水中苦味酸的测定

将水样中的苦味酸氯化后,用ECD气相色谱法测定氯化苦的量,来确定苦味酸的浓度。采用保留时问定性,外标法定量。实验表明,该方法能快速有效地提取并测定水体中的苦味酸。在HP-5毛细管柱上,对苦味酸的氯化产物有较好的分离效果。方法快速、反应较为彻底,灵敏度高、精密度和准确度较好。     

氯气远程监测技术的开发与实践

分析了氯气监测现状及存在问题,介绍了为实现远程监测而开发的局域网的系统组成、性能及效果,并提出了改进建议。     

炼化装置挥发性有机物检测方法介绍

结合石油化工行业生产的实际,介绍一种炼化装置挥发性有机物检测方法,并依据EPA的计算方法对装置的挥发性有机物的泄漏量进行了估算.     

Effect of elevated tropospheric ozone on methane and nitrous oxide emission from rice soil in north India

Physiological changes in crop plants in response to the elevated tropospheric ozone (O₃) may alter N and C cycles in soil. This may also affect the atmosphere-biosphere exchange of radiatively important greenhouse gases (GHGs), e.g. methane (CH₄) and nitrous oxide (N₂O) from soil. A study was carried out during July to November of 2007 and 2008 in the experimental farm of Indian Agricultural Research Institute, New Delhi to assess the effects of elevated tropospheric ozone on methane and nitrous oxide emissions from rice (Oryza sativa L.) soil. Rice crop was grown in open top chambers (OTC) under elevated ozone (EO), non-filtered air (NF), charcoal filtered air (CF) and ambient air (AA). Seasonal mean concentrations of O₃ were 4.3 ± 0.9, 26.2 ± 1.9, 59.1 ± 4.2 and 27.5 ± 2.3 ppb during year 2007 and 5.9 ± 1.1, 37.2 ± 2.5, 69.7 ± 3.9 and 39.2 ± 1.8 ppb during year 2008 for treatments CF, NF, EO and AA, respectively. Cumulative seasonal CH₄ emission reduced by 29.7% and 40.4% under the elevated ozone (EO) compared to the non-filtered air (NF), whereas the emission increased by 21.5% and 16.7% in the charcoal filtered air (CF) in 2007 and 2008, respectively. Cumulative seasonal emission of N₂O ranged from 47.8 mg m⁻² in elevated ozone to 54.6 mg m⁻² in charcoal filtered air in 2007 and from 46.4 to 62.1 mg m⁻² in 2008. Elevated ozone reduced grain yield by 11.3% and 12.4% in 2007 and 2008, respectively. Global warming potential (GWP) per unit of rice yield was the least under elevated ozone levels. Dissolved organic C content of soil was lowest under the elevated ozone treatment. Decrease in availability of substrate i.e., dissolved organic C under elevated ozone resulted in a decline in GHG emissions. Filtration of ozone from ambient air increased grain yield and growth parameters of rice and emission of GHGs.     

Soil hydraulic response to land-use change associated with the recent soybean expansion at the Amazon agricultural frontier

Clearing for large-scale soy production and the displacement of cattle-breeding by soybeans are major features of land-use change in the lowland Amazon that can alter hydrologic properties of soils and the runoff generation over large areas. We measured infiltrability and saturated hydraulic conductivity (Ksat) under natural forest, pasture, and soybeans on Oxisols in a region of rapid soybean expansion in Mato Grosso, Brazil. The forest-pasture conversion reduced infiltrability from 1258 to 100 mm/h and Ksat at all depths. The pasture-soy conversion increased infiltrability from 100 to 469 mm/h (attributed to shallow disking), did not affect Ksat at 12.5 cm, but decreased Ksat at 30 cm from 122 to 80 mm/h, suggesting that soybean cultivation enhances subsoil compaction. Permeability decreased markedly with depth under forest, did not change under pasture, and averaged out at one fourth the forest value under soybeans with a similar pattern of anisotropy. Comparisons of permeability with rainfall intensities indicated that land-use change did not alter the predominantly vertical water movement within the soil. We conclude that this landscape is well buffered against land-use changes regarding near-surface hydrology, even though short-lived ponding and perched water tables may occur locally during high-intensity rainfall on pastures and under soybeans.     

固体径迹探测器与RAD-7测氡仪测定民用建筑工程室内氡浓度的比较

民用建筑工程室内氡的监测方法很多,其中固体径迹探测器法属于国标方法,RAD-7测氡仪法为近年来引进的仪器监测方法。本文对两种方法进行了比较,包括监测方法及原理、比对试验,并分析了2种方法的相关性、一致性和精度,以及两者在民用建筑工程室内氡验收监测的实际应用中的优缺点等,结果表明:以上两种方法从技术角度上讲,各有优点,均能满足一般室内空气中氡浓度的监测要求,虽然可利用固体径迹探测器法累积测量的结果来估算居住者受照剂量,进而评价氡的辐射危害,但因检验周期(至少30 d)过长,所以不适宜于工程检测;比较而言,RAD-7测氡仪的配置参数和测量方式更适宜于民用建筑工程的室内氡监测,已成为目前监测的主要方法,但在实际监测中,还需注意合理设置足够长的采样时间、湿度控制在10%以下、气路中残留气体的冲洗净化以及当初测值接近或超过《规范》规定的限量值时,有必要进一步延长监测时间进行跟踪监测等事项,以保证监测结果准确可靠。     

Combination of steam-enhanced extraction and electrical resistance heating for efficient remediation of perchloroethylene-contaminated soil: Coupling merits and energy consumption

● Coupling merits of SEE and ERH were explored by a laboratory-scale device. ● SEE promotes the soil electrical conductivity and ERH process. ● Preheating soil by ERH improves the soil permeability and SEE. ● Combined method is more energy-efficient for perchloroethylene extraction. In situ thermal desorption (ISTD) technology effectively remediates soil contaminated by dense nonaqueous phase liquids (DNAPLs). However, more efforts are required to minimize the energy consumption of ISTD technology. This study developed a laboratory-scale experimental device to explore the coupling merits of two traditional desorption technologies: steam-enhanced extraction (SEE) and electrical resistance heating (ERH). The results showed that injecting high-density steam (> 1 g/min) into loam or clay with relatively high moisture content (> 13.3%) could fracture the soil matrix and lead to the occurrence of the preferential flow of steam. For ERH alone, the electrical resistance and soil moisture loss were critical factors influencing heating power. When ERH and SEE were combined, preheating soil by ERH could increase soil permeability, effectively alleviating the problem of preferential flow of SEE. Meanwhile, steam injection heated the soil and provided moisture for maintaining soil electrical conductivity, thereby ensuring power stability in the ERH process. Compared with ERH alone (8 V/cm) and SEE alone (1 g/min steam), the energy consumption of combined method in remediating perchloroethylene-contaminated soil was reduced by 39.3% and 52.9%, respectively. These findings indicate that the combined method is more favorable than ERH or SEE alone for remediating DNAPL-contaminated subsurfaces when considering ISTD technology.     

The impact of different voltage application modes on biodegradation of chloramphenicol and shift of microbial community structure

● Presented coupled system enhanced biodegradation of antibiotic chloramphenicol. ● HRT and electrical stimulation modes were key influencing factors. ● Electrical stimulation had little effect on the chloramphenicol metabolic pathway. ● Microbial community structure varied with the voltage application mode. Exoelectrogenic biofilms have received considerable attention for their ability to enhance electron transfer between contaminants and electrodes in bioelectrochemical systems. In this study, we constructed anaerobic-aerobic-coupled upflow bioelectrochemical reactors (AO-UBERs) with different voltage application modes, voltages and hydraulic retention times (HRTs). In addition, we evaluated their capacity to remove chloramphenicol (CAP). AO-UBER can effectively mineralize CAP and its metabolites through electrical stimulation when an appropriate voltage is applied. The CAP removal efficiencies were ~81.1%±6.1% (intermittent voltage application mode) and 75.2%±4.6% (continuous voltage application mode) under 0.5 V supply voltage, which were ~21.5% and 15.6% greater than those in the control system without voltage applied, respectively. The removal efficiency is mainly attributed to the anaerobic chamber. High-throughput sequencing combined with catabolic pathway analysis indicated that electrical stimulation selectively enriched Megasphaera, Janthinobacterium, Pseudomonas, Emticicia, Zoogloea, Cloacibacterium and Cetobacterium, which are capable of denitrification, dechlorination and benzene ring cleavage, respectively. This study shows that under the intermittent voltage application mode, AO-UBERs are highly promising for treating antibiotic-contaminated wastewater.     

2000~2020年长江流域植被NDVI动态变化及影响因素探测

研究植被动态变化并探测驱动其变化的影响因素,对区域生态环境质量监测和林业恢复工程效应评估具有重要现实意义.利用MODIS NDVI数据、基于站点的气象数据、DEM数据、人口密度数据和夜间灯光数据等,结合Theil-Sen Median斜率估计、Mann-Kendall显著性检验、稳定性分析和地理探测器,在多时空尺度下分析2000～2020年长江流域植被NDVI时空演变特征及稳定性,并探测驱动植被NDVI空间分异的主要影响因素.结果表明,2000～2020年长江流域植被NDVI整体呈波动上升趋势.除太湖水系外,其余流域单元植被NDVI均呈上升趋势.长江流域植被NDVI呈上升趋势的面积占84.09%,其中,呈极显著上升和显著上升的区域占53.67%,主要分布在乌江、宜宾至宜昌、嘉陵江、汉江和洞庭湖水系.除金沙江石鼓以上和太湖水系植被NDVI稳定性较差以外,其他流域单元植被NDVI整体较为稳定.海拔是影响各流域单元植被生长的重要因素,而气候因子对金沙江石鼓以上植被NDVI的影响程度最高,人文因子对乌江、湖口以下干流和太湖水系植被NDVI影响最大.长江流域影响因素双因子交互作用均表现为双因子增...