流域生态服务市场化补偿管理制度

为平衡流域上下游之间经济发展与环境保护利益的矛盾,解决依赖政府支出补偿能力有限的问题,我国许多地方尝试着在流域生态补偿中引入市场机制,各地涌现出大量的生态服务市场化补偿案例,成为目前中小流域生态服务补偿的有益探索和重要补充。为保障流域生态服务市场的健康发展和有效运行,对其管理制度的研究显得尤为重要。鉴于此,在总结国际生态服务市场管理实践和政策经验的基础上,对我国当前流域生态补偿相关的管理实践、政策和法律制度进行评价,并以此为基础,从管理政策、法律制度和市场机制3个层面,给出我国生态服务市场管理制度的框架设计     

两晋以来气候变化对太湖流域稻麦两熟复种的影响

太湖流域的稻麦两熟复种大约产生于东晋南朝时期（317～589年）,此后这一种植制度长期存在,并不断有所发展。考察发现,此一区域的稻麦两熟在历史上的大多数时候并无突出的季节矛盾,只是有两个时期例外。这两个时期一是明末清初,一是19世纪。太湖流域历史上突出的季节矛盾不由人口、品种等社会原因引起,而由气候变化这一自然因素导致。明末清初和19世纪分别是历史上最为寒冷的时期,是气候变冷造成了这一区域稻麦两熟突出的季节矛盾     

合肥城市绿地系统的景观生态评价

城市绿地作为城市结构中的自然生产力主体,在城市生态系统中起着重要的作用。为科学合理地评价合肥城市绿地系统的景观生态现状,建立较为全面、科学的评价指标体系,运用景观生态学的原理和方法,选取多样性指数、均匀度指数、破碎度指数、分离度指数、分维度指数、连通性指数等8个景观指数对合肥市城市绿地系统的景观格局进行研究和分析。研究结果表明,合肥市城市绿地生态格局总体上较好,绿地率和人均公园绿地面积较高;但也存在绿地分布不均,各种类型相差较大,破碎度较高,多样性程度不高,分形维数指数偏低,绿地景观的自然性和复杂性不够,连通度较低等问题。针对存在的问题,提出了合肥城市绿地景观生态规划的优化建议。研究结果为合肥市城市绿地景观生态系统的规划、设计提供了生态学依据,为“生态园林城市和森林城市”建设提供了理论依据     

面向突发性水污染事件的三维可视化系统

针对突发性水污染事件的突发性、复杂性与潜在的次生衍生危害等特点,设计并开发了面向突发性水污染事件的三维可视化系统。对建设三维可视化系统的需求进行了分析,提出了系统的四层体系结构,基于三维地理信息系统World Wind组件,采用三维可视化环境建模、海量数据缓存机制以及基础地理信息集成等信息技术,开发了系统的基本应用与高级应用,将系统应用到2005年发生在松花江流域的突发性水污染事件中。实例表明:所设计的三维可视化系统具有集成性、可扩展性和较好三维表现力等特点,支持海量数据与复杂应用的集成与三维展示,为突发性水污染事件的空间模拟和决策支持提供支撑。     

山区沿河公路水毁危险性评价方法的研究

为了预测评价山区沿河公路水毁灾害,通过理论分析和专家系统调查,阐明了沿河公路水毁危险性的含义,确定了其主要危险因子(洪水流量、水位、流速)和次要危险因子(洪水持续时间、河流形态)。运用灰色系统的关联度方法,根据关联序确定了各危险因子的权重;在因子等级划分的基础上,提出了沿河公路水毁危险性指数的计算方法,并在工程中得到了应用。研究成果可供沿河公路水毁易发段危险性点及整个路段的评价参考。     

Plutonium isotopes concentration in seawater and bottom sediment off the Pacific coast of Aomori sea area during 1991-2005

A radioactivity survey was launched in 1991 to determine the background levels of ^239+240Pu in the marine environment off a commercial spent nuclear fuel reprocessing plant before full operation of the facility. Particular attention was focused on the ²⁴⁰Pu/²³⁹Pu atom ratio in seawater and bottom sediment to identify the origins of Pu isotopes. The concentration of ^239+240Pu was almost uniform in surface water, decreasing slowly over time. Conversely, the ^239+240Pu concentration varied markedly in the bottom water and was dependent upon the sampling point, with higher concentrations of ^239+240Pu observed in the bottom water sample at sampling points having greater depth. The ²⁴⁰Pu/²³⁹Pu atom ratio in the seawater and sediment samples was higher than that of global fallout Pu, and comparable with the data in the other sea area around Japan which has likely been affected by close-in fallout Pu originating from the Pacific Proving Grounds. The ²⁴⁰Pu/²³⁹Pu atom ratio in bottom sediment samples decreased with sea depth. The land-originated Pu is not considered as the reason of the increasing ^239+240Pu concentration and also decreasing the ²⁴⁰Pu/²³⁹Pu atom ratio with sea depth, and further study is required to clarify it.     

Cs, Pu concentrations and the Pu/Pu atom ratio in a sediment core from the sub-aqueous delta of Yangtze River estuary

A sediment core collected from the sub-aqueous delta of the Yangtze River estuary was subjected to analyses of ¹³⁷Cs and plutonium (Pu) isotopes. The ¹³⁷Cs was measured using γ-spectrometry at the laboratories at the Nanjing University and Pu isotopes were determined with Accelerator Mass Spectrometry (AMS), measurements made at the Australian National University. The results show considerable structure in the depth concentration profiles of the ¹³⁷Cs and ^239+240Pu. The shape of the vertical ¹³⁷Cs distribution in the sediment core was similar to that of the Pu. The maximum ¹³⁷Cs and ^239+240Pu concentrations were 16.21 ± 0.95 mBq/g and 0.716 ± 0.030 mBq/g, respectively, and appear at same depth. The average ²⁴⁰Pu/²³⁹Pu atom ratio was 0.238 ± 0.007 in the sediment core, slightly higher than the average global fallout value. The changes in the ²⁴⁰Pu/²³⁹Pu atom ratios in the sediment core indicate the presence of at least two different Pu sources, i.e., global fallout and another source, most likely close-in fallout from the Pacific Proving Grounds (PPG) in the Marshall Islands, and suggest the possibility that Pu isotopes are useful as a geochronological tool for coastal sediment studies. The ¹³⁷Cs and ^239+240Pu inventories were estimated to be 7100 ± 1200 Bq/m² and 407 ± 27 Bq/m², respectively. Approximately 40% of the ^239+240Pu inventory originated from the PPG close-in fallout and about 50% has derived from land-origin global fallout transported to the estuary by the river. This study confirms that AMS is a useful tool to measure ²⁴⁰Pu/²³⁹Pu atom ratio and can provide valuable information on sedimentary processes in the coastal environment.     

Detection of tritium sorption on four soil materials

In order to measure groundwater age and design nuclear waste disposal sites, it is important to understand the sorption behavior of tritium on soils. In this study, batch tests were carried out using four soils from China: silty clays from An County and Jiangyou County in Sichuan Province, both of which could be considered candidate sites for Very Low Level Waste disposal; silty sand from Beijing; and loess from Yuci County in Shanxi Province, a typical Chinese loess region. The experimental results indicated that in these soil media, the distribution coefficient of tritium is slightly influenced by adsorption time, water/solid ratio, initial tritium specific activity, pH, and the content of humic and fulvic acids. The average distribution coefficient from all of these influencing factors was about 0.1-0.2 mL/g for the four types of soil samples. This relatively modest sorption of tritium in soils needs to be considered in fate and transport studies of tritium in the environment.     

Depth profile of ²³⁶U/²³⁸U in soil samples in La Palma, Canary Islands

The vertical distribution of the ²³⁶U/²³⁸U isotopic ratio was investigated in soil samples from three different locations on La Palma (one of the seven Canary Islands, Spain). Additionally the ²⁴⁰Pu/²³⁹Pu atomic ratio, as it is a well establish tool for the source identification, was determined. The radiochemical procedure consisted of a U separation step by extraction chromatography using UTEVA^® Resin (Eichrom Technologies, Inc.). Afterwards Pu was separated from Th and Np by anion exchange using Dowex 1x2 (Dow Chemical Co.). Furthermore a new chemical procedure with tandem columns to separate Pu and U from the matrix was tested. For the determination of the uranium and plutonium isotopes by alpha spectrometry thin sources were prepared by microprecipitation techniques. Additionally these fractions separated from the soil samples were measured by Accelerator Mass Spectrometry (AMS) to get information on the isotopic ratios ²³⁶U/²³⁸U, ²⁴⁰Pu/²³⁹Pu and ²³⁶U/²³⁹Pu, respectively. The ²³⁶U concentrations [atoms/g] in each surface layer (∼2 cm) were surprisingly high compared to deeper layers where values around two orders of magnitude smaller were found. Since the isotopic ratio ²⁴⁰Pu/²³⁹Pu indicated a global fallout signature we assume the same origin as the probable source for ²³⁶U. Our measured ²³⁶U/²³⁹Pu value of around 0.2 is within the expected range for this contamination source.     

An occupational exposure assessment of polychlorinated dibenzo-p-dioxin and dibenzofurans in firefighters

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) are unintentional byproducts of combustion and industrial processes. Firefighters face the risk of occupational exposure to PCDD/Fs. Congener-specific analyses of 17 PCDD/Fs were performed on 20 serum samples collected from firefighters and fire scene investigators, and four soot samples that had deposited on the surfaces of the fire helmets and were collected after the firefighters had fought fires. The PCDD/F concentrations on the helmets that were contaminated by being worn at the fire scenes were 63-285 times higher than those on a clean helmet. The median serum PCDD/F concentration of the 16 firefighters (12 pg WHO₂₀₀₅-TEQ g⁻¹ lipid) was not different from those of the males from the general Taiwanese population (9.4 pg WHO₂₀₀₅-TEQ g⁻¹ lipid). However, the median PCDD/F level in the four fire scene investigators (15 pg WHO₂₀₀₅-TEQ g⁻¹ lipid) was higher than those in the male from the general Taiwanese population (Mann-Whitney U test, p < 0.01). Furthermore, the serum samples from the firefighters and fire scene investigators, and the soot samples from the fire scenes presented similarly distinctive PCDD/F profiles that had elevated proportions for 10 PCDF congeners. Limited data indicated that the fire scene investigators were occupationally exposed to PCDD/Fs at the fire scenes. We suggested that the firefighters were not occupationally exposed to PCDD/Fs at the fire scenes due to appropriate protection. However, the fire scene investigators may have had more occupational exposure to PCDD/Fs due to poor protection, and further research must be performed to confirm this.