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301.
Baba A Ereeş FS Hiçsönmez U Cam S Ozdilek HG 《Environmental monitoring and assessment》2008,139(1-3):277-285
Fifteen bottled mineral waters purchased at random all over Turkey were analyzed for their chemical composition by OPTIMA-2000
ICP-AES Perkin Elmer techniques. Results show a wide spread in the chemical specification of these mineral waters, with differences
in chemical composition observed in the regions being due to the geological environment and the majority of bottled mineral
waters exceeding the pH limit of Turkish drinking water standards. When the concentrations of elements are evaluated, it can
readily be seen that generally there are three types of mineral water in Turkey. The concentrations of Al, B, Ba, Cd, Cu,
Cr, Fe, Mn Pb and Zn in mineral water were compared with the limits established by the Turkish Standard for Natural Mineral
Waters (Turkish Official Gazette 2004); water standards prepared by World Health Organization (2006) and the United States of America Environmental Protection Agency (US EPA) drinking water standards (1993). Such a comparison shows that, except for Ba and Mn, the concentrations of the other heavy metals are lower than the limit
of the US.EPA in Turkey. Some parameters examined were found to comprise strong correlations pair-wise. 相似文献
302.
固相萃取-高效液相色谱法同时测定饮用水中苯胺和联苯胺 总被引:3,自引:0,他引:3
用Waters Oasis MCX固相萃取小柱富集水中的苯胺和联苯胺,以2%氨水-甲醇混合溶液为洗脱液,采用高效液相色谱法DAD检测器在285 nm波长下测定。苯胺和联苯胺分别在0 mg/L~100 mg/L和0 mg/L~10.0 mg/L范围内线性良好,检出限分别为0.3 μg/L和0.1 μg/L,饮用水加标平行测定6次的RSD分别为0.9%和0.3%,回收率分别为98.3%~99.1%和97.6%~102%。 相似文献
303.
以N-(4-异丙基苯基)-N-亚丁基脲分子印迹聚合物为吸附剂,建立了饮用水中苯基脲除草剂的分子印迹固相萃取方法。上样后固相萃取柱依次用2.5mL0.1mol/L盐酸和2.5mL去离子水淋洗,然后氮气吹干,再用1mL含8%乙腈的甲苯溶液淋洗,最后用2mL甲醇洗脱。将建立的方法用于自来水中异丙隆、非草隆、甲氧隆、绿麦隆、枯莠隆、灭草隆、伏草隆、草不隆等8种苯脲类除草剂的测定,除伏草隆和草不隆的回收率较低外,其余6种除草剂的回收率均〉60%。 相似文献
304.
电感耦合等离子体质谱法测定饮用水中15种稀土元素 总被引:2,自引:0,他引:2
采用电感耦合等离子体质谱法测定饮用水中15种稀土元素,采取内标校正法,以Rh、Re、Bi为内标,结合优化仪器条件和干扰校正方程来消除干扰.15种稀土元素的方法检出限为0.000 2μg/L~ 0.003 μg/L,混合标准溶液平行测定的RSD< 6%,饮用水样品的加标回收率为98%~120%. 相似文献
305.
分析了近年来江苏省几起典型的饮用水水源地突发环境事件及其特点,指出,结构性、布局性突发环境事件风险突出,交通运输带来的环境风险仍在凸显,企业非法排污产生的环境风险不小,饮用水水源地监测预警手段不足,联合治水模式尚未形成,流域性环境风险防控机制尚未建立。提出,应开展饮用水水源地突发环境事件风险评估,健全突发环境事件监控预警网络,健全饮用水水源地突发环境事件联防联控机制,加强饮用水水源地突发环境事件应急处置技术研究,加快产业机构调整和备用水源地建设。 相似文献
306.
307.
Concentrations of PFOS, PFOA and other perfluorinated alkyl acids in Australian drinking water 总被引:1,自引:0,他引:1
Perfluorinated alkyl acids (PFAAs) are persistent environmental pollutants, found in the serum of human populations internationally. Due to concerns regarding their bioaccumulation, and possible health effects, an understanding of routes of human exposure is necessary. PFAAs are recalcitrant in many water treatment processes, making drinking water a potential source of human exposure. This study was conducted with the aim of assessing the exposure to PFAAs via potable water in Australia. Sixty-two samples of potable water, collected from 34 locations across Australia, including capital cities and regional centers. The samples were extracted by solid phase extraction and analyzed via liquid chromatography/tandem mass spectrometry for a range of perfluoroalkyl carboxylates and sulfonates. PFOS and PFOA were the most commonly detected PFAAs, quantifiable in 49% and 44% of all samples respectively. The maximum concentration in any sample was seen for PFOS with a concentration of 16 ng L−1, second highest maximums were for PFHxS and PFOA at 13 and 9.7 ng L−1. The contribution of drinking water to daily PFOS and PFOA intakes in Australia was estimated. Assuming a daily intake of 1.4 and 0.8 ng kg−1 bw for PFOS and PFOA the average contribution from drinking water was 2-3% with a maximum of 22% and 24% respectively. 相似文献
308.
A sampling survey investigated the formation of nitrogenous disinfection by-products (N-DBPs) and carbonaceous DBPs (C-DBPs) from pre-chloramination, an increasingly common treatment strategy in China for regulated C-DBP control, followed by subsequent conventional water treatment processes, i.e., coagulation, sedimentation, and filtration. Dihalogenated N-DBPs typically peaked in the summer and early autumn with a relatively higher temperature, with the maximum levels of dichloroacetamide (DCAcAm), dichloroacetonitrile (DCAN), bromochloroacetonitrile, dibromoacetonitrile and dichloroacetone at 1.8, 6.3, 6.0, 2.6 and 1.8 μg L−1 in the finished water, respectively. Also, the levels of all the dichlorinated N-DBPs were correlated with the ratio of dissolved organic nitrogen (DON) to dissolved organic carbon, implying autochthonous DON played an essential role in the formation of these DBPs. In contrast, the yields of trihalogenated DBPs [chloroform (CF), trichloronitromethane (TCNM) and trichloroacetone (TCAce)] appeared not to be significantly affected by seasons. CF and DCAN were the dominant species in trihalomethanes (THMs) and dihaloacetonitriles (DHANs), respectively. Bromine was more readily incorporated into DHANs to form brominated DBPs than THMs during pre-chloramination. Although pre-chloramination can ensure the finished water to meet with the current Chinese THM regulatory limits, the increased levels of TCNM and TCAce may be a new water quality concern. 相似文献
309.
Occurrence of perfluorooctanoate and perfluorooctanesulfonate in the Korean water system: implication to water intake exposure 总被引:1,自引:0,他引:1
Kim SK Kho YL Shoeib M Kim KS Kim KR Park JE Shin YS 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1167-1173
Perfluorinated compounds (PFCs) measured in surface running waters indicated the existence of different emission sources in eight main city basins. The tap water reflected the contamination pattern and levels in their corresponding source water basins. The daily intakes through tap water consumption ranged from <0.01 to 0.73 ng kg−1 d−1 for perfluorooctanoate (PFOA) and <0.01 to 0.08 ng kg−1 d−1 for perfluorooctanesulfonate (PFOS). Tap water intake-derived exposure accounted for 8.6%-101% (for PFOA) and while <10% (for PFOS) of total daily exposure, which was estimated from Korean serum concentrations using a pharmacokinetic model. Our findings indicate that tap water intake could be an important contributor to PFOA exposure in Korean populations; accordingly, additional efforts are necessary to improve the removal efficiency of perfluorinated compounds (PFCs) in the water purification process. However, more fundamentally the aim would be to reduce the discharge of PFCs from potential sources within the basin. 相似文献
310.
新型显色剂2-对氨基苯基-2'-羟基二乙胺与水中挥发酚在碱性条件下,经铁氰化钾作用发生反应,反应产物用乙酸丁酯萃取后在可见紫外分光光度计600 nm波长下比色定量。该方法测定挥发酚在0.001 mg/L~0.100 mg/L范围内线性良好,方法检出限为0.000 8 mg/L,加标回收率为100%。用该方法与4-氨基安替吡啉三氯甲烷萃取分光光度法同时测定实际水样,结果无显著差异。 相似文献