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751.
Paper recycling is an environmental important activity that is carried out in all the countries, but during the recycling process a paper waste is produced. Generally these wastes are placed in landfill sites but it is possible to profit it as secondary fuel and raw material in manufacture furnaces.
In this work the combustion of the waste papers with cement and ceramic raw material has been studied with the objective to analyse the interaction of these substances with the emitted pollutants like PAHs and PCDD/Fs.
The results of the study show that the presence of inorganic material produces an increment in the lighter PAH emission but chlorinated compounds are not affected. The PCDD/F emission level found in the combustion of this waste is quite low compared with other wastes subjected to similar conditions. 相似文献
752.
Pinho P Augusto S Martins-Loução MA Pereira MJ Soares A Máguas C Branquinho C 《Environmental pollution (Barking, Essex : 1987)》2008,154(3):380-389
With the aim of determining the main drivers of changes in nitrophytic and oligotrophic macro-lichen communities in an industrial region with a Mediterranean climate, we considered both land-cover types and atmospheric pollutants. We determined the relation between the abundance of nitrophytic and oligotrophic species with environmental factors considering the distance of influence of land-cover types. The results showed that oligotrophic species decreased in the proximity of artificial areas, barren land and agricultural areas, associated with higher concentrations of NO2 and Zn, and Ti, probably dust of industrial and agricultural origin. Nitrophytic species were positively related to all the mentioned land-cover types, and with higher concentrations of Fe and N. Magnesium, probably from ocean aerosols, was negatively related to oligotrophic species and positively to nitrophytic. 相似文献
753.
Cadmium and lead were determined simultaneously in seawater by differential pulse stripping voltammetry (DPSV) preceded by
adsoptive collection of complexes with 8-hydroxyquinoline (oxine) on to a hanging mercury drop electrode (HMDE). In preliminary
experiments the optimal analytical condition for oxine concentration was found to be 2.10−5 M, at pH 7.7, the accumulation potential was −1.1 V, and the initial scannig potential was −0.8 V. The peak potentials were
found −0.652 V for Cd and −0.463 V for Pb At the 60 s accumalation time. The limit of detection (LOD) and limit of quantitatification
(LOQ) were found to be by voltammetry as 0.588 and 1.959 μg l−1 (RSD, 5.50%) for Cd and 0.931 and 3.104 μg l−1 (RSD, 4.10%) for Pb at 60 s stirred accumulation time respectively. In these conditions the most of the seawater samples
are amenable for direct voltammetric determination of cadmium and lead using a HMDE. An adsorptive stripping mechanism of
the electrode reaction was proposed. For the comparison, seawater samples were also analysed by ICP-atomic emission spectrometry
method (ICP-AES). The applied voltammetric technique was validated and good recoveries were obtained. 相似文献
754.
Spectroscopic Distribution of Dissolved Organic Matter in a Dam Reservoir Impacted by Turbid Storm Runoff 总被引:1,自引:0,他引:1
Spectroscopic characteristics of dissolved organic matter (DOM) in a large dam reservoir were determined using ultraviolet
absorbance and fluorescence spectroscopy to investigate spatial distribution of DOM composition after turbid storm runoff.
Water samples were collected along a longitudinal axis of the reservoir at three to four depths after a severe storm runoff.
Vertical profiles of turbidity data showed that a turbid water layer was located at a middle depth of the entire reservoir.
The spectroscopic characteristics of DOM samples in the turbid water layer were similar to those of terrestrial DOM, as demonstrated
by the higher specific UV absorbance (SUVA) and the lower fluorescence emission intensity ratio (F
450/F
500) compared to other surrounding DOM samples in the reservoir. Synchronous fluorescence spectroscopy revealed that higher content
of humic-like DOM composition was contained in the turbid water. Fluorescence excitation–emission matrix (EEM) showed that
lower content of protein-like aromatic amino acids was present in the turbid water DOM. The highest protein-like fluorescence
was typically observed at a bottom layer of each sampling location. The bottom water DOM exhibited extremely high protein-like
florescence near the dam site. The particular observation was attributed to the low water temperature and the isolation of
the local bottom water due to the upper location of the withdrawal outlet near the dam. Our results suggest that the distribution
of DOM composition in a dam reservoir is strongly influenced by the outflow operation, such as selective withdrawal, as well
as terrestrial-origin DOM inputs from storm runoff. 相似文献
755.
NOx分解还原催化研究进展 总被引:1,自引:0,他引:1
介绍和评价了NO_x分解还原的3类催化剂:贵金属催化剂、氧化物催化剂、金属离子置换的分子筛。在NO_x的碳氢化合物选择性催化还原反应(HC-SCR反应)中,同样有3类催化剂,即金属氧化物、贵金属和分子筛。由于Cu-ZSM-5是目前最有希望投入实际使用的一种,故本文重点介绍了它对NO_x的HC-SCR反应的催化机理,以及温度、O_2含量、Cu~(2+)的置换度、不同种类HC及HC含量等各种因素对Cu-ZSM-5的影响,并对其工作台试验进行了评价,指出了其存在的问题及当前的研究热点。 相似文献
756.
不同母质发育的水稻土中铁、锰对甲烷排放的影响 总被引:1,自引:0,他引:1
盆栽结果表明,不同土壤类型铁、锰含量的差异是造成不同土壤类型间甲烷排放量差异甚大的重要因素之一。土壤中铁、锰通过对土壤氧化还原电位及根膜形成的影响而影响甲烷的排放。 相似文献
757.
The paper presents an emission inventory for Cochin, which is a highly industrialized area situated in the southern part of India. A proper emission inventory is very important for planning pollution control programmes, particularly in coastal sites like Cochin, where environmental situations are of growing concern owing to their typical meterorological conditions. In a systematic way the sources are broadly classified as point, line and area sources. The data on emissions from industries, fuel consumption for vehicular and domestic activities along with the respective emission factors are used for estimating the emissions. The study reveals that industrial sources are mainly responsible for emissions of particulate matter, oxides of sulphur and ammonia in the region. Automobiles are the prime sources of hydrocarbons, oxides of nitrogen and carbon monoxide emitting 95%, 77% and 70% respectively of their total emissions, while the contribution from domestic sources is not very significant. 相似文献
758.
建立了氢氧化钠吸收液-离子色谱测定固定污染源废气中氯气的方法。研究采样和分析条件,采用50 mL冲击式吸收瓶,以氢氧化钠为吸收液,利用硫代硫酸钠将样品中的次氯酸完全转化为氯离子,过滤后用离子色谱进行分析。可在采样时选择0.3 μm石英滤膜消除颗粒物干扰,在氢氧化钠吸收液前串联硫酸吸收液消除氯化氢干扰。测试结果显示:氯离子曲线线性关系良好,相关系数为0.999 0;方法检出限为0.02 mg/m3,测定下限为0.08 mg/m3;空白加标的相对标准偏差为0.82%~1.4%,加标回收率为98.0%~107%;实际样品基体加标的相对标准偏差为1.8%~2.7%,加标回收率为98.0%~104%。测试结果表明该方法具有较高的精密度和正确度。 相似文献
759.
New Metal Emission Patterns in Road Traffic Environments 总被引:10,自引:0,他引:10
The increased awareness of traffic as a major diffuse metal emission source emphasizes the need for more detailed information
on the various traffic-related sources and how and where the metals are dispersed. In this study, metal emission patterns
in the road traffic environment were examined from the perspective of different surrounding factors, e.g. the importance of
intersections, deceleration, vehicle speed and traffic density. A total of 148 topsoil samples from 18 south Swedish roads
were analysed (using GFAAS) for traffic-emitted metals, i.e. Cd, Cr, Cu, Ni, Pb, Sb and Zn. The roadside topsoil metal concentrations
were used to examine correlations between metals and surrounding factors. The studied metals were divided into three groups
corresponding to different emission sources: metals from decelerating activities (Cu, Sb and Zn), metals as historical residues
from the combustion of petrol (Pb and Cd), and non-source-specific metals (Cr and Ni). It was found that Cu and Sb, despite
their rather short history as traffic-emitted metals, have increased more than eightfold in roadside soils compared to background
levels. The major source of road traffic related Cu and Sb is brake linings. The significant increase of Cu and Sb in roadside
topsoil stresses the need for metal transport studies as well as effect studies of these metals. Metals emitted due to decelerating
activities were not correlated to elevated concentrations near road junctions. Emission patterns of traffic-related metals
alongside roads are crucial in order to be able to evaluate the optimal localization of storm water treatment ponds. 相似文献
760.
Mitigation of methane and nitrous oxide emissions from drained irrigated rice fields 总被引:23,自引:0,他引:23
One of the important cultural practices that affect methane and nitrous oxide emissions from tropical rice plantations is the water drainage system. While drainage can reduce methane emissions, it can also increase nitrous oxide emissions, as well as reduce yields. In this experiment, four different water drainage systems were compared in a rice field in central Thailand including: (1) continuous flooding, (2) mid-season drainage, (3) multiple drainage and (4) a local method (drainage was done according to local cultural practice) in order to find a system of drainage that would optimize yields while simultaneously limiting methane and nitrous oxide emissions. Methane and nitrous oxide emission were observed and compared with rice yield and physical changes of rice plants. It was found that drainage during the flowering period could reduce methane emission. Interestingly, nitrous oxide emission was related to number of drain days rather than the frequency of draining. Fewer drain days can help reduce nitrous oxide emission. The mid-season drainage and the multiple drainage, with 6.9% and 11.4% reduction in rice yield, respectively, had an average methane emission per crop 27% and 35% lower when compared to the local method. Draining with fewer drain days during the flowering period was recommended as a compromise between emissions and yield. The field drainage can be used as an option to reduce methane and nitrous oxide emissions from rice fields with acceptable yield reduction. Mid-season drainage during the rice flowering period, with a shortened drainage period (3 days), is suggested as a compromise between the need to reduce global warming and current socio-economic realities. 相似文献