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531.
Lakhani A Parmar RS Satsangi GS Prakash S 《Environmental monitoring and assessment》2007,133(1-3):435-445
Fog water samples were collected in the months of December and January during 1998–2000 at Agra, India. The samples were analyzed
for pH, major anions (F−, Cl−, SO4
2−, NO3
−, HCOO− and CH3COO−), major cations (Ca2+, Mg2+, Na+ and K+) and NH4
+ using ion chromatography, ICP-AES and spectrophotometer methods, respectively. pH of fog water samples ranged between 7.0
and 7.6 with a volume weighted mean of 7.2, indicating its alkaline characteristic. NH4
+ contributed 40%, SO4
2− and NO3
− accounted for 28%, while Ca2+, Mg2+, Na+ and K+ accounted for 16% of the total ionic concentration. The ratios of Mg2+/Ca2+ and Na+/Ca2+ in fog water indicates that 50–75% of fog water samples correspond to the respective ratios in local soil. Significant correlation
between Ca2+, Mg2+, Na+ and K+ suggests their soil origin. The order of neutralization, NH4
+ (1.4) > Ca2+ (0.28) > Mg2+ (0.12), indicates that NH4
+ is the major neutralizing species. Fog water and atmospheric alkalinity were also computed and were found to be 873 and 903 neqm−3, respectively. Both of these values are higher than values reported from temperate sites and thus indicate that at the present
level of pollutants, there is no risk of acid fog problem. The study also shows that the alkaline nature of fog water is due
to dissolution of ammonia gas and partly due to interaction of fog water with soil derived aerosols. 相似文献
532.
Dispersion of atmospheric contaminants in the vicinity of an isolated cubical model building was investigated in the field. A dual source/receptor technique was used in the experiments, which was proved to be very useful for the investigation of pollution dispersion. This experimental technique involved the simultaneous release of two different tracer gases from two different point sources, and the deployment of a FID (Flame Ionization Detector) co-located with a UVIC®(Ultra-Violet Ion Collector) detector. Both mean concentrations and concentration fluctuation statistics were examined. In this paper concentration fluctuation statistics are presented. The effect of the upwind source location on intermittency values and on the cumulative density function (cdf) is examined. The exact location of a source placed upwind of an obstacle has a very significant and complex effect on both mean concentrations and concentration fluctuations. As the lateral or vertical displacement between the two sources is increased, cross-correlation values between data taken simultaneously by two co-located detectors decrease rapidly. 相似文献
533.
Sulfate () concentrations and fluxes were studied for multiple storm events in the Point Peter Brook watershed, a glaciated, forested
watershed located in Western New York, USA. Investigations were performed across one large (696 ha) and three small (1.6–3.4 ha)
catchments with varying extent of riparian and wetland areas. Concentrations of in groundwater sources (mean values: 238–910 μmolc L−1) were considerably greater than concentrations recorded for rainfall (60 μmolc L−1) and throughfall (72–129 μmolc L−1). Seasonality in concentrations was most pronounced for valley-bottom riparian waters with maximum concentrations in late winter–spring (February–March)
and a minimum in late summer (August). Concentrations of in wetland water were considerably less than riparian water indicating the likelihood of reduction in anoxic wetland conditions. Storm events displayed a dilution pattern in concentrations with a minimum coinciding with the maximum in throughfall contributions. End member mixing analysis (EMMA)
was able to predict the storm event concentrations of for four of the six comparisons. Concentrations of at the outlet of the large (696 ha) catchment were much greater than values recorded for the smaller catchments. Exports
of in streamflow exceeded the inputs from atmospheric deposition suggesting that watersheds like Point Peter Brook may not show
any immediate response to decreases in atmospheric deposition. 相似文献
534.
Bahar B Herting G Wallinder IO Hakkila K Leygraf C Virta M 《Environmental monitoring and assessment》2008,140(1-3):175-189
Changes in chemical speciation of copper and the capacity of concrete pavement to retain copper in runoff water from external
buildings have been investigated at urban field conditions, and in parallel laboratory experiments simulating outdoor scenarios.
The research study showed the concrete surface to form a copper rich surface layer (≈50 μm thick) upon exposure, and a high
capacity to significantly reduce the bioavailable fraction of released copper (20–95%). The retention capacity of copper varied
between 5 and 20% during single runoff events in the laboratory, and between 10 and 40% of the total copper release during
single natural runoff events. The capacity to retain and reduce the bioavailable fraction of non-retained copper increased
with increasing wetness of the concrete surfaces, increasing pH of the runoff water and decreasing flow rates. Bioassay testing
with bacterial and yeast bioreporters showed the bioavailable fraction of non-retained copper to be significantly lower than
the total copper concentration in the runoff water, between 22 and 40% for bacteria and between 8 and 31% for yeast. The application
of generated data to simulate a fictive outdoor scenario, suggests a significant reduction of bioavailable and total copper
to background values during environmental entry as a result of dilution, and the interaction with solid surfaces, organic
matter and complexing agents already in the drainage system. 相似文献
535.
Landsat5 TM遥感影像上太湖蓝藻水华反射光谱特征研究 总被引:5,自引:2,他引:3
利用ENVI遥感软件的FLAASH工具对2005年10月17日大规模蓝藻水华暴发的太湖Landsat5 TM影像进行大气校正处理,反演获得蓝藻水华和其他地物类型的遥感反射率图像,提取了不同集聚程度蓝藻水华的可见波段至近红外波段反射率数据,并与陆生植被、无蓝藻水面等地物的光谱反射率进行了比较。研究表明,与陆生植被、无蓝藻水面相比,蓝藻水华在TM2波段和TM4波段具有更高的反射率,在可见光波段整体反射率略高于陆生植被,在TM5、TM7波段则受水的影响反射率很低。从蓝藻水华、陆生植被的细胞生理结构、生长环境、复杂的遥感反射、散射及透射模型方面初步讨论了光谱差异的原因。 相似文献
536.
537.
Chen Xun-lai Feng Ye-rong Li Jiang-nan Lin Wen-shi Fan Shao-jia Wang An-yu Fong Soikun Lin Hui 《Environmental Modeling and Assessment》2009,14(3):351-363
The atmospheric haze over the Pearl River Delta (PRD) was investigated by using the Models-3 Community Multi-scale Air Quality
modeling system with meteorological fields simulated by the Fifth-generation National Center for Atmospheric Research/Penn
State University Mesoscale Model (MM5) from September 26th to September 30th, 2004. The model-simulated meteorological elements
and particulate matter with aerodynamic diameter less than 10 μm (PM10) were compared with observations at four air quality-monitoring stations. The results showed that MM5 successfully reproduced
the diurnal variations of temperature, wind speed, and wind directions at these stations. The temporal variations of the simulated
values were consistent with those of the observed (such as temperature, wind speed, and wind direction). The correlation coefficient
was 0.91 for temperature and 0.56 for wind speed. The modeling results show that the spatial distributions of simulated PM10 were closely related to the source emissions indicating three maxima of PM10 over the PRD. The sea–land breezes diurnal cycle played a significant role in the redistribution and transport of PM10. Nighttime land breeze could transport PM10 to the coast and the sea, while daytime sea breeze (SB) could carry the accumulated PM10 offshore back to the inland cities. PM10 could also be transported vertically to a height of up to about 1000 m because of strong turbulence in the SB front. Process
analyses indicated that the emission sources and the vertical diffusion were the major processes to influence the concentrations
of particulate matter with aerodynamic diameter less than 2.5 μm (PM2.5). 相似文献
538.
A. M. O. Abdul Raheem F. A. Adekola I. O. Obioh 《Environmental Modeling and Assessment》2009,14(4):497-509
A combination of multivariate statistical methods including factor analysis, principal component analysis, principal component
regression, and multiple linear regression (MLR) were employed to evaluate the influence of seasons on the concentrations
of ozone, sulfur (IV) oxide, and oxides of nitrogen in ambient air of Nigerian cities of Lagos and Ilorin. The former city
is located in the coastal area, and it is highly congested with a high intensity of marine, vehicular, and industrial activities,
and the latter city is a medium size town, located in the central guinea savannah zone of Nigeria. Samples were collected
using a high-volume sampler from near the ground at various sites of diverse human and industrial activities, during wet and
dry seasons from 2003 to 2006. The PCA reveals three distinct groupings during the day for all data, which is a reflection
of different factors contributing to the atmospheric chemistry of these cities. The predicted ozone concentration values by
MLR agree fairly well with the measured data. The dependence of ozone on meteorological parameters including relative humidity,
air temperature, and sun exposure and the precursor pollutants depends on weather and the anthropogenic activities. The results
for the two cities indicate that reduction in the level of NO2 is accompanied by an increase in the level of ozone, suggesting the interconversion between the two via photochemical activity. 相似文献
539.
灰霾期间气溶胶的污染特征 总被引:11,自引:0,他引:11
从颗粒物的时空分布和浓度水平方面综述了灰霾期间气溶胶的污染特征,介绍了灰霾期间气溶胶中金属元素、水溶性离子、有机碳和元素碳的浓度特征,以及颗粒物与能见度的相关性研究进展。指出:灰霾天气多发生在冬季,且气溶胶中PM2.5占的比重大;气溶胶污染与地理环境、气候条件、经济发展水平等有密切关系;水溶性离子多集中在PM2.5中;能见度的下降与气溶胶特别是细颗粒物有很大关系。提出目前灰霾研究中主要存在3大问题:一是对灰霾期间气溶胶中含有的有机物类别及其对不同季节发生灰霾的贡献率仍需进一步研究;二是灰霾期间气溶胶中有机物的形成机理尚不明确;三是不同源排放的气溶胶对灰霾形成的贡献率有待探讨。建议系统地开展大气细颗粒物有害成分的鉴定、源排放颗粒物的物理化学特性、扩散过程中各种物质间的反应和转化等方面的研究,为大气污染防治法规的制定提供依据。 相似文献
540.
微波消解ICP-MS法同时测定大气颗粒物中多种痕量元素 总被引:3,自引:0,他引:3
采用微波消解电感耦合等离子体质谱法同时测定大气颗粒物中13种元素,选择硝酸体系消解20 min,硝酸加入体积为8 mL。Cu、Ni、Cr、Pb、Al、Mg、Mn、Ca在0μg/L~100μg/L,Ag、Ba、Co、Cd、Sn在0μg/L~5.00μg/L范围内线性良好,除Al、Mg、Ca检出限较高外,其他10种元素的检出限为0.07 ng/m3~1.82 ng/m3(按采样体积0.688 m3、定容体积50 mL计),滤膜样品平行测定3次的RSD≤1.2%,加标回收率在92%~108%之间。 相似文献