全文获取类型
收费全文 | 273篇 |
免费 | 3篇 |
国内免费 | 31篇 |
专业分类
安全科学 | 28篇 |
废物处理 | 9篇 |
环保管理 | 17篇 |
综合类 | 137篇 |
基础理论 | 21篇 |
污染及防治 | 54篇 |
评价与监测 | 40篇 |
社会与环境 | 1篇 |
出版年
2023年 | 8篇 |
2021年 | 11篇 |
2020年 | 19篇 |
2019年 | 3篇 |
2018年 | 11篇 |
2017年 | 11篇 |
2016年 | 10篇 |
2015年 | 8篇 |
2014年 | 13篇 |
2013年 | 20篇 |
2012年 | 17篇 |
2011年 | 21篇 |
2010年 | 11篇 |
2009年 | 13篇 |
2008年 | 20篇 |
2007年 | 18篇 |
2006年 | 15篇 |
2005年 | 10篇 |
2004年 | 3篇 |
2003年 | 10篇 |
2002年 | 5篇 |
2001年 | 8篇 |
2000年 | 9篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1984年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有307条查询结果,搜索用时 15 毫秒
41.
Runmiao Xue Ariel Donovan Haiting Zhang Yinfa M Craig Adams John Yang Bin Hu Enos Inniss Todd Eichholz Honglan Shi 《环境科学学报(英文版)》2018,30(2):82-91
When adding sufficient chlorine to achieve breakpoint chlorination to source water containing high concentration of ammonia during drinking water treatment, high concentrations of disinfection by-products(DBPs) may form. If N-nitrosamine precursors are present, highly toxic N-nitrosamines, primarily N-nitrosodimethylamine(NDMA), may also form. Removing their precursors before disinfection should be a more effective way to minimize these DBPs formation. In this study, zeolites and activated carbon were examined for ammonia and N-nitrosamine precursor removal when incorporated into drinking water treatment processes.The test results indicate that Mordenite zeolite can remove ammonia and five of seven N-nitrosamine precursors efficiently by single step adsorption test. The practical applicability was evaluated by simulation of typical drinking water treatment processes using six-gang stirring system. The Mordenite zeolite was applied at the steps of lime softening, alum coagulation, and alum coagulation with powdered activated carbon(PAC) sorption. While the lime softening process resulted in poor zeolite performance, alum coagulation did not impact ammonia and N-nitrosamine precursor removal. During alum coagulation, more than67% ammonia and 70%–100% N-nitrosamine precursors were removed by Mordenite zeolite(except 3-(dimethylaminomethyl)indole(DMAI) and 4-dimethylaminoantipyrine(DMAP)). PAC effectively removed DMAI and DMAP when added during alum coagulation. A combination of the zeolite and PAC selected efficiently removed ammonia and all tested seven N-nitrosamine precursors(dimethylamine(DMA), ethylmethylamine(EMA), diethylamine(DEA), dipropylamine(DPA), trimethylamine(TMA), DMAP, and DMAI) during the alum coagulation process. 相似文献
42.
The effect of K deactivation on V_2O_5/WO_3-TiO_2 and Ce-doped V_2O_5/WO_3-TiO_2 catalysts in the selective catalytic reduction(SCR) of NOxby NH_3 was studied.Ce-doped V_2O_5/WO_3-TiO_2 showed significantly higher resistance to K deactivation than V_2O_5/WO_3-TiO_2.Ce-doped V_2O_5/WO_3-TiO_2 with K/V = 4(molar ratio) showed 90% NOxconversion at 350°C,whereas in this case V_2O_5/WO_3-TiO_2 showed no activity.The fresh and K-poisoned V_2O_5/WO_3-TiO_2 and Ce-doped V_2O_5/WO_3-TiO_2 catalysts were investigated by means of in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS),NH_3-temperature progress decomposition(NH_3-TPD),X-ray photoelectron spectroscopy(XPS) and H2-temperature program reduction(H_2-TPR).The effect of Ce doping on the improving resistance to K of V_2O_5/WO_3-TiO_2 were discussed. 相似文献
43.
44.
HANNA C200离子分析仪测定水中的氨氮操作简便、快速、试剂用量小;经统计学处理,标准样品在中间浓度精密度、准确度较高;测定值更准确。 相似文献
45.
Jean-Franois Cabaraux Franois-Xavier Philippe Martine Laitat Bernard Canart Marc Vandenheede Baudouin Nicks 《Agriculture, ecosystems & environment》2009,130(3-4):86-92
Gaseous emissions from agriculture contribute to a number of environmental effects. Carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) are greenhouse gases taking part to the global problem of climate change. Ammonia (NH3) emissions are responsible of soil acidification and eutrophication and contribute also to indirect emissions of N2O. This work evaluated the influence of the type of floor on the emissions of these gases in the raising of weaned pigs. Two trials were carried out. In the first trial, the animals were kept either on fully slatted floor or on straw-based deep litter and, in the second one, either on fully slatted floor or on sawdust-based deep litter. For each trial and on each type of floor, 2 successive batches of weaned pigs were raised without changing the litter or emptying the slurry pit between the 2 batches. The rooms were automatically ventilated to maintain a constant ambient temperature.The performance of the animals was not significantly different according to the floor type. In trial 1, the nitrogen contents of the straw deep litter (including the substrate) and slurry were respectively 276 and 389 g pig−1. In trial 2, the sawdust deep litter and slurry nitrogen contents were respectively 122 and 318 g pig−1.Raising pigs on straw deep litter produced proportionately around 100% more NH3 than raising pigs on slatted floor (0.61 g NH3-N d−1 pig−1 vs. 0.31 g NH3-N d−1 pig−1; P < 0.05). Differences in CO2, H2O and CH4 emissions were not significant between systems. Raising pigs on sawdust deep litter produced also proportionately more NH3 (+52%; 0.55 g NH3-N d−1 pig−1 vs. 0.36 g NH3-N d−1 pig−1; P < 0.01) but also more CO2 (+25%; 427 g d−1 pig−1 vs. 341 g d−1 pig−1; P < 0.001) and H2O (+65%; 981 g d−1 pig−1 vs. 593 g d−1 pig−1; P < 0.001) and less CH4 (−40%; 0.52 g d−1 pig−1 vs. 0.86 g d−1 pig−1; P < 0.001) than raising pigs on slatted floor. Practically no N2O emission was observed from rooms with slatted floor while the N2O emissions were 0.03 and 0.32 g N2O-N d−1 pig−1 for the straw and sawdust deep litter respectively. The warming potential of the greenhouse gases (N2O + CH4), were about 22, 34 and 168 g CO2 equivalents per day and per pig on fully slatted floor, straw or sawdust deep litter respectively.In conclusion, pollutant gas emissions from rearing of weaned pig seem lower with fully slatted plastic floor system than with deep litter systems. 相似文献
46.
为制定热排放标准的需要,用动态实验和静态实验方法研究了热冲击与氨对鲢、鳙、草、鲤鱼的急性和亚急性效应。结果表明:选择温度与起始致死温度(TL50)值随着驯化温度的升高而增大,鳙鱼对热冲击的反应较敏感。氨对鲢、鳙、鲤鱼的急性毒性(96h)LC50值分别为0.38、0.30、0.66mgNH3/L(非离解氨)。水温升高5℃,鲤鱼的(96h)LC50。值从0.66mgNH3/L下降到0.44mgNH3/L,热冲击明显提高了氨对鲤鱼的毒性。氨对鲤鱼的亚急性毒性结果表明,鳃、肝组织出现了病理改变。以上室内实验结果可作为评价监测热污染水质的科学依据。 相似文献
47.
Yuchen Gao Jianguo Jiang Yuan Meng Tongyao Ju Siyu Han 《Frontiers of Environmental Science & Engineering》2023,17(3):32
48.
《Process Safety and Environmental Protection》2014,92(6):862-868
The industrial processes used for the production of nitrogenous fertilizers are the main generators of reactive nitrogen compounds, chemicals and effluents that ultimately impact the biosphere. Exergy analysis has been performed to a nitrogen fertilizer factory in the State of Bahia, Brazil, where the Anaerobic Ammonium Oxidation (Anammox) and other physical–chemical processes are used to partially or totally handle the feed streams normally sent to a stripping tower.The results showed that the combined use of physical–chemical and biological process can improve the overall exergetic efficiency and avoid the emission of reactive compounds to the atmosphere allowing the recovery of the condensate lost as effluent, so that it can be reincorporated in the production of steam network, increasing energy efficiency and environmental performance of the process. 相似文献
49.
Arizzi Novelli Alessandra Picone Marco Losso Chiara Volpi Ghirardini Annamaria 《毒物与环境化学》2013,95(4-6):183-191
The aim of this study was to investigate the toxicity of total ammonia towards sea urchin bioassays, in order to elucidate the role of ammonia as confounding factor in sediment quality assessment studies. New toxicity data, expressed as EC50, NOEC and LOEC are reported for Paracentrotus lividus based on experiments at differing pH values. Results confirmed that sperm cell toxicity test is not very sensitive to ammonia, while total ammonia embryotoxicity is strictly pH dependent. Accurate observations of embryotoxic effects at increasing total ammonia concentrations evidenced progressive shifts from malformed plutei to gastrula and blastula blockages. Toxicity data obtained for P. lividus are comparable with previous results with other echinoid species. 相似文献
50.
Estimating the volatilization of ammonia from synthetic nitrogenous fertilizers used in China 总被引:11,自引:0,他引:11
Although it has long been recognized that significant amounts of nitrogen, typically in the form of ammonia (NH(3)) applied as fertilizer, are lost to the atmosphere, accurate estimates are lacking for many locations. In this study, a detailed, bottom-up method for estimating NH(3) emissions from synthetic fertilizers in China was used. The total amount emitted in 2005 in China was estimated to be 3.55 Tg NH(3)-N, with an uncertainty of ± 50%. This estimate was considerably lower than previously published values. Emissions from urea and ammonium bicarbonate accounted for 64.3% and 26.5%, respectively, of the 2005 total. The NH(3) emission inventory incorporated 2448 county-level data points, categorized on a monthly basis, and was developed with more accurate activity levels and emission factors than had been used in previous assessments. There was considerable variability in the emissions within a province. The NH(3) emissions generally peaked in the spring and summer, accounting for 30.1% and 48.8%, respectively, of total emissions in 2005. The peaks correlated with crop planting and fertilization schedules. The NH(3) regional distribution pattern showed strong correspondence with planting techniques and local arable land areas. The regions with the highest atmospheric losses are located in eastern China, especially the North China Plain and the Taihu region. 相似文献