全文获取类型
收费全文 | 923篇 |
免费 | 92篇 |
国内免费 | 297篇 |
专业分类
安全科学 | 75篇 |
废物处理 | 48篇 |
环保管理 | 82篇 |
综合类 | 670篇 |
基础理论 | 123篇 |
污染及防治 | 129篇 |
评价与监测 | 169篇 |
社会与环境 | 14篇 |
灾害及防治 | 2篇 |
出版年
2024年 | 3篇 |
2023年 | 10篇 |
2022年 | 18篇 |
2021年 | 26篇 |
2020年 | 24篇 |
2019年 | 28篇 |
2018年 | 25篇 |
2017年 | 32篇 |
2016年 | 44篇 |
2015年 | 48篇 |
2014年 | 59篇 |
2013年 | 119篇 |
2012年 | 76篇 |
2011年 | 85篇 |
2010年 | 62篇 |
2009年 | 60篇 |
2008年 | 42篇 |
2007年 | 85篇 |
2006年 | 77篇 |
2005年 | 57篇 |
2004年 | 48篇 |
2003年 | 46篇 |
2002年 | 31篇 |
2001年 | 32篇 |
2000年 | 24篇 |
1999年 | 30篇 |
1998年 | 25篇 |
1997年 | 14篇 |
1996年 | 16篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 14篇 |
1992年 | 12篇 |
1991年 | 9篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有1312条查询结果,搜索用时 31 毫秒
81.
82.
Yamaguchi N Nakano M Takamatsu R Tanida H 《Journal of environmental radioactivity》2010,101(6):451-9983
The transformation of inorganic iodine (I− and IO3−) incubated in soils with varying amounts of organic matter (Andosols from the surface layer of an upland field and forest, as well as Acrisols from surface and subsurface layers of an upland field) was investigated by using the iodine K-edge X-ray absorption near-edge structure (XANES). After 60 d of reaction, both I− and IO3− were transformed into organoiodine in surface soils containing sufficient amounts of organic matter, whereas IO3− remained unchanged in the subsurface soil of Acrisols with low organic matter contents. Transformation of IO3− into organoiodine was not retarded when the microbial activity in soil was reduced by γ-ray irradiation, suggesting that microbial activity was not essential for the transformation of inorganic iodine into organoiodine. Soil organic matter has the ability to transform inorganic iodine into organoiodine. 相似文献
83.
K. Yoshida I. Fuzesi M. Suzan L. Nagy 《Journal of environmental science and health. Part. B》2013,48(2):169-183
Abstract A traditional method to determine operator dermal exposure is to quantify the amount of pesticide coming into contact with specific body regions and then to integrate the deposition density values with the total body surface. It is known that extremely high deposition values may occur in the hand region; however, the source of contamination is generally assumed to be direct splash or contact with the pesticide container. One of the parameters affecting operator/pilot exposure could be the transfer of pesticide residue, particularly in the case of pesticides with a longer half‐life, from contaminated surfaces of spray equipment by direct contact over extended periods. If the rate of skin absorption of pesticide is readily known, the expected values of daily dose for an operator or pilot may significantly rise due to the extended contact period. This study produced field data on the surface contamination of spray equipment used for ground and aerial applications. If field data on precise work practice (time‐motion) observations are incorporated, it may be possible to estimate the potential exposure of operator/pilot due to hand contact with contaminated surfaces. 相似文献
84.
钢渣掺量对泡沫混凝土砌块性能的影响 总被引:1,自引:0,他引:1
泡沫混凝土是一种环保、节能的保温隔热材料,以其优良的保温性能,受到越来越多研究者的关注。对钢渣的特性进行了分析测试,对钢渣不同掺量对泡沫混凝土砌块特性的影响进行了研究,结果表明,采用添加5%~35%钢渣所制备的钢渣泡沫混凝土砌块,其密度等级为JC/T1062—2007中的B10级,掺人5%、15%钢渣的泡沫混凝土抗压强度达到A3.5等级,掺人25%、35%钢渣的泡沫混凝土抗压强度达到A2.5等级。随着钢渣掺量的增大,抗压强度、抗折强度降低,吸水率增大。在同一钢渣掺量的情况下,泡沫混凝土砌块的抗压强度变化率增加显著,而且随着钢渣的加入量升高而增大。钢渣的加入有利于提高泡沫混凝土砌块的后期抗压强度。 相似文献
85.
采用水相共沉淀法制备小尺寸磁性Fe3O4纳米颗粒,以没食子酸作为还原剂和表面修饰剂,还原Ag[(NH3)2]+制备出Fe3O4/Ag磁性纳米颗粒。研究该磁性纳米颗粒对水溶液中铅离子的吸附行为,研究结果表明,pH为7.0,吸附温度30℃时可得到最好的处理效果,铅的去除率可达99.7%以上,Fe3O4/Ag颗粒吸附行为符合二级动力学模型(R2 > 0.99)。该磁性纳米颗粒经过多次再生处理后,仍具有很好的吸附效果,表明Fe3O4/Ag在水处理方面拥有良好的应用前景。 相似文献
86.
Dimkpa CO Calder A Britt DW McLean JE Anderson AJ 《Environmental pollution (Barking, Essex : 1987)》2011,159(7):1749-1756
The toxicity of commercially-available CuO and ZnO nanoparticles (NPs) to pathogenic bacteria was compared for a beneficial rhizosphere isolate, Pseudomonas chlororaphis O6. The NPs aggregated, released ions to different extents under the conditions used for bacterial exposure, and associated with bacterial cell surface. Bacterial surface charge was neutralized by NPs, dependent on pH. The CuO NPs were more toxic than the ZnO NPs. The negative surface charge on colloids of extracellular polymeric substances (EPS) was reduced by Cu ions but not by CuO NPs; the EPS protected cells from CuO NPs-toxicity. CuO NPs-toxicity was eliminated by a Cu ion chelator, suggesting that ion release was involved. Neither NPs released alkaline phosphatase from the cells’ periplasm, indicating minimal outer membrane damage. Accumulation of intracellular reactive oxygen species was correlated with CuO NPs lethality. Environmental deposition of NPs could create niches for ion release, with impacts on susceptible soil microbes. 相似文献
87.
88.
Salbutamol is a potent β2-adrenergic receptor agonist widely used in the treatment of bronchial asthma and chronic obstructive pulmonary disease. An increasing number of studies have detected salbutamol in natural water systems worldwide. Studies have shown that sunlight degrades salbutamol resulting in the formation of products; some showing higher toxicity to bacteria Vibrio fischeri than the parent compound. In this contribution, steady-state absorption and emission techniques, high-performance liquid chromatography, and transient absorption spectroscopy are used to investigate the photochemistry of salbutamol in aqueous buffer solutions at controlled pH values. Ground- and excited-state calculations that include solvent effects are performed to guide the interpretation of the experimental results. Salbutamol is sensitive to UVB light absorption in the pH range from 3 to 12, forming products that absorb light at longer wavelengths than the parent compound. Quantum yields of degradation reveal that the deprotonated species is 10-fold more photo-active than the protonated species. In line with this result, the fluorescence quantum yield of the protonated species is more than an order of magnitude higher than that of the deprotonated species. Transient absorption spectroscopy shows that population of the triplet state occurs with a rate constant of 7.1 × 108 s−1 in the protonated species, while a rate constant of 1.7 × 1010 s−1 is measured for the deprotonated species. While degradation of the deprotonated species is not affected by the presence of molecular oxygen, a twofold increase in the photodegradation yield of the protonated species in air-saturated conditions is observed. 相似文献
89.
火电厂CO2减排技术主要包括燃烧前处理、燃烧中减排及燃烧后捕集三类。介绍了IGCC、富氧燃烧、胺吸收法、生物法等CO2捕集与封存技术,分析其存在问题及应用前景。 相似文献
90.
本研究利用红外光谱(FTIR)、扫描电镜(SEM)和X射线粉末衍射(XRD)观察了共沉淀法合成羟基磷灰石(HAP)的形貌及其晶型结构,并探讨了Ca/P摩尔比、反应时间及反应温度等因素对羟基磷灰石吸附水中氟离子性能的影响。结果表明,n(Ca/P)=1.5/1、反应时间1 h、反应温度40℃、陈化时间48 h、煅烧温度200℃、煅烧时间2 h时,HAP除氟效果最佳,吸附效率和吸附容量分别达到68.8%和6.88 mg/g。实验数据Langmuir等温模式拟合效果优于Freundlich模式,热力学参数计算可知,HAP对氟离子的吸附是自发(ΔG00),吸热(ΔH00),熵增(ΔS00)的过程。HAP对氟离子的吸附符合拟二级反应动力学过程。 相似文献