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排序方式: 共有232条查询结果,搜索用时 31 毫秒
91.
Jonatas S. RomanoMariane S. Miranda Meiri B.R. OliveiraFlávio A. Rodrigues 《Journal of Cleaner Production》2011,19(11):1224-1228
Metals can be stabilized into cement matrix by solidification/stabilization process. Rice hull is an agricultural residue containing about 10-20% (weight) of silica. It can be used to synthesize β-Ca2SiO4, an important component of Portland cement. Furthermore it is possible to prepare β-Ca2SiO4 doped with heavy metals. Here we describe the synthesis of β-Ca2SiO4 doped with zinc and the behavior of mortars prepared using this material. Products were analyzed by X-ray diffraction, differential thermal analysis and scanning electron microscopy coupled to energy-dispersive spectroscopy. The maximum amount of zinc that can be inserted into β-Ca2SiO4, without affecting the crystalline structure, is limited to 2% (molar basis). In comparison with conventional mortars, zinc-modified mortars show a similar behavior, regarding porosity, resistance to acidic attack and compressive strength. The synthesis of β-Ca2SiO4 doped with zinc presents a new possibility for safety enhancement in solidification/stabilization processes. 相似文献
92.
93.
《International Journal of Sustainable Engineering》2013,6(4):240-247
ABSTRACTThe biogas constituting majorly CH4 and CO2 has been produced by Ca(OH)2 pre-treated wheat straw with pre-digested cow dung. Some of the key thermodynamic parameters like specific heat capacity, density and heating capacity of the biogas produced have also been calculated per day as well as throughout the hydraulic retention time. The governing equations of biogas with appropriate phase and interfacial conditions describing the physics of the biogas have been derived. The control volume approach has been used to predict the total volume (ml) of biogas, CH4 and CO2 throughout the experiment and on the daily basis. The effects of feedstock, temperature and pressure on the production of biogas, CH4 and CO2 in anaerobic digestion have also been studied. The average number of molar fraction and conversion ratio of CH4 and CO2 are correlated with number of carbon atoms available in feedstock. Numerical calculations by using developed model and Modified Gompertz model have shown proficient agreement with the experimental observations. 相似文献
94.
Yuan Cheng Qinqin Yu Jiumeng Liu Youwen Sun Linlin Liang Zhenyu Du Guannan Geng Wanli Ma Hong Qi Qiang Zhang Kebin He 《Frontiers of Environmental Science & Engineering》2022,16(2):18
95.
Abstract A series of mesocosms was exposed to a suite of light treatments and nutrient enrichment in order to generate algal communities of varying biomass. the influence of this biomass on the speciation of copper (II) was studied. Distribution coefficients ( Kd,Lkg?1) were relatively high (log Kd = 5 to 7), indicative of robust trace metal sequestration, and were likely controlled by the particulate organic carbon content (foc). Differences in Kd over time and among treatments were significant, as was the relationship between Kd and foc. Fluorescence quenching was used to determine binding capacities ( Lt , M) and their associated binding constants ( Kcond ,M?1) in order to model the solid phase copper speciation. the Kcond ranged between 2.1 and 5.2 × 1012M?1, indicating a very strong copper-ligand complex, and was higher in mesocosms that received more light. the light Lt increased over time, dramatically after the nutrient enrichment, but did not vary systematically among light treatments. Lt ranged from 7.2 × 10? 7 to 4.9 × 10? 5 M. the large magnitudes of Kd , Kcond and Lt ensured that greater than 97% of total copper in the mesocosms was complexed by organic matter. the total copper concentration ([Cu]T, M) needed to reach a target dissolved copper concentration of 10?12.5 M (pCu = 12.5) was determined for each mesocosm over time. [Cu]T was between 8.02 × 10?5 and 3.41 × 10?2 M, and increased over time. the [Cu]T normalized to the target pCu (Effective Dose Ratio, EDR) increased directly with increases in algal biomass, indicating a direct link between system productivity and copper exposure. Approximately 45% of the variance in EDR was explained by variance in total biomass, while the residual variance in EDR was due likely to differences in the strengths of particle associations and magnitude of binding capacities. 相似文献
96.
Motomu Toda Masayuki Yokozawa Akihiro Sumida Tsutomu Watanabe Toshihiko Hara 《Ecological modelling》2009
A simulation study was carried out to investigate simultaneously the effects of eco-physiological parameters on competitive asymmetry, self-thinning, stand biomass and NPP in a temperate forest using an atmosphere–vegetation dynamics interactive model (MINoSGI). In this study, we selected three eco-physiological relevant parameters as foliage profiles (i.e. vertical distribution of leaf area density) of individual trees (distribution pattern is described by the parameter η), biomass allocation pattern in individual tree growth (χ) and the maximum carboxylation velocity (Vmax). The position of the maximal leaf area density shifts upward in the canopy with increasing η. For scenarios with η < 4 (foliage concentrated in the lowest canopy layer) or η > 12 (foliage concentrated in the uppermost canopy layer), a low degree of competitive asymmetry was produced. These scenarios resulted in the survival of subordinate trees due to a brighter lower canopy environment when η < 4 or the generation of spatially separated foliage profiles between dominant and subordinate trees when η > 12. In contrast, competition between trees was most asymmetric when 4 ≤ η ≤ 12 (vertically widespread foliage profile in the canopy), especially when η = 8. In such cases, vertically widespread foliage of dominant trees lowered the opportunity of light acquisition for subordinate trees and reduced their carbon gain. The resulting reduction in carbon gain of subordinate trees yielded a higher degree of competitive asymmetry and ultimately higher mortality of subordinate trees. It was also shown that 4 ≤ η ≤ 12 generated higher self-thinning speed, smaller accumulated NPP, litter-fall and potential stand biomass as compared with the scenarios with η < 4 or η > 12. In contrast, our simulation revealed small effects of χ or Vmax on the above-mentioned variables as compared with those of η. In particular, it is notable that greater Vmax would not produce greater potential stand biomass and accumulated NPP although it has been thought that physiological parameters relevant to photosynthesis such as Vmax influence dynamic changes in forest stand biomass and NPP (e.g. the greater the Vmax, the greater the NPP). Overall, it is suggested that foliage profiles rather than biomass allocation or maximum carboxylation velocity greatly govern forest dynamics, stand biomass, NPP and litter-fall. 相似文献
97.
Xiangyu Yang Qiang He Fucheng Guo Xiaobo Liu Yi Chen 《Frontiers of Environmental Science & Engineering》2021,15(6):138
98.
This paper reports the results of gasification tests using a catalytic fluidized bed gasifier to obtain a H2-rich stream by feeding different pellets made of wood, biomass/plastic and olive husks to the gasifier. The effects of both the steam supply and an in-bed catalyst on gasifier performance have been investigated. In general, pelletization was an effective pre-treatment for improving the homogeneity of the fuel and the reliability of the feeding devices. The use of biomass/plastic pellets in a catalyst bed yielded good results in terms of the hydrogen concentration (up to 32% vol.), even if an increase in tar production and in the fine/carbon elutriation rate was observed in comparison with wood pellets. 相似文献
99.
Advanced reburning (AR) is effective for nitrogen oxides (NOx) reduction, which integrates the basic reburning (BR) with the injection of nitrogen agents and additive compounds. The basic reburning of poplar, cornstalk, wheat-straw and peanut shell, is studied on a boiler simulator facility (BSF). The influence of operating parameters and the synergistic effect of the injection of ammonia, urea or/and sodium carbonate on NOx reduction are investigated. The results show that an efficiency of 54–67% NOx reduction could be achieved during the basic reburning process under the optimum operating conditions and the efficiency would be increased if nitrogen agent is injected with the over-fire air or into the burnout zone. Further, co-injection of sodium carbonate with the nitrogen agent could make the NOx reduction process more thorough. On the whole, 85–92% NOx reduction could be achieved during the advanced reburning process with a reburning fuel heat input of 15–20%. 相似文献
100.
Fly ash (FA) and bottom ash (BA) from a softwood pellet boiler were characterized and evaluated as soil amendments. In a greenhouse study, two plant species (rye grass, Lolium perenne L. and oats, Avena sativa) were grown in three different treatments (1% FA, 1% BA, non-amended control) of a silty loam soil. Total concentrations of plant nutrients Ca, K, Mg, P and Zn in both ashes were elevated compared to conventional wood ash. Concentrations of Cd, Cr, Pb, Se and Zn were found to be elevated in the FA relative to BA and the non-amended soil. At 28 d, oat above-ground biomass was found to be significantly greater in soil amended with FA. Potassium and Mo plant tissue concentrations were significantly increased by addition of either ash, and FA significantly increased Zn tissue concentrations. Cadmium and Hg tissue concentrations were elevated in some cases. As soil amendments, either pellet ash is an effective liming agent and nutrient source, but high concentrations of Cd and Zn in FA may preclude its use as an agricultural soil amendment in some jurisdictions. Lower ash application rates than those used in this study (i.e. <1%) may still provide sufficient nutrients and effective neutralization of soil acidity. 相似文献