全文获取类型
收费全文 | 492篇 |
免费 | 20篇 |
国内免费 | 109篇 |
专业分类
安全科学 | 120篇 |
废物处理 | 24篇 |
环保管理 | 72篇 |
综合类 | 220篇 |
基础理论 | 73篇 |
污染及防治 | 67篇 |
评价与监测 | 34篇 |
社会与环境 | 10篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 10篇 |
2022年 | 11篇 |
2021年 | 24篇 |
2020年 | 24篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 16篇 |
2015年 | 25篇 |
2014年 | 17篇 |
2013年 | 27篇 |
2012年 | 23篇 |
2011年 | 21篇 |
2010年 | 15篇 |
2009年 | 19篇 |
2008年 | 21篇 |
2007年 | 44篇 |
2006年 | 29篇 |
2005年 | 33篇 |
2004年 | 25篇 |
2003年 | 32篇 |
2002年 | 31篇 |
2001年 | 18篇 |
2000年 | 27篇 |
1999年 | 18篇 |
1998年 | 19篇 |
1997年 | 16篇 |
1996年 | 7篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 1篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1975年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有621条查询结果,搜索用时 15 毫秒
601.
602.
中国降水酸度和离子浓度的时空分布 总被引:136,自引:7,他引:129
1991~1995年在全国进行了酸雨观测,建立了覆盖全国的具有区域代表性的酸沉降监测网,含271个测站?降水的pH值和电导率在现场采样后立即测量,降水样品的化学分析则在实验室里进行?主要离子SO2-4,NO-3,NH+4,Ca2+浓度的加权均值分别为125.86,19.96,67.89和80.41μeq/L?由离子浓度地理分布图看出,这些离子浓度地理分布状况因离子而异?值得注意的是降水中SO2-4和NO-3浓度,北方非酸雨区甚高于南方酸雨区,这说明降水的酸度并不简单地决定于降水中SO2-4和NO-3的绝对浓度,而决定于这些离子对于Ca2+和NH+4的相对浓度?发现了降水年均pH值低至4的一些地区,此值可能是目前世界年降水酸性最强的地区?文中还对代表性地区1986~1993年降水化学特征进行了分析,结果表明降水的酸度仍在升高? 相似文献
603.
Zhi‐Jun Liu Donald E. Weller David L. Correll Thomas E. Jordan 《Journal of the American Water Resources Association》2000,36(6):1349-1365
ABSTRACT: We measured the base‐flow stream chemistry in all the major physiographic provinces of the Chesapeake Bay drainage basin. The spatial variation of stream chemistry was closely related to differences in geology and land cover among the sampled watersheds. Some stream chemistry variables were strongly affected by geological settings in the watersheds while others were more influenced by land cover. The effects of land cover differed among chemical constituents and regions. Concentrations of Ca2+, Mg2+, pH, total alkalinity, and conductivity were mainly functions of carbonate bedrock, especially in the Great Valley. Nitrate‐N and total dissolved N were closely related to cropland and increased as the percentage of cropland increased. The rate of increase varied from region to region with the highest in the Piedmont. Na+ and Cl? were mainly affected by the percentage of developed area in a watershed, especially in the Coastal Plain and Piedmont. We observed no significant effects of region or land cover on species of phosphorus because samples were collected under base flow conditions and only dissolved forms were measured. Dissolved silicate (DSi) was not related to any other water chemistry variables. DSi increased as developed area decreased and cropland increased in the Coastal Plain, but these patterns were reversed in the Piedmont. There was no consistent pattern in the spatial variation of land cover effects on the reduced forms of N, dissolved organic P, dissolved organic matter, and K+. 相似文献
604.
Effect of atmospheric precipitation on the dissolved loads of the Dongjiang River, China 总被引:1,自引:0,他引:1
IntroductionTheatmosphericprecipitationhaslongbeenrecognizedasprovidinganinputofsubstancetothesurfacewaterandasourceofelementscarriedbyrivers (Stallard ,1981;Meybeck ,1983) .Itisestimatedthatapproximately 3 0 %ofsoluteloadsofworldriversarederivedfromthera… 相似文献
605.
606.
Negative-wave-based leakage detection and localization technology has been widely used in the pipeline system to diminish leak loss and enhance environmental protection from hazardous leak events. However, the fluid mechanics behind the negative wave method has yet been disclosed. The objective of this paper is to investigate the generation and propagation of negative wave in high-pressure pipeline leakage. A three-dimensional computational fluid dynamic (CFD) study on the negative wave was carried out with large eddy simulation (LES) method. Experimentally validated simulation presented the transient wave generation at the leak onset and the comprehensive wave evolution afterwards. Negative wave was proven to be a kind of rarefaction acoustic waves induced by transient mass loss at the onset of leakage. Diffusion due to the density difference at wave fronts drives the negative wave propagation. Propagation of negative wave can be categorized into three states – semi-spherical wave, wave superposition and plane wave, based on different wave forms. The wave characteristics at different states were elucidated and the attenuation effects were discussed respectively. Finally, a non-dimensional correlation was proposed to predict the negative wave amplitude based on pipeline pressure and leak diameter. 相似文献
607.
In case of accidents involving releases of hazardous materials, calculating the gas dispersion is essential for assessing risks. In general, the leaked chemical is assumed to be instantly dispersed to the atmosphere if the leak occurs in the outdoor location. However, a different approach should be made for the incidents when sources are located inside a building. For the indoor release, the gas will be diluted prior to the release to the atmosphere and the gas release from a building to the atmosphere demands the application of another model before the dispersion calculation. The indoor release model calculates average indoor concentration and volumetric flowrate to the exterior. The model is fast and reasonably accurate compared to rigorous but time-consuming computational fluid dynamics (CFD) models. The model results were compared with experimental data, and CFD simulation results both with simple geometry to demonstrate validation and assess the performance of the indoor release model. Lastly, the behavior and effect of mitigation of indoor release were demonstrated by using the model results. 相似文献
608.
609.
610.
A computational model to predict acute aquatic toxicity to the ciliate Tetrahymena pyriformis has been developed. A general prediction of toxicity can be based on three consecutive steps: 1. Identification of a potential reactive mechanism via structural alerts; 2. Confirmation and quantification of (bio)chemical reactivity; 3. Establishing a relationship between calculated reactivity and toxicity. The method described herein uses a combination of a reactive toxicity (RT) model, including computed kinetic rate constants for adduct formation (log k) via a Michael acceptor mechanism of action, and baseline toxicity (BT), modelled by hydrophobicity (octanol-water partition coefficient). The maximum of the RT and BT values defines acute toxicity for a particular compound. The reactive toxicity model is based on site-specific steric and quantum chemical ground state electronic properties. The performance of the model was examined in terms of predicting the toxicity of 106 potential Michael acceptor compounds covering several classes of compounds (aldehydes, ketones, esters, heterocycles). The advantages of the computational method are described. The method allows for a closer and more transparent mechanistic insight into the molecular initiating events of toxicological endpoints. 相似文献