首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10781篇
  免费   1016篇
  国内免费   1884篇
安全科学   2257篇
废物处理   231篇
环保管理   1861篇
综合类   5270篇
基础理论   1297篇
环境理论   16篇
污染及防治   715篇
评价与监测   786篇
社会与环境   657篇
灾害及防治   591篇
  2024年   69篇
  2023年   279篇
  2022年   434篇
  2021年   478篇
  2020年   453篇
  2019年   440篇
  2018年   371篇
  2017年   470篇
  2016年   553篇
  2015年   543篇
  2014年   585篇
  2013年   777篇
  2012年   838篇
  2011年   948篇
  2010年   607篇
  2009年   639篇
  2008年   547篇
  2007年   682篇
  2006年   599篇
  2005年   482篇
  2004年   374篇
  2003年   363篇
  2002年   311篇
  2001年   248篇
  2000年   200篇
  1999年   202篇
  1998年   137篇
  1997年   148篇
  1996年   127篇
  1995年   94篇
  1994年   110篇
  1993年   80篇
  1992年   65篇
  1991年   55篇
  1990年   40篇
  1989年   37篇
  1988年   40篇
  1987年   22篇
  1986年   14篇
  1985年   20篇
  1984年   13篇
  1983年   12篇
  1982年   25篇
  1981年   20篇
  1980年   19篇
  1979年   20篇
  1978年   14篇
  1977年   10篇
  1972年   18篇
  1971年   20篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
211.
2019年秋季在珠三角典型沿海城市珠海观测到一次中重度污染过程,本文对此次过程的污染特征、形成机制和来源进行了研究.通过 采集PM2.5样品,分析了9种水溶性无机离子(WSIIs)、有机碳(OC)、元素碳(EC)和水溶性有机碳(WSOC)等化学组分的浓度水平和污染特征;进一步结合污染过程中的不利天气形势、72 h后向气流轨迹及PM2.5的潜在源贡献因子(WPSCF)和浓度权重轨迹(WCWT)等方法分析了污染的形成机制和来源.结果表明,有机物(OM)是污染时期PM2.5中增长最快的组分,其次是占WSIIs约82.46%的SO42-、NO3-和NH4+(SNA). NO3-/SO42-均值为0.20,表明珠海以固定源污染为主;硫氧化率(SOR)均值为0.65,氮氧化率(NOR)均值为0.08,高温高湿的气象条件可能是 造成珠海比中国其他城市SOR偏高而NOR偏低的原因.在污染时段,二次有机碳(SOC)明显增加,WSOC/SOC随污染物的升高而降低并趋近于1,因此, 污染时期的WSOC可能主要是二次生成的.副高控制型、台风外围型和高压出海型等天气形势控制着整个珠三角地区时,不利于污染物的传输和扩散,使污染加剧.后向气流轨迹分析表明,污染时期的气团轨迹主要来自于高污染的内陆地区,这可能是造成此次污染形成的重要原因和来源.WPSCF和WCWT的高值区主要集中在江西、广东等内陆地区,因此,珠海在控制本地排放的同时,也应该关注上风向临近省市的污染排放.  相似文献   
212.
Atmospheric lead pollution in fine particulate matter in Shanghai, China   总被引:1,自引:1,他引:1  
The Pb-monitoring program was extended for 6 years from 2002 to 2007 at 17 representative urban sites (6 traffic, 5 industrial, and 6 residential sites), and 3 suburban sites to assess the lead pollution in fine particulate matter (PM2.5) after phasing out leaded gasoline in Shanghai. Compared with Pb levels reported in other places, the Pb pollution in Shanghai is still serious after phasing out leaded gasoline, which remains at high concentration range (213–176 ng/m3) in PM2.5 in winter. Significant spati...  相似文献   
213.
“无废城市”建设已经成为应对城市固体废物(以下简称“固废”)管理挑战的国际趋势,我国也启动了“无废城市”建设试点工作。本文介绍了国际“无废城市”实践的背景和发展趋势,对我国和其他高收入国家的“无废城市”相关政策和具体实施方案进行了对比分析。分析结果表明,“无废城市”的推进政策与实施措施存在国别差异,我国的“无废城市”采纳了“问题导向”的推进策略,而高收入国家则是“目标导向”。最后对进一步推进我国“无废城市”建设试点工作提出了四点建议。  相似文献   
214.
ABSTRACT

Researchers often focus on the most intense conflicts, skewing our perception of the diversity and nature of policy conflicts. The paper examines the discourse engaged in the siting of three pipeline projects under construction, each with varying levels of conflict, and one rejected project of high conflict. We analyze over 700 newspaper articles that span the life of each proposed pipeline and supplement the news media data with interviews. Using these data, we compare differences in actor types, frames, and behaviors in natural gas pipeline siting processes characterized by high, medium, and low conflict. Comparing the characteristics of energy siting conflicts at varying intensities helps support corresponding portrayals of how people engage in the policy process. This paper offers theoretical and empirical guidance on understanding policy conflict intensity variation.  相似文献   
215.
ABSTRACT

In order to study the effect of fly ash content in cemented paste backfill (CPB) on its anti-sulfate erosion, the apparent phenomenon, strength development, and hydration products change the law of CPB with different fly ash content under long-term soaking of 5% sodium sulfate solution were studied by the macrotest and microanalysis, in addition, the mechanism of CPB anti-sulfate attack was analyzed by combining with a scanning electron microscope (SEM). The results indicated that the effect of sulfate environment on the strength of fly ash cemented paste backfill (FCPB) was mainly determined by the hydration products in the FCPB at different soaking times. In the early soaking stage, the formation of ettringite (AFt) in FCPB could improve its compactness, which was conducive to improving the strength of FCPB. In the late soaking stage, there were ettringite-type erosion damage and gypsum erosion-type damage internal of the FCPB with low content fly ash, resulting in microfracture, cracking of the FCPB, and reducing the strength. CPB with an appropriate content of fly ash could improve the internal structure of the FCPB to achieve the purpose of anti-sulfate erosion.  相似文献   
216.
从经济、社会、资源、环境保护4个层面构建了切合山西省实际情况的绿色转型发展指标体系,采用熵权法及聚类分析方法对山西省的绿色转型发展现状进行了评价,根据评价结果,结合政策背景,提出了山西省实现绿色转型发展的路径,以实现山西省均衡快速的绿色转型发展。  相似文献   
217.
A detailed nitrogen (N) budget has been developed for an urban ecosystem based on the method of material flow analysis. How increased human activity and urbanisation influences N cycling have also been analysed. Total N input and output in the urban ecosystem of Zhengzhou City (ZUE) was calculated at 304.8?Gg was 275.3?Gg year?1, resulting in an N accumulation of 29.5?Gg year?1. Industry and human life activities, which respectively accounted for 43.8% and 34.2% of total N inputs and 52.6% and 29.1% of total N outputs, were the core of N flow in the urban ecosystem. Humans activities mediated more than 98% N inputs into the ZUE, 73.2% of N was released into the atmosphere and 11.7% into hydrosphere. This very large volume of released N could contribute to regional problems. High energy consumption, insufficient wastewater treatment facility practices, and low N use efficiency are the primary causes of pollution. The major challenge ahead for the urban ecosystem is how to manage high-intensity N pollutant inputs to the urban ecosystems coupled with incomplete N cycling and removal. Based on the analysis of the N budget and loading, this study also proposes an N management strategy for the ZUE.  相似文献   
218.
Identifying source information after river chemical spill occurrences is critical for emergency responses. However, the inverse uncertainty characteristics of this kind of pollution source inversion problem have not yet been clearly elucidated. To fill this gap, stochastic analysis approaches, including a regional sensitivity analysis method, identifiability plot and perturbation methods, were employed to conduct an empirical investigation on generic inverse uncertainty characteristics under a well-accepted uncertainty analysis framework. Case studies based on field tracer experiments and synthetic numerical tracer experiments revealed several new rules. For example, the release load can be most easily inverted, and the source location is responsible for the largest uncertainty among the source parameters. The diffusion and convection processes are more sensitive than the dilution and pollutant attenuation processes to the optimization of objective functions in terms of structural uncertainty. The differences among the different objective functions are smaller for instantaneous release than for continuous release cases. Small monitoring errors affect the inversion results only slightly, which can be ignored in practice. Interestingly, the estimated values of the release location and time negatively deviate from the real values, and the extent is positively correlated with the relative size of the mixing zone to the objective river reach. These new findings improve decision making in emergency responses to sudden water pollution and guide the monitoring network design.
  相似文献   
219.
To study heavy metal pollution and assess the health risk of river water in Huayuan County, Xiangxi, Hunan Province, 11 water samples were collected from the Huayuan River and Brother Rivers in August and December 2016. Heavy metal (Pb, Zn, Cr, Cu, Fe, and Ni) concentrations were determined from the samples. The health risk assessment model recommended by the U.S. Environmental Protection Agency (USEPA) was applied to assess the health risk of heavy metals in the main surface waters of Huayuan County. The results indicated that the concentrations of heavy metals (Pb, Zn, Cr, Cu, Fe, and Ni) of surface water in the research area were 2.57 × 10-3, 4.66 × 10-4, 1.65 × 10-3, 6.27 × 10-4, 0.19, and 8.50 × 10-4 mg/L, respectively. The health risk of surface waters with heavy metals was high. Therefore, the chemical carcinogenic substance (Cr) health risk index was five or six times higher than that of chemical non-carcinogens (Pb, Zn, Cu, and Ni). The average health risk indices of non-carcinogenic substances were in the order Pb > Cu > Zn > Ni. The correlation and principal component analysis of surface water showed that the six heavy metal elements were composed of three main components in the main surface waters of the county. The first principal component was comprised of Fe and Ni (33.28%), which was mainly from internal pollution. The second component was comprised of Cu and Cr (26.98%), which was primarily due to industrial waste water, rainwater leaching mineral waste produced by heavy metal mining, and smelting enterprises. The third component, resulting from geochemical pollution, was Zn (17.10%). The health risk indices triggered by heavy metal in surface waters was high. Heavy metal pollutants in the research area need to be controlled in the order Cr, Pb, Cu, Zn and Ni. © 2018 Science Press. All rights reserved.  相似文献   
220.
研究了尼龙6在亚超临界水中的解聚反应,以期为废旧尼龙6的回收利用提供技术参数.实验分别利用气质联用仪和紫外分光光度计对解聚后的液相产物进行定性和定量分析,并考察了不同的反应温度、反应压力和反应时间对液相产物收率的影响.结果表明,液相产物绝大部分为己内酰胺;解聚的最佳条件为370 ℃、25 MPa、60 min;己内酰胺最大收率为96%.通过动力学分析和Arrhenius关系计算,得出尼龙6亚超临界水解聚的活化能为64.4 kJ/mol.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号