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101.
102.
Atsuyoshi Nakayama Norioki Kawasaki Ioannis Arvanitoyannis Seiichi Aiba Noboru Yamamoto 《Journal of Polymers and the Environment》1996,4(3):205-211
Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.1H and13C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×104. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT
m andT
g values of the copolymers showed a gradual depression with an increase in BL content. NoT
m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers. 相似文献
103.
J. J. Jesudason R. H. Marchessault T. Saito 《Journal of Polymers and the Environment》1993,1(2):89-98
The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity. 相似文献
104.
小径薄壁管广泛用于工艺管道中,在对其进行无损探伤时,一般采用双壁双影椭圆成像法和双壁重叠成像法,针对小径薄壁管对接焊缝透照成像的特殊要求,具体介绍双壁双影椭圆成像法的透照布置方法。 相似文献
105.
106.
Demonstration of Line Transect Methodologies to Estimate Urban Gray Squirrel Density 总被引:2,自引:0,他引:2
Eric W. Hein 《Environmental management》1997,21(6):943-947
Sciurus carolinensis ) have been labor intensive and costly, I demonstrate the use of line transect surveys to estimate gray squirrel density and
determine the costs of conducting surveys to achieve precise estimates. Density estimates are based on four transects that
were surveyed five times from 30 June to 9 July 1994. Using the program DISTANCE, I estimated there were 4.7 (95% CI = 1.86–11.92)
gray squirrels/ha on the Clemson University campus. Eleven additional surveys would have decreased the percent coefficient
of variation from 30% to 20% and would have cost approximately $114. Estimating urban gray squirrel density using line transect
surveys is cost effective and can provide unbiased estimates of density, provided that none of the assumptions of distance
sampling theory are violated. 相似文献
107.
城市垃圾甲烷气体排放及减排对策 总被引:6,自引:0,他引:6
本文讲述了城市垃圾的现状以及影响垃圾甲烷排放的各种因素,并根据IPCCGuidelines(1995)提供的方法对1990~2010年江浙沪地区城市垃圾甲烷排放量的变化趋势进行了预测统计计算,1990年江浙沪地区城市垃圾甲烷排放量为7123万吨,2010年预测的甲烷排放量为26676万吨,本文就垃圾中甲烷的排放提出了切实可行的减排方案。 相似文献
108.
环境保护要依靠公众参与——关于环境保护主要依靠力量的市民调查 总被引:2,自引:1,他引:2
环境问题和环境保护已日益深入到社会政治、经济、文化、生活各个领域。在呼吁公众参与的条件下,依靠谁去搞好环境保护?公众是如何看待自己在环境保护中的作用的呢?对这些问题的回答将有助于了解公众关于环境保护的心态,有助于环境保护公众参与政策更具有针对性的实施。本文就这一话题进行了城市居民的抽样调查。调查表明,公众普遍认为,政府和公众参与是搞好环保的主要依靠力量;而公众对环境宣传教育和污染企业的治理以及技术进步的期望较低。本文进一步分析了不同年龄、文化程度、职业和人均月收入带来的影响,以期把握不同层次公众的心态。在此基础上本文就环境宣传教育如何促进公众参与提出了一些思考。 相似文献
109.
110.
UV/O3复合降解水中2,4-二氯酚的试验研究 总被引:2,自引:1,他引:2
以紫外光源为主要依托,变换反应器中的不同工艺条件,分别对紫外光、臭氧和紫外/臭氧三种不同于工艺条件对水中污染物2,4-二氯酚(2 ,4-DCP)的降解规律进行研究.结果表明,UV/O3复合对2,4-DCP的降解较UV、O3单独作用效果好;溶液的酸碱度影响UV/O3对2 ,4-DCP的降解;此外,溶液中含有细菌时,E. coli的杀灭效果仍表现为UV/O3>O3>UV.细菌的杀灭和2,4-DCP的降解均消耗羟基自由基,形成竞争反应,从而影响到2,4-DCP的降解效果. 相似文献