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实验测定了林西矿肥煤样品30~900℃煤自燃全过程热动力学特征参数,得出:TG/DTG曲线显示煤样DTG初始临界温度45℃,干裂温度122℃,活性温度195℃,增速温度265℃,质量极大值温度342℃,着火温度465℃,最大热失重速率温度515℃和燃尽温度690℃;DSC曲线显示,煤样初始放热温度60℃、最大热释放速率温度511℃。结合TG-DTG-DSC曲线综合分析可知,煤温达到510℃左右时煤样反应最剧烈。由煤自燃标志气体测定实验系统得出:煤温130℃后CO,CO 2释放量迅速增加,210℃增加速度下降;CH 4,C 2 H 6含量变化具有规律性且两者变化相近;C 2 H 4出现温度为130℃;C 2 H 4/C 2 H 6比值在190~350℃有较强的规律性,呈上升趋势且上升速度较快;350℃之后,CH 4,C 2 H 6,C 2 H 4体积分数均开始急剧增大;C 2 H 4/CO与C 2 H 4/CO 2变化趋势大致相同,在130~350℃时缓慢增长,达到350℃后比值呈指数形式上升。经拟合曲线,得到活化能的3个突变点温度:70,180,220℃,其中180℃与交叉点温度相吻合。通过以上研究,得到了肥煤自燃全过程的热力学特征参数,为实际生产中防治煤自燃提供了理论依据。 相似文献
115.
Introduction: Exploratory data reduction techniques, such as Factor Analysis (FA) and Principal Component Analysis (PCA), are widely used in questionnaire validation with ordinal data, such as Likert Scale data, even though both techniques are indicated to metric measures. In this context, this study presents an e-survey, conducted to obtain self-reported behaviors between Brazilian drivers (N = 1,354, 55.2% of males) and Portuguese drivers (N = 348, 46.6% of males) based on 20 items from the Driver Behavior Questionnaire (DBQ) on a five-point Likert Scale. This paper aimed to examine DBQ validation using FA and PCA compared to Categorical Principal Component Analysis (CATPCA) which is more indicative to use with Likert Scale data. Results: The results from all techniques confirmed the most replicated factor structure of DBQ, distinguishing behaviors as errors, ordinary violations, and aggressive violation. However, after Varimax rotation, CATPCA explained 11% more variance compared to FA and 2% more than PCA. We identified cross-loadings among the component of the techniques. An item changed its dimension in the CATPCA results but did not change the structural interpretability. Individual scores from dimension 1 of CATPCA were significantly different from FA and PCA. Individual scores from factor 1 of CATPCA were significantly different from FA and PCA. Practical applications: The CATPCA seems to be more advantageous in order to represent the original data and considering data constrains. In addition to finding an interpretable factorial structure, the representation of the original data is regarded as relevant since the factor scores could be used for crash prediction in future analyses. 相似文献
116.
Pool fire is a common form of fire, which is constantly investigated along with the development of fire science and is also comprehensively employed as stable fire sources in examining other fire scenarios such as building and tunnel fires. According to the records in Science Citation Index Expanded database in the Web of Science Core Collection, a total of 1073 articles or reviews related to pool fires have been published from 1966 to 2019. In order to have a better understanding of knowledge structure of this topic and further identify its development history and currently popular concerns, a bibliometric analysis of pool fire research is conducted by means of visualization software VOSviewer and CiteSpace. This work visually provides a comprehensive overview of pool fire research in terms of annual publication output, source journals, productive countries/regions, authors and their cooperation network, subject terms, and reference co-citation analysis. The analysis provides networks of co-cited references, authors, countries, subject terms, and their respective clusters, indicating their ranking in contributions to the pool fire related publications. The results can be applied to enhance the understanding of pool fire research and support further work in this area. 相似文献
117.
This paper mainly studied the influence of particle size distribution on the explosion risk of aluminum powder under the span of large particle size distribution. The measurement was carried out with the 20 L explosion ball and the Hartmann tube. The statistical analysis was used to analyze the relevance between the parameters of explosion risk and the particle size parameters. Test results showed that with the increase of particle size, the sensitivity parameter increases and the intensity parameter deceleration decreases. The effect of particle size change on MEC and MIE of small particle size aluminum powder is relatively small but greater impact on Pm and (dP/dt)m. The small particle size components greatly increasing the sensitivity of the explosion and accelerating the rate of the explosion reaction; while the large particle size component contributes to the maximum explosion pressure. D3,2 particle size dust determines the risk of aluminum powder explosion. 相似文献
118.
Point Sampling Digital Imagery with ‘Samplepoint’ 总被引:1,自引:0,他引:1
Measuring percent occurrence of objects from digital images can save time and expense relative to conventional field measurements. However, the accuracy of image analysis had, until now, not reached the level of the best conventional field measurements. Additionally, most image-analysis software programs require advanced user training to successfully analyze images. Here we present a new software program, ‘SamplePoint,’ that provides the user a single-pixel sample point and the ability to view and identify the pixel context. We found SamplePoint to allow accuracy comparable with the most accurate field-methods for ground-cover measurements. Expert use of the program requires minimal training and its ease of use allows rapid measurements from image data. We recommend SamplePoint for calibrating the threshold-detection level of image-analysis software or for making direct measurements of percent occurrence from digital images. 相似文献
119.
To investigate the effect of temperature on effective diffusion coefficients and retardation factors for Zn and Cd, combined
diffusion and sequential extraction analyses were conducted at 15 ˚C and 55 ˚C. The effective diffusion coefficients of the metals increased up to ten times according to the increased temperature. On
the other hand, the effect of temperature on the retardation factor depended on the retention mechanisms of the metals. The
distribution coefficient for Zn, which was mainly partitioned in the carbonate phase, increased up to two times with the increase
in temperature. On the other hand, the distribution coefficient for Cd, which was mainly partitioned in the exchangeable phase,
was hardly affected by the temperature change. Results of combined diffusion and sequential extraction analysis showed that
the effect of temperature on the heavy metals’ (Zn and Cd) migration through the compacted natural clay was influenced by
the combined effects of the diffusion coefficient and the retardation factor. Additionally, we could also observe the change
in retention mechanism for the metals with the change in pore water concentration. 相似文献
120.
通过计算43种有机磷农药的各种结构参数,运用多元线性回归分析方法比较了适用于有机磷农药色谱保留值的定量关系表达式,建立了有机磷农药结构参数对色谱保留值的QSPR模型.模型分析表明:磷酸酯与硫逐磷酸酯两类有机磷农药的模型非交叉验证相关系数R2分别为0.991和0.998,标准误差SE分别为0.0539和0.2874,交叉验证相关系数Q2分别为0.976和0.990,标准偏差Scv分别为0.086和0.610.在已知磷酸酯与硫逐磷酸酯两类有机磷农药结构参数的情况下,此模型可有助于有机磷农药的色谱分析. 相似文献