和制备方法，可有效地改善Cu^2＋的溶出问题，使该类催化剂具有广阔的应用前景。     

Long Term Trends in Sulphur and Nitrogen Deposition in Europe and the Cause of Non-linearities

Emissions of sulphur and oxidized nitrogen compounds in Europe have been reduced following a series of control measures during the last two decades. These changes have taken place during a period in which the primary gases and the wet deposition throughout Europe were extensively monitored. Since the end of the 1970s, for example land based sulphur emissions declined by between 90 and 70% depending on the region. Over the same period the total deposition of sulphur and its partitioning into wet and dry deposition have declined, but the spatial pattern in the reduction in deposition differs from that of emission and has changed with time. Such non-linearities in the emission-deposition relationship are important to understand as they complicate the process of assessing the effects of emission reduction strategies. Observed non-linearities in terrestrial sulphur emission-deposition patterns have been identified in north west Europe due to increases in marine emissions, and are currently slowing the recovery of freshwater ecosystems. Changes in the relative amounts of SO₂ and NH₃ in air over the last two decades have also changed the affinity of terrestrial surfaces for SO₂ and have therefore changed the deposition velocity of SO₂ over substantial areas. The consequence of this effect has been the very rapid reduction in ambient SO₂ concentration in some of the major source areas of Europe, where NH₃ did not change much. Interactions between the different pollutants, generating non-linearities are now being incorporated in long-range transport models to simulate the effects of historical emission trends and to provide projections into the future. This paper identifies non-linearities in emission deposition relationships for sulphur and nitrogen compounds in Europe using data from the EMEP long-rang transport model and measured concentration fields of the major ions in precipitation and of SO₂ and NO₂ in surface air.     

催化湿式氧化法处理吡虫啉农药废水

自制了Cu／Mn，Cu／Ce，Cu／Ni，Ce／Mn，Ce／Ag等催化剂，经过性能比较，选择催化活性较高且金属溶出量较小的Cu／Ni作催化剂。用催化湿式氧化法处理吡虫啉农药废水，考察了各种因素对处理效果的影响。实验结果表明：在进水pH为6．93、Cu／Ni加入量为4．0g、反应温度为190oC、氧分压为1．6MPa、反应时间为120min的条件下，COD去除率为95％；处理后废水的BOD5／COD从0．093增至0．590，可生化性明显改善。     

电解铝生产含氟工业烟气湿法吸收治理中试装置设计实现

本文通过对国内外近几年有关电解铝含氟化氢工业尾气净化处理大量的参考文献的分析研究及国内外电解铝生产企业在尾气治理方面的技术应用和尾气净化装置运行状况的调研,结合自己的专业特长和工程经验,建立一套有关电解铝含氟化氢尾气在处理、净化氟化氢方面的技术方案,设计制作一套湿法氟化氢吸收中试装置,从工艺方案优化设计、安全运行、设备设计及选材、自动控制、建立相关的副产物检测方法和后续产物的综合利用等方面进行了研究和探讨。     

大气氮磷沉降量分析——以杭州北里湖为例

为更好地了解大气氮磷沉降量的影响因素及其对水环境的影响,采用自制采样器,对杭州北里湖2011年4月-2012年2月大气氮、磷的总、湿沉降进行采集,并通过对干、湿沉降量的计算,探讨了大气干、湿沉降中TN、TP、NH4+-N和NO3--N的变化趋势.结果表明,因秋季利于沉降而不利于扩散,夏季降水多,各物质的干沉降量表现出秋季高、夏季低的特点,湿沉降量则夏季较高.TN干沉降以NH4+-N为主,其干沉降量与气温、气压及降水量有关,而NO3--N干沉降量与风速有关;大气湿沉降量除NO3--N外,TN、TP和NH4+-N与降水量均呈现出较强的相关性,相关系数分别为0.882、0.700和0.827.在研究期间,TN、NH4+-N和NO3--N以湿沉降为主,TP以干沉降为主;北里湖大气总沉降的入湖TN量为4 503.74kg/km2,TP为100.14 kg./km2,入湖的TN/TP比值高达45,远超出正常水平,这对北里湖水体的富营养化产生了严重影响.     

Analysis of Wet Precipitation of Air Pollutants in Mumbai (India)

Bulk precipitation samples at Mumbai (India) were collectedduring the monsoon seasons of 1991 to 1996 and analysed forionic concentrations using an Ion Chromatograph DIONEX model100. The variability of sulphate to nitrate ratio in rainwaterfluctuates in a wide range from 1.5 to 20 and governed by thesulphate concentrations in the sample. The regression analysisof the data reveals that in the bulk precipitation at Mumbai, SO₄ ^2- is becoming increasingly important relative toNO₃ ^-. The role of meteorological influences onscavenging of air pollutants by rain water has been tried toexplain the phenomena. The computed wet deposition rates for Sand N during 1991–1996 show that the S deposition is higherthan N in all the years. There is a wide fluctuation indeposition rates of S ranging from 2 to 55 kg km² per annum.     

A feasibility and cost comparison of perchloroethylene dry cleaning to professional wet cleaning: case study of Silver Hanger Cleaners, Bellingham, Massachusetts

The Toxics Use Reduction Institute (TURI) has been working with the dry cleaning sector for over 10 years - focusing on the ultimate goal of eliminating the use of perchloroethylene in this sector due to the availability of less toxic, feasible alternatives. Professional wet cleaning has been identified as one of these alternatives and has been a focus of the Institute in recent years. In 2008, the Institute provided a matching grant to Silver Hanger Cleaners in Bellingham, Massachusetts to convert their operations from perchloroethylene-based to water-based processes. Two years of data have been collected from the facility, reflecting one year of solvent use and one year of dedicated professional wet cleaning. The analysis of that data is presented here, including capital costs, performance data and associated costs, operational costs, and resource use and associated costs.     

废弃电路板湿法破碎能耗试验研究

采用Design-Expert 7.1软件对废弃电路板湿法冲击式破碎机能耗试验进行了方案设计和结果分析;拟合出了能耗与试验影响因素之间的定量关系模型,给出了能耗的残差分布以及不同操作变量之间的等高线和三维响应关系;利用Design-Expert 7.1对电路板破碎能耗试验的条件进行了优化,获得了最佳的操作指标。     

空塔钠碱法烟气脱硫实验研究

在内径200mm,高度1100mm的喷淋塔内,采用Na2CO3作为吸收剂进行SO2吸收实验,重点研究了液气比(L/G)、空塔气速、进口SO2质量浓度、吸收液pH及初始浓度对脱硫效率的影响。通过实验得到该系统适宜操作条件:吸收液pH值在6.5～7.5之间,液气比在1～1.5之间,吸收液初始浓度5%,空塔气速1.6m/s,在此条件下,进口SO2质量浓度在3000mg/m3以内,脱硫效率可以达到80%以上。     

火电湿法烟气脱硫流程优化的实现方案研究

在给定脱硫流程模拟优化参数的情况下,尝试了基于DCS系统和基于OA局域网的两种优化控制改进方案,后一种方案解决了优化控制系统的安全性、稳定性、扩展性、易管理等问题。同时采用该控制系统的3号脱硫系统的控制效果最佳,且脱硫效率循环浆液泵功率比随着操作方式相近度的提高而呈递增趋势。