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21.
Chengliang Li Andreas Schffer Harry Vereecken Marc Heggen Rong Ji Erwin Klumpp 《环境科学学报(英文版)》2013,25(3):466-472
The aggregation of multi-walled carbon nanotubes (MWCNTs) in the aqueous phase not only inhibits their extensive utilization in various aspects but also dominates their environmental fate and transport.The role of surfactants at low concentration in the aggregation of MWCNTs has been studied,however the effect of perfluorinated surfactants at low concentration is uncertain.To understand this interfacial phenomenon,the influences of perfluorooctanoic acid (PFOA),and sodium dodecyl sulfate (SDS) as a control,on MWCNT aggregation in the aqueous phase were examined by the UV absorbency method.Influences of pH and cationic species on the critical coagulation concentration (CCC) value were evaluated.The CCC values were dependent on the concentration of PFOA,however a pronounced effect of SDS concentration on the CCC values was not observed.The CCC values of the MWCNTs were 51.6 mmol/L in NaCl and 0.28 mmol/L in CaCl 2 solutions,which suggested pronounced differences in the effects of Na+ and Ca2+ ions on the aggregation of the MWCNTs.The presence of both PFOA and SDS significantly decreased the CCC values of the MWCNTs in NaCl solution.The aggregation of the MWCNTs took place under acidic conditions and was not notably altered under neutral and alkaline conditions due to the electrostatic repulsion of deprotonated functional groups on the surface of the MWCNTs. 相似文献
22.
制药废水组成复杂,污染物浓度高,污水CODcr浓度达10000mg/l,含有大量有毒、有害物质。本中采用催化氧化预处理+水解酸化+UASB+接触氧化+炭滤吸附的工艺流程,通过改善细部参数及改良配套设备设计,提高了各单元去除效率,降低了能耗及处理成本,出水CODcr浓度达到污水综合排放标准. 相似文献
23.
水泥行业二氧化碳排放统计——以贵阳市为例 总被引:1,自引:1,他引:0
本文从水泥行业二氧化碳的排放统计出发,研究二氧化碳排放的重要影响因素、二氧化碳排放的指标体系,从而得出一套水泥行业二氧化碳排放统计的核算方法.以贵阳市为例,从三种不同活动水平的统计数据对水泥行业生产工艺过程中产生的CO2排放量进行估算比较,验证统计核算方法的有效性,为贵阳市乃至全国水泥行业CO2的减排提供一个可行的科学依据. 相似文献
24.
Jayant A. Sathaye Kenneth Andrasko 《Mitigation and Adaptation Strategies for Global Change》2007,12(6):971-1000
Climate change programs have largely used the project-specific approach for estimating baseline emissions of climate mitigation
projects. This approach is subjective, lacks transparency, can generate inconsistent baselines for similar projects, and is
likely to have high transaction costs. The use of regional baselines, which partially addresses these issues, has been reported
in the literature on forestry and agriculture projects, and in greenhouse gas (GHG) mitigation program guidance for them (e.g.,
WRI/WBCSD GHG Project Protocol, USDOE’s 1605(b) registry, UNFCCC’s Clean Development Mechanism). This paper provides an assessment
of project-specific and regional baselines approaches for key baseline tasks, using project and program examples. The regional
experience to date is then synthesized into generic steps that are referred to as Stratified Regional Baselines (SRB). Regional
approaches generally, and SRB in particular explicitly acknowledge the heterogeneity of carbon density, land use change, and
other key baseline driver variables across a landscape. SRB focuses on providing guidance on how to stratify lands into parcels
with relatively homogeneous characteristics to estimate conservative baselines within a GHG assessment boundary, by applying
systematic methods to determine the boundary and time period for input data.
相似文献
Kenneth AndraskoEmail: |
25.
Steven De Gryze Juhwan LeeStephen Ogle Keith PaustianJohan Six 《Agriculture, ecosystems & environment》2011,144(1):150-158
We predicted changes in yields and direct net soil greenhouse gas (GHG) fluxes from converting conventional to alternative management practices across one of the world's most productive agricultural regions, the Central Valley of California, using the DAYCENT model. Alternative practices included conservation tillage, winter cover cropping, manure application, a 25% reduction in N fertilizer input and combinations of these. Alternative practices were evaluated for all unique combinations of crop rotation, climate, and soil types for the period 1997-2006. The crops included were alfalfa, corn, cotton, melon, safflower, sunflower, tomato, and wheat. Our predictions indicate that, adopting alternative management practices would decrease yields up to 5%. Changes in modeled SOC and net soil GHG fluxes corresponded to values reported in the literature. Average potential reductions of net soil GHG fluxes with alternative practices ranged from −0.7 to −3.3 Mg CO2-eq ha−1 yr−1 in the Sacramento Valley and −0.5 to −2.5 Mg CO2-eq ha−1 yr−1 for the San Joaquin Valley. While adopting a single alternative practice led to modest net soil GHG flux reductions (on average −1 Mg CO2-eq ha−1 yr−1), combining two or more of these practices led to greater decreases in net soil GHG fluxes of up to −3 Mg CO2-eq ha−1 yr−1. At the regional scale, the combination of winter cover cropping with manure application was particularly efficient in reducing GHG emissions. However, GHG mitigation potentials were mostly non-permanent because 60-80% of the decreases in net soil GHG fluxes were attributed to increases in SOC, except for the reduced fertilizer input practice, where reductions were mainly attributed to decreased N2O emissions. In conclusion, there are long-term GHG mitigation potentials within agriculture, but spatial and temporal aggregation will be necessary to reduce uncertainties around GHG emission reductions and the delivery risk of the associated C credits. 相似文献
26.
The objective of this study was to compare the effects of repeated field applications of three urban compost amendments and one farmyard manure amendment over a 9-year period on aggregate stability in a silty loam soil initially characterized by low clay and initial organic matter contents and poor aggregate stability. Three different aggregate stability tests with increasing disruptive intensities (fast wetting > mechanical breakdown > slow wetting tests) and different disaggregation mechanisms, were used. All of the amendments, which were applied at approximately 4 Mg C ha−1 every other year, increased the organic carbon content and improved the stability of the aggregates against the disruptive action of water, as determined by each of the stability tests. However, the year-to-year variations in the aggregate stability that related to factors other than the organic inputs were greater than the cumulative increase in aggregate stability relative to the control. The positive effects of the tested amendments on aggregate stability were linked to their contribution to soil organic C contents (r = 0.54 for the fast wetting test and r = 0.41-0.42 for the mechanical breakdown and slow wetting tests; p < 0.05). The addition of urban composts had a larger positive effect on aggregate stability than farmyard manure at the majority of sampling dates. The addition of biodegradable immature compost, such as municipal solid waste (MSW), improved the aggregate stability through an enhanced resistance to slaking. The addition of mature composts, such as the co-compost of sewage sludge and green wastes (GWS) or biowaste compost (BW), improved the aggregate stability by increasing interparticular cohesion. The MSW compost was the most efficient in improving aggregate stability during the first 6 years of the experiment (average improvements of +22%, +5% and +28% in the fast wetting, mechanical breakdown and slow wetting tests, respectively, compared to the control treatment); this result was likely due to the larger labile organic pool of the MSW compost that was highly effective at stimulating soil microbial activity. After the first 6 years, the two other composts, GWS and BW, became more efficient (average improvements of +25%, +61% and +33% in the fast wetting, mechanical breakdown and slow wetting tests, respectively, compared to the control treatment), which was probably linked to the greater increase in soil organic C contents. Therefore, the application of urban compost to silty soil that is susceptible to water erosion was effective at improving aggregate stability and thus could be used to enhance the resistance of soil to water erosion. 相似文献
27.
Carbon footprint of food - approaches from national input-output statistics and a LCA of a food portion 总被引:1,自引:0,他引:1
Yrjö Virtanen Sirpa KurppaMerja Saarinen Juha-Matti KatajajuuriKirsi Usva Ilmo MäenpääJohanna Mäkelä Juha GrönroosAri Nissinen 《Journal of Cleaner Production》2011,19(16):1849-1856
The aim of the study, on which this paper is based, was to provide guidance to consumers to make environmentally responsible choices in their food consumption, to assist food supply chain stakeholders to identify the key areas for environmental improvements, and to provide policy makers with a tool for monitoring the potential impacts on climate change resulting from developments within the food sector. At the macro level, the EIO-LCA model was developed specifically for the Finnish food chain; at the micro level, LCAs were performed on 30 lunch portions. The contribution of the Finnish food chain to climate change was 14%, which comprised 40% CO2 emissions, 25% CH4 emissions, and 34% N2O emissions. The share of impacts from domestic agricultural processes was the highest, at 69%. The impact of a single lunch portion ranged between 0.65 and 3.80 kg of equivalent CO2. According to the EIO-LCA model, the average impact was 7.7 kg CO2 eq/person daily. The consumer phase accounted for between 8 and 47% of the climate change impacts for homemade portions. In ready-to-eat portions industry and retail phases were emphasized, representing 25-38% of climate change impacts. We present an approach to steer the Finnish food sector onto an environmentally sustainable path; practical tools for consumers and farmers will especially need to be developed further. 相似文献
28.
TiO2 nanotubes as solid-phase extraction adsorbent for the determination of
polycyclic aromatic hydrocarbons in environmental water samples 总被引:1,自引:0,他引:1
Bochra Bejaoui Kefi Latifa Latrous El Atrache Hafedh Kochkar Abdelhamid Ghorbel 《环境科学学报(英文版)》2011,23(5):860-867
An analytical method based on TiO2 nanotubes solid-phase extraction (SPE) combined with gas chromatography (GC) was
established for the analysis of seven polycyclic aromatic hydrocarbons (PAHs): acenaphtylene, acenaphthene, anthracene, fluorene,
phenanthrene, fluoranthene and pyrene. Factors a ecting the extraction e ciency including the eluent type and its volume, adsorbent
amount, sample volume, sample pH and sample flow rate were optimized. The characteristic data of analytical performance were
determined to investigate the sensitivity and precision of the method. Under the optimized extraction conditions, the method showed
good linearity in the range of 0.01–0.8 g/mL, repeatability of the extraction (RSD were between 6.7% and 13.5%, n = 5) and
satisfactory detection limits (0.017–0.059 ng/mL). The developed method was successfully applied to the analysis of surface water
(tap, river and dam) samples. The recoveries of PAHs spiked in environmental water samples ranged from 90% to 100%. All the results
indicated the potential application of titanate nanotubes as solid-phase extraction adsorbents to pre-treat water samples. 相似文献
29.
30.
Multi-walled carbon nanotube(MWCNT) sheet was fabricated from a drawable MWCNT forest and then deposited on poly(methyl methacrylate) film. The film was further coated with a natural antimicrobial peptide nisin. We studied the effects of nisin coating on the attachment of Bacillus anthracis spores, the germination of attached spores, and the subsequent biofilm formation from attached spores. It was found that the strong adsorptivity and the super hydrophobicity of MWCNTs provided an ideal platform for nisin coating. Nisin coating on MWCNT sheets decreased surface hydrophobicity, reduced spore attachment, and reduced the germination of attached spores by 3.5 fold, and further inhibited the subsequent biofilm formation by 94.6% compared to that on uncoated MWCNT sheet. Nisin also changed the morphology of vegetative cells in the formed biofilm.The results of this study demonstrated that the anti-adhesion and antimicrobial effect of nisin in combination with the physical properties of carbon nanotubes had the potential in producing effective anti-biofilm formation surfaces. 相似文献