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181.
建立了可同时分析饮用水中铁、铜、镍、锌、钴、镉、锰等过渡金属离子的方法。优化后的离子色谱条件:选用 Dionex IonPac CS5A色谱柱(4 mm×250 mm),以7.0 mmol/L 吡啶-2,6-二羧酸+66 mmol/L KOH+74 mmol/L HCOOH+5.6 mmol/L K2SO4为淋洗液,流速为1.2 mL/min,柱温为30 ℃;以0.5 mmol/L 4-(2-吡啶偶氮)间苯二酚+1.0 mol/L 2-二甲醇胺+0.5 mol/L氨水+0.3 mol/L NaHCO3为衍生液,流速为0.7 mL/min,紫外检测器波长为520 nm。结果表明,该离子色谱柱对以上过渡金属具有很好的保留和分离效果,衍生后的紫外检测手段具有优异的灵敏度和选择性。该方法稳定性良好,连续进样5针的相对标准偏差均小于0.79%;标准曲线线性关系良好,r≥0.998 8;方法检出限低,Fe3+为0.8 μg/L,Fe2+为4 μg/L,Cu2+为0.8 μg/L,Ni2+为3 μg/L,Zn2+为2 μg/L,Co2+为0.9 μg/L,Cd2+为16 μg/L,Mn2+为6 μg/L;检测结果准确,低、中、高3个水平的加标回收率均大于91.5%。该方法适用于环境水体中过渡金属离子的定量分析。  相似文献   
182.
应用气相色谱法测定海水中氯氟烃,海水用Niskin采水器采集,将海水转移玻璃注射器中储藏直到分析。把大约30mL海水引入到一个玻璃气提器中,用高纯氮气将溶解在海水中氯氟烃(CFC's)吹扫出来浓缩在冷捕集器中,然后把捕集器加热,用高纯氮气CFC's送入气相色谱分离柱,CFC's由电子捕获检测器(ECD)检测出。结果表明:该方法快速,灵敏度高,分离效果好,适用于分析测定水体中氯氟烃。  相似文献   
183.
气体检测器及其在环境污染事故应急监测中的应用   总被引:6,自引:0,他引:6  
介绍了常用挥发性有机污染物(VOC)检测器的特性,并阐述了光离子化检测器(PID)的原理,特点及其在环境污染事故应急监测中的应用。  相似文献   
184.
The Earth is continually bombarded by high-energy particles coming from the outer space and the sun. These particles, termed cosmic radiation, interact with nuclei of atmospheric constituents and decrease in intensity with depth in the atmosphere. Measurements of photon and gamma radiation, performed with a Radiameter at 1 m above the ground, indicated dose rates of 50-100 nSv/h.The neutron dose rate was measured with the CR-39 track etch detector calibrated by the CERN-EU high-energy Reference Field (CERF) facility. Correlation between neutron dose rates and altitudes at 36 sites was examined in order to obtain a significant positive correlation coefficient; the resulting linear regression enabled estimation of a neutron dose at particular altitude. The measured neutron dose rate in Osijek (altitude of 89 m, latitude of 45.31° N) was 110 nSv/h.  相似文献   
185.
Concentrations of the natural radionuclides 238U, 226Ra, 232Th and 40K have been measured by γ-ray spectrometry in 796 topsoil samples from the Pearl River Delta Zone (PRDZ) of Guangdong, China. The mean concentrations for 238U, 226Ra, 232Th and 40K were found to be 140 ± 37 Bq kg−1, 134 ± 41 Bq kg−1, 187 ± 80 Bq kg−1 and 680 ± 203 Bq kg−1 dry mass, respectively. These values were all higher than the mean values in soil for China and the world. Outdoor air-absorbed dose rates, calculated from activity concentrations of 226Ra, 232Th and 40K, ranged from 86 to 237 nGy h−1, with a mean value of 165 ± 46 nGy h−1. The corresponding annual outdoor effective dose rate per person was estimated to be between 0.11 and 0.29 mSv y−1, with a mean value of 0.20 ± 0.06 mSv y−1, which was also higher than the world mean value of 0.07 mSv y−1. The radium equivalent activity (Raeq) and the external hazard index (Ir) resulted from the natural radionuclides in soil, were also calculated and found to vary from 230 to 676 Bq kg−1 and from 0.6 to 1.8, respectively. The Raeq and the Ir in all the investigated regions were up to 75% higher than the set limits of 370 Bq kg−1 and 1.0, respectively.  相似文献   
186.
The calibration of scintillation detectors for gamma radiation in a well characterized setup can be transferred to other geometries using Monte Carlo simulations to account for the differences between the calibration and the other geometry. In this study a calibration facility was used that is constructed from bricks of well-known activity concentrations of 40K and of radionuclides from the 238U- and 232Th-series. Transfer of the calibration was attempted to a Marinelli beaker geometry with the detector inside a lead shield and to an in situ application with the detector positioned on a sand bed. In general this resulted in good correspondence (within 5-10%) between the activity concentrations derived using the transferred calibration and activities that were derived by independent measurements. Some discrepancies were identified that were attributed to coincident summing in the natural decay series and interference of radon.  相似文献   
187.
The aim of this work is to determine the radioactivity concentration of 226Ra, 232Th and 40K in sub-surface (0-5 cm) soil samples collected from Awanda, Bikoué, Ngombas in the southwestern region of Cameroon, to assess their contribution to the external dose exposure relative to the United Nation Scientific Committee on Effects of Atomic Radiation (UNSCEAR) data. An HPGe p-type detector coupled to a multichannel analyzer was used to perform measurements and data processing. The activity concentrations of 226Ra varied from 0.06 ± 0.01 to 0.27 ± 0.02 kBq kg−1 with a mean value of 0.13 ± 0.01 kBq kg−1 wet weight. The activity concentrations of 232Th varied from 0.10 ± 0.01 to 0.70 ± 0.05 kBq kg−1 with a mean value of 0.39 ± 0.03 kBq kg−1 wet weight, and 40K concentrations varied from 0.37 ± 0.02 to 1.53 ± 0.11 kBq kg−1 with a mean value of 0.85 ± 0.07 kBq kg−1 wet weight, respectively. The mean value of outdoor annual effective doses were estimated to be 0.48 mSv y−1, 0.39 mSv y−1 and 0.38 mSv y−1 from Ngombas, Awanda and Bikoué, respectively. The studied areas can be said to have a high background radiation level.  相似文献   
188.
In the framework of a 222Rn screening campaign that was carried out in 58 public secondary schools in Galicia (NW Spain), the largest radon-prone area in the Iberian Peninsula, a positive correlation between indoor 222Rn concentration and outdoor gamma exposure rate was obtained. A new approach to the data acquisition in screening surveys was tested, improving the performances of this type of study and gathering useful data for future remedial actions. Using short-period detectors (charcoal canisters) firstly, in order to detect places showing 222Rn concentrations over 400 Bq m−3, the number of locations to be measured with long-period detectors (etched track detectors) is reduced. In this screening campaign, 34% of the schools surveyed presented at least one site exceeding the 400 Bq m−3 recommended action level established by the EU, and 15% had at least one site with 222Rn values over 800 Bq m−3. The maximum value recorded was 2084 ± 63 Bq m−3. These results are discussed and compared with data obtained in schools of several countries with similar geology. Seven schools were also studied for seasonal variations of 222Rn activity concentration. The results were not conclusive, and no significant correlation between season and 222Rn concentration was established. Finally, a continuous 222Rn concentration monitor was placed in the secondary school exhibiting a mean value of the 222Rn concentration very close to 400 Bq m−3. Maximum 222Rn concentration values were found to occur at times when the school was unoccupied.  相似文献   
189.
收尘区脉冲供电对电除尘器收集性能的影响   总被引:2,自引:0,他引:2  
建立了双区电除尘器实验模型,研究了预荷电压、不同供电方式下极板间距、电极型式对双区电除尘器收尘效果的影响.结果表明:随着预荷电压逐渐升高,除尘效率也随之增加,双区除尘效果明显优于单区的除尘效果.脉冲供电对电除尘器的除尘性能影响明显,与直流供电相比,脉冲供电对PM25的分级效率可提高16.9%;在较高的电压时,极板间距为...  相似文献   
190.
随着城市化进程加快,城市热环境发生显著变化,对人类活动造成很大影响。为探究天津市城市热环境时空变化及其影响因素,基于2005—2020年四期Landsat遥感数据,利用辐射传输方程法反演地表温度,计算城市热岛比例指数,用标准差椭圆法分析城市热环境发展和布局,利用地表温度并结合土地利用分类研究城市地物覆盖类型与地表温度的响应关系,并采用地理探测器探究高程、绿地、建筑用地和水体对地表温度变化的影响差异。结果表明:天津市热岛足迹沿主干道由市内六区向环城四区发展,天津城市热环境呈现先增高后降低的趋势;由标准差椭圆分析可知,城市热岛呈现发展主轴维持在东北—西南方向,整体空间格局呈现放射状分布;天津市中心城区建筑用地面积占比逐年增加,水体面积占比逐年降低,各类型地物平均温度排序为:建筑用地>绿地>水体;地理探测器分析表明:NDBI和NDVI是影响地表温度变化的主要因子,NDVI和MNDWI对LST交互作用最强,是城市热环境驱动作用最强的因子组合。  相似文献   
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