Dyes adsorption using a synthetic carboxymethyl cellulose-acrylic acid adsorbent

Removal of noxious dyes is gaining public and technological attention. Herein grafting polymerization was employed to produce a novel adsorbent using acrylic acid and carboxymethyl cellulose for dye removal. Scanning electron microscopy and Fourier-transform infrared spectroscopy verified the adsorbent formed under optimized reaction conditions. The removal ratio of adsorbent to Methyl Orange, Disperse Blue 2BLN and malachite green chloride reached to 84.2%, 79.6% and 99.9%, respectively. The greater agreement between the calculated and experimental results suggested that pseudo second-order kinetic model better represents the kinetic adsorption data. Equilibrium adsorptions of dyes were better explained by the Temkin isotherm. The results implied that this new cellulose-based absorbent had the universaiity for removal of dyes through the chemical adsorption mechanism.     

Two-step accelerated mineral carbonation and decomposition analysis for the reduction of CO2 emission in the eco-industrial parks

Carbon dioxide（CO2） emissions are a leading contributor to the negative effects of global warming. Globally, research has focused on effective means of reducing and mitigating CO2 emissions. In this study, we examined the efficacy of eco-industrial parks（EIPs） and accelerated mineral carbonation techniques in reducing CO2 emissions in South Korea.First, we used Logarithmic Mean Divisia Index（LMDI） analysis to determine the trends in carbon production and mitigation at the existing EIPs. We found that, although CO2 was generated as byproducts and wastes of production at these EIPs, improved energy intensity effects occurred at all EIPs, and we strongly believe that EIPs are a strong alternative to traditional industrial complexes for reducing net carbon emissions. We also examined the optimal conditions for using accelerated mineral carbonation to dispose of hazardous fly ash produced through the incineration of municipal solid wastes at these EIPs. We determined that this technique most efficiently sequestered CO2 when micro-bubbling, low flow rate inlet gas, and ammonia additives were employed.     

西安市2013年空气质量状况分析

本文收集西安市2013年环境监测站发布的空气质量指数（AQI）及环境空气状况与监测月报资料,对空气质量等级、AQI变化情况、主要污染物浓度变化趋势及采暖期和非采暖期浓度比较进行分析.研究结果表明：西安市2013空气质量二级以上的达标率为37.8％,年均AQI值为151,SO2、NO2、PM10和PM2.5的月监测浓度变化趋势无显著意义,采暖期平均浓度均显著高于非采暖期平均浓度,PM2.5采暖期均值是非采暖期均值的3.09倍.由此可见控制SO2、NO2、PM10和PM2.5的排放是改善西安市空气质量的重点工作.     

乙酰胺低共熔离子液体吸收SO_2的研究

制备了3种乙酰胺-无机盐类低共熔离子液体,测定了其物理性质并将其应用于SO2气体的吸收。结果表明,这些低共熔离子液体具有和传统离子液体相似的性质,例如熔点低、粘度低、密度高、电导率高以及较宽的液态范围。此类离子液体对SO2气体有较好的吸收能力,而且吸收量和温度的关系满足二次多项式方程。红外光谱结果表明吸收是可逆的,回收的离子液体可高效重复使用至少5次。乙酰胺-硫氰酸钠(3∶1)对SO2的质量分数吸收量为0.554 g/g(20℃,1 atm),具有吸收量高、成本低和易回收的优势,是一个很有前景的SO2吸收剂。     

水葫芦与猪粪堆肥化过程CO_2与NH_3释放特征研究

为探讨水葫芦与猪粪在交替式好氧厌氧堆肥作用下CO2与NH3产生与释放特征,将水葫芦、猪粪与木屑以1.7:1.0:0.3(湿重比)的比例混合均匀,进行为期56 d交替式好氧厌氧堆肥化处理。结果表明,交替好氧厌氧条件下水葫芦与猪粪混合堆肥尾气中CO2浓度随堆肥进行先增加后缓慢减少,前14 d CO2释放量占该阶段总有机碳(TOC)减少量的92.75%。NH3的释放浓度随堆肥进行而逐渐降低,堆肥NH3释放浓度与温度变化具有明显相关性。NH3挥发是堆肥氮损失的主要根源,占堆肥过程前14 d总氮(TN)损失的73.79%。     

电力行业碳捕集现状和发展趋势

全面介绍了燃煤电厂3种CO2捕集技术,包括燃烧前捕集,燃烧后捕集以及富氧燃烧捕集技术。通过对各种CO2捕集技术的对比,提出各种捕集方法的适用范围和优、缺点。在此基础上调查了我国碳捕集技术的研究以及碳捕集示范工程项目的进展,分析了我国电力行业碳捕集技术现状和面临的问题并对电力行业碳捕集发展趋势进行了探讨。     

可再生胺类脱硫剂的选择研究

采用哌嗪等二元胺和二乙醇胺为吸收剂,对模拟烟气进行SO2的吸收解吸实验研究,筛选出性能优异的吸收剂,并考察添加剂H2 S O 4对其性能的影响。实验表明:可再生胺类吸收剂脱硫率可接近100%,二元胺吸收剂较醇胺的SO 2吸收量大、pH值随时间变化慢、首次解吸率高;羟乙基支链对胺类吸收剂的抗氧化能力、SO2吸收量和首次解吸率均有影响,环状二元胺比链状二元胺的抗氧化能力好、首次解吸率高;在N-(2-羟乙基)哌嗪溶液中添加硫酸构成N-(2-羟乙基)哌嗪/H 2S O 4脱硫体系后,脱硫率未受影响、SO2吸收量变小、首次解吸率显著提高,具有更好的循环使用性能。     

V2O5/TiO2催化剂脱除NO的研究

采用了等体积浸渍法制备二氧化钛负载钒氧化物催化剂（V2O5/TiO2）,研究了V2O5负载量、反应温度、烟气流量、氨氮比以及运行时间各因素对NH3选择性催化还原NO反应（SCR）效率的影响.研究结果表明：经过500℃温度下煅烧,烟气流量为200ml/min,负载量为7wt％的V2O5/TiO2催化剂,在400℃温度下反应,NO脱除率可达70.5％.     

浙江省污水污泥处理处置状况的调查

通过对丽水、宁波、衢州、诸暨等浙江省境内十几个地区的污水处理厂的调查发现:目前浙江省内的污水处理工艺中,A2/O、A/O、氧化沟三种工艺占了近50%的份额。而SBR因其方法特点正在受到越来越多的重视。在污泥处理工艺中,填埋占了最大的一部分,有近70%的污水处理厂将产生的污泥进行填埋处理。目前,污泥处理技术单一,需要继续探寻污泥的减量和资源化技术,为日益增多的污泥探寻出路。     

丹东市降水pH值及酸雨分析

分析2013年大气降水pH值及近10年历史演变的方法分析丹东市酸雨污染现状、特征,并从污染源和气候条件解释酸雨形成的原因,确定酸雨的形成受外来空气污染物影响较大,而酸雨强度的大小具有本地环境条件和环境污染特征。