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41.
In order to assess the potential health risks of Hg pollution, total mercury (T–Hg) and methyl mercury (MeHg) concentrations were determined in air, dust, surface soil, crops, poultry, fish and human hair samples from an electronic waste (e-waste) recycling area in Taizhou, China. High concentrations of T–Hg and MeHg were found in these multiple matrices, and the mean concentration was 30.7 ng/m3 of T–Hg for atmosphere samples, 3.1 μg/g of T–Hg for soil, 37.6 μg/g of T–Hg for dust, 20.3 ng/g of MeHg for rice and 178.1 ng/g of MeHg for fish, suggesting that the e-waste recycling facility was a significant source of Hg. The inorganic Hg (I–Hg) levels (0.84 μg/g) in hair samples of e-waste workers were much higher than that in the reference samples. Pearson''s correlation coefficients showed that strong positive correlations (p < 0.01) between hair I–Hg and time staying in industrial area (r = 0.81) and between MeHg and fish consumption frequency (r = 0.91), imply that workers were mainly exposed to Hg vapor through long-time inhalation of contaminated air and dust, while other population mainly exposed to MeHg through high-frequency fish consumption. The estimated daily intakes of Hg showed that dietary intake was the major Hg exposure source, and Hg intakes from rice and fish were significantly higher than from any other foods. The estimated total daily intakes (TDIs) of MeHg for both children (696.8 ng/(kg·day)) and adults (381.3 ng/(kg·day)) greatly exceeded the dietary reference dose (RfD) of 230 ng/(kg·day), implying greater health risk for humans from Hg exposures around e-waste recycling facilities. 相似文献
42.
Naturally-occurring and artificially-induced polyploids have been documented in various fish species but to date no comparison has been reported of the impacts of ploidy on fish biomarker responses to organic pollutants. This study describes effects of ploidy, gender, and dose on biliary fluorescent aromatic compound (FAC) concentrations, hepatic ethoxyresorufin-O-deethylase (EROD) and glutathione S-transferase (GST) activities in one of the most commonly cultured warm-water species, the African catfish Clarias gariepinus. Recently matured male and female diploid and triploid fish were intraperitoneally (i.p.) injected with 0, 5 or 25 mg/kg benzo[a]pyrene (BaP) and liver and gallbladder were sampled 48 hr later. No significant differences were found between ploidies in bile concentrations of 7,8 dihydrodiolbenzo[a]pyrene (7,8D BaP), 1-hydroxybenzo[a]pyrene (1-OH BaP) or 3-hydroxybenzo[a]pyrene (3-OH BaP). However, concentrations of the biliary FACs did differ between males and females at different dose of injection with generally higher concentrations in females at the low dose of BaP and higher concentrations in males at the higher BaP concentration. Hepatic EROD activity did not exhibit gender-dependent difference, whereas it was significantly higher in triploids than diploids. GST activities were not significantly influenced by any of the tested factors. This work advanced our understanding of the role of ploidy, gender, and dose in biotransformation of pollutants in fish. 相似文献
43.
Current political conditions, primarily budgetary uncertainty, and the related reluctance to make funding commitments for
future generations, have raised questions about the costs of conservation and environmental protection that have not previously
been asked. As Federal investments are scrutinized and budgets become ever more constrained, the costs associated with environmental
requirements could begin to be of greater importance and to influence decisions on Federal projects. In response to concerns
about the U.S. Army Corps of Engineers (Corps) spending under the Endangered Species Act (P.L. 93-205) (ESA), a limited investigation
was performed to determine the accuracy of reported Corps expenditures. The investigation showed that, for particular groups
of species, actual conservation costs for threatened and endangered species may be twice the amounts previously reported in
the annual ESA expenditure reporting to the U.S. Fish and Wildlife Service. In light of this finding, the Corps has sought
a means to provide more accurate and consistent reporting of expenditures for addressing threatened and endangered species.
A Species Costs Template (template) has been developed to identify the types and magnitude of costs related to the ESA and
to counteract the impediments (legal, institutional, and practical) to underreporting costs. The template will be used by
the Corps for reporting ESA costs beginning with Fiscal Year 2005 (FY05) (reported in January 2006). Five broad categories
of expenditures (effects determination costs, ESA protection and conservation costs, equipment costs, opportunity costs, and
other species costs) are identified by the template. 相似文献
44.
Shao Nan Li 《毒物与环境化学》2013,95(4):239-245
Responses of gill ATPase and liver esterase of topmouth gudgeon, Pseudorasobora parva under sublethal exposure to glyphosate (WSC 41% as isopropyl amine salt) at 1.0, 5.0 and 25?mg/L and metsulfuron methyl (technical 98.2%) at 0.0095, 0.085 and 0.85?mg/L of water were measured at 8th, 16th, 24th and 65th days of exposure. Two way analysis of variance (ANOVA) followed by least significant difference (LSD) test and parameter estimates indicated a significant inhibitory effect on gill ATPase activity (max. 57%) by metsulfuron methyl and liver esterase activity by glyphosate (max. 43%) as compared to the control, but the differences in the residual activities among the concentration levels of the herbicides were not significant. The activities changed significantly with the sampling times except gill ATPase activity under metsulfuron methyl exposure. In most of the cases, the maximum inhibitory effect on the enzymes was recorded on the 8th day and over-recovering appeared with time. 相似文献
45.
Levels of aromatic hydrocarbons in muscle or plaice and halibut were determined by fluorescence, using the chrysene standard, as recommended by the International Oceanographic Commision, for the analysis of PAH in environmental extracts. Concentrations were highest in muscle of halibut collected at the most contaminated, nearshore site, in the Saguenay Fjord of the St. Lawrence Estuary, compared to other locations further from shore. Although concentrations of fluorescing compounds were not statistically different in plaice, the saturated hydrocarbons displayed unquestionably more biodegradation, with a decrease of n-alkanes and increase of branched aliphatics, at the less contaminated site. Synchronous fluorescence indicated the presence of benzenoid and biphenyl hydrocarbons in the extracted mixtures, while GC-MS-TIC analysis tentatively identified the presence of a series of benzenoid (alkyl benzenes), chlorinated (PCB and DDE), N (trialkylamines) and O (phenols) hydrocarbons. These anthropogenic compounds could derive from petroleum products, surfactants and common products used in industry and households. This study emphasizes the importance of a multispectroscopic approach when investigating complex environmental mixtures. 相似文献
46.
Pilot survey of a broad range of priority pollutants in sediment and fish from the Ebro river basin (NE Spain) 总被引:2,自引:0,他引:2
Lacorte S Raldúa D Martínez E Navarro A Diez S Bayona JM Barceló D 《Environmental pollution (Barking, Essex : 1987)》2006,140(3):471-482
Priority organic pollutants were investigated in sediments and fish collected along the Ebro river basin (NE Spain) to evaluate their occurrence, transport and bioavailability. Sediments were collected in 18 sites and two species of fish were captured in nine sites according to the availability in each area. The sampling sites covered industrial, urban and agricultural areas. Four methods were used to detect 20 organochlorine compounds (OCs), 8 polycyclic aromatic hydrocarbons, 3 organotin compounds, 2 alkylphenols and 40 polybrominated diphenyl ethers (PBDEs) from purified extracts. The contamination pattern was site specific and no downstream increase in concentration of pollutants was observed but rather a generalized low level diffuse pollution. Target compounds were detected in sediments at 0.01 to 2331 microg/kg dry weight, and only OCs and PBDEs were accumulated in benthopelagic fish. Toxicological assessment was performed according to predicted environmental levels and revealed sites where adverse effects could occur. 相似文献
47.
In 1994, the sinking of the ‘Apollo Sea’ off the West coast of South Africa led to the deposition of ca. 2 500 tons of heavy
fuel oil over 150 km of coastline. The impact of the spill on rocky shore invertebrates, rock-pool fish fauna and rock lobsters
was assessed by conducting surveys shortly after the spill, and again two months later. Where possible, results of these surveys
were compared with existing data from before the sinking of the Apollo Sea. Among the fish fauna of rock-pools, changes in
total density of fishes were largely due to changes in the abundance ofClinus superciliosus and were within the range of natural variation for the species and the community as a whole. Community structure of the rock-pool
fish fauna also remained unaffected.
At three of four impacted rocky shore sites no changes could be detected in overall benthic community structure, although
the winkleNodilittorina africana was affected. At the fourth site, a boulder beach, statistical analysis showed distinct differences in community structure
between heavily and lightly contaminated areas, as well as between all areas compared with previously existing data. There
were also significant changes in the lightly oiled areas between the first and second surveys after the spill.
Oil-fouled lobster were found at one of three sites investigated. Ca. 7 % of the seabed in this particular area was polluted.
Antennae and forelegs of almost all lobsters in the vicinity of the oil were fouled. Examination of the gut-contents confirmed
that oil inhibits the ability of lobster to feed. Although there was no evidence that mortalities of lobster were caused by
the spill, growth rates may be reduced by the decreased feeding rate. Overall, the impact of the spill was strikingly less
than might have been predicted from the effects of other oil spills.
Nomenclature: Names of fish species follow Smith & Heemstra (1986). 相似文献
48.
Fish Community Structure as a Measure of Degradation and Rehabilitation of Riparian Systems in an Agricultural Drainage Basin 总被引:7,自引:0,他引:7
/ Assessing the health of ecological components of agroecosystems may be accomplished by examining changes in the drainage basin, which serves as an integrator of the agroecosystem landscape. In this study we examined fish communities in terms of an array of indicators of structure and related these to changes in riparian vegetation and agricultural practice. Evidence suggests management practices designed to foster healthier environments by, for example, reestablishing riparian vegetation were associated with positive impacts on the integrity of the fish community. At the same time, continued intensification of agricultural practices in parts of the drainage basin in recent years likely has had an off-setting influence in overall improvements in agroecosystem health. Assessments of changes in the structure of the fish associations provide the balance sheet by which the counteracting influences can be aggregated and assessed.KEY WORDS: Fish community structure; Riparian system; Agricultural drainage basin 相似文献
49.
Petroleum products are complex mixtures of hydrocarbons. They are important as constituents of fuels and lubricants, and as key raw materials for the chemicals industry. Since there is a potential for accidental releases to the aquatic environment, bioaccumulation of higher hydrocarbons is of concern. Here, the bioconcentration behaviour of two representative hydrocarbons, the dodecane isomers n-dodecane and 2,2,4,6,6-pentamethylheptane (PMH), was investigated in fathead minnows at concentrations in water below their maximum aqueous solubility. The concentration of n-dodecane in fish did not exceed our method limit of detection of 60 μg/kg. In contrast, PMH could be quantified in fish. No significant increase in the ratio of PMH concentrations in fish to water could be detected indicating that an exposure time of 4–10 days is sufficient to approach steady-state. For n-dodecane the upper limit of the bioconcentration factor (BCF) is estimated by dividing the method limit of detection by the exposure concentration and a value of 240 l/kg is derived. For PMH the bioconcentration factor, estimated as the average fish/water concentration ratio during the steady-state part of the experiment, ranges between 880 and 3500 l/kg. The BCFs of both compounds are small compared to their hydrophobicity. Given that both linear and branched hydrocarbons are known to be biotransformed by fish, it appears that efficient metabolism of the test compounds in fathead minnows prevents bioaccumulation. 相似文献
50.
Although filial cannibalism (eating one’s own offspring) occurs in numerous species, including several teleost fishes, its
adaptive value is still not well understood. One often-discussed explanation is that individuals enhance their mass and body
condition by consuming part of their eggs. However, evidence for this assumption is scarce thus far. In this study, male three-spined
sticklebacks (Gasterosteus aculeatus), a species with paternal care, were allowed to care for a batch of eggs or for an empty nest under food-deprived conditions.
All brood-caring males cannibalised at least part of their eggs and thus preserved their initial mass and body condition.
Furthermore, mass as well as body condition was significant positively correlated with the number of cannibalised eggs. In
contrast, empty-nest males that had no possibility to cannibalise eggs significantly lost mass and body condition. This is,
to our knowledge, the first experimentally documented evidence that mass as well as body condition were preserved by filial
cannibalism. 相似文献