Ammonium nitrate thermal decomposition with additives

Runaway reactions present a potentially serious threat to the chemical process industry and the community; such reactions occur time and time again often with devastating consequences. The main objective of this research is to study the root causes associated with ammonium nitrate (AN) explosions during storage. The research focuses on AN fertilizers and studies the effects of different types of fertilizer compatible additives on AN thermal decomposition. Reactive Systems Screening Tool (RSST) has been used for reactivity evaluation and to better understand the mechanisms that result in explosion hazards. The results obtained from this tool have been reported in terms of parameters such as “onset” temperature, rate of temperature and pressure rise and maximum temperature. The runaway behavior of AN has been studied as a solid and solution in water. The effect of additives such as sodium sulfate (Na₂SO₄) and potassium chloride (KCl) has also been studied. Multiple tests have been conducted to determine the characteristics of AN decomposition accurately. The results show that the presence of sodium sulfate can increase the “onset” temperature of AN decomposition thus acting as AN thermal decomposition inhibitor, while potassium chloride tends to decrease the “onset” temperature thus acting as AN thermal decomposition promoter.     

A study of the precursors leading to ‘organisational’ accidents in complex industrial settings

This study aggregates the narrative findings from the investigation of 12 accidents or ‘near hits’ across a wide range of industrial settings to build a catalogue of organisational and cultural precursors to accidents. It was found that many were important factors in multiple events. It is argued that by addressing these potential vulnerabilities using the findings and proposed tools based upon them, organisations undertaking safety related activities will not only develop greater awareness of these deeper-lying issues but should be able to better control the risks associated with them.The precursors have been classified under eight headings and examples of key findings from three of these are presented. Statements providing potential defences against the identified vulnerabilities have been developed which should enable organisations to scrutinise the adequacy of existing expectations or requirements within their business. Probing questions have been developed based on the statements which should allow an assessment to be made as to whether these have been ‘embedded’ in the organisation.It is argued that organisational vulnerability tools should be developed to enable a systematic approach to ‘diagnosing’ incubating precursors. It is also argued that there is the potential for further resilience to be achieved through the use of models of the complex dynamics of socio-technical processes within organisations.     

Male approach and female avoidance as mechanisms of population discrimination in sagebrush lizards

Reproductive isolation and speciation can result from female choice for particular males. Isolation can also result, however, from male mating preferences or from aggressive encounters which then influence mating decisions. In this study, we use laboratory discrimination trials to study the behavioral mechanisms of population discrimination in sagebrush lizards (Sceloporus graciosus). We specifically ask three questions about population-level discrimination: (1) Does it vary in strength in relation to the geographic distance between the populations? (2) Is it more apparent in inter- or intra-sexual interactions? (3) Does it take the form of attraction or avoidance? We ran 890 trials that tested the ability of male and female sagebrush lizards from one population to discriminate their own population from four other populations. In addition, we utilized both sequential and simultaneous-choice designs, which enabled us to distinguish between attraction and avoidance. We found that most population-level discrimination was exhibited by male lizards preferring to associate with particular types of females, as well as female avoidance of particular types of males. The strength and direction of both discriminations depended on the populations compared and on whether the tests were conducted as sequential- or simultaneous-choice tests, producing a complex relationship between geographic distance and behavioral discrimination. Our results suggest that there are roles for male attraction and female avoidance in population discrimination, reproductive isolation, and speciation.     

The application of geographic information systems to geochemical studies in Jamaica

The Centre for Nuclear Sciences (CNS) uses a raster based geographic information system (GIS), integrated with a relational database to store information on point sampled data, including concentrations of over 50 elements and/or ions in a variety of sample materials. These data are filtered in the GIS to create surface layers and are assigned colours according to percentile ranges allowing visual inspection to be used to identify significant features and trends. The database currently contains raster map layers for soils and geologic features, point site data for water and air, and vector data for roads, rivers and streams. While data are still being added to the database interesting results are already being obtained and a few instances where the GIS was used to assist in the data interpretation are reported.     

Environmental and genetic influences on mating strategies along a replicated food availability gradient in guppies (Poecilia reticulata)

Food availability is expected to influence the relative cost of different mating tactics, but little attention has been paid to this potential source of adaptive geographic variation in behavior. Associations between the frequency of different mating tactics and resource availability could arise because tactic use responds directly to food intake (phenotypic plasticity), because populations exposed to different average levels of food availability have diverged genetically in tactic use, or both. Different populations of guppies (Poecilia reticulata) in Trinidad experience different average levels of food availability. We combined field observations with laboratory “common garden” and diet experiments to examine how this environmental gradient has influenced the evolution of male mating tactics. Three independent components of variation in male behavior were found in the field: courtship versus foraging, dominance interactions, and interference competition versus searching for mates. Compared with low-food-availability sites, males at high-food-availability sites devoted more effort to interference competition. This difference disappeared in the common garden experiment, which suggests that it was caused by phenotypic plasticity and not genetic divergence. In the diet experiment, interference competition was more frequent and intense among males raised on the greater of two food levels, but this was only true for fish descended from sites with low food availability. Thus, the association between interference competition and food availability in the field can be attributed to a genetically variable norm of reaction. Genetically variable norms of reaction with respect to food intake were found for the other two behavioral components as well and are discussed in relation to the patterns observed in the field. Our results indicate that food availability gradients are an important, albeit complex, source of geographic variation in male mating strategies.     

Social network theory in the behavioural sciences: potential applications

Social network theory has made major contributions to our understanding of human social organisation but has found relatively little application in the field of animal behaviour. In this review, we identify several broad research areas where the networks approach could greatly enhance our understanding of social patterns and processes in animals. The network theory provides a quantitative framework that can be used to characterise social structure both at the level of the individual and the population. These novel quantitative variables may provide a new tool in addressing key questions in behavioural ecology particularly in relation to the evolution of social organisation and the impact of social structure on evolutionary processes. For example, network measures could be used to compare social networks of different species or populations making full use of the comparative approach. However, the networks approach can in principle go beyond identifying structural patterns and also can help with the understanding of processes within animal populations such as disease transmission and information transfer. Finally, understanding the pattern of interactions in the network (i.e. who is connected to whom) can also shed some light on the evolution of behavioural strategies.     

Onsets of schooling behavior and social transmission in chub mackerel Scomber japonicus

Grouping behavior has various types of antipredator functions. Some of these functions require social transmission of information, such as the many-eyes effect, whereas others do not, such as the dilution and confusion effects. Functions of grouping behavior would enhance with social transmission among group members. We investigated and compared the onsets of schooling behavior and social transmission of information in chub mackerel Scomber japonicus. Onset of schooling behavior was observed in rearing tanks by calculating the degree of parallel swimming. Onset of social transmission was examined by using visual cues from conspecifics. A group of five individuals was put in each of three experimental chambers from which they could see a group of conspecifics in the neighboring chamber. A weak electric stimulus was given to one of these chambers, and information transfer among individuals was observed. We found that social transmission by visual cues started on 30 days posthatching (25.1 mm in standard length), which was 2 weeks after the onset of schooling behavior. The late onset of social transmission relative to schooling behavior might be attributed to different predation pressure with development, or by underdevelopment of optic tectum, as the volume of the optic tectum did not increase just after the onset of schooling behavior.     

Propagation of olfactory information within the honeybee hive

Transfer of information about food source characteristics within insect societies is essential to colony-foraging success. The food odor communicated within honeybee hives has been shown to be important for food source exploitation. When successful foragers return to the nest and transfer the collected nectar to hive mates through mouth-to-mouth contacts (trophallaxis), potential recruits receiving these samples learn the food odor by associative learning. The food then becomes rapidly distributed among colony members, which is mainly a consequence of the numerous trophallaxes between hive-mates of all ages during food processing. We tested whether the distribution of food among hive mates causes a propagation of olfactory information within the hive. Using the proboscis extension response paradigm, we show that large proportions of bees of the age groups representing the main worker castes, 4 to 9-day-old bees (nurse-aged bees), 12 to 16-day-old bees (food processor-aged bees), and actual foragers (about 17+ day old bees) associatively learn the food odor in the course of processing food that has been collected by only a few foragers. Results further suggest that the information is shared more or less equally between bees of the three age groups. This shows that olfactory information about the flower species exploited by foragers is distributed within the entire colony and is acquired by bees of all age groups, which may influence many behaviors inside and outside the hive.     

Populations of Pecos pupfish (<Emphasis Type="Italic">Cyprinodon pecosensis</Emphasis>) differ in their susceptibility to hybridization with sheepshead minnow (<Emphasis Type="Italic">C. variegatus</Emphasis>)

The importance of sexual selection in hybridization between species that evolved in allopatry is poorly understood. Even less is known about differences between populations in their resistance or susceptibility to genetic introgression with a congener. Here we examine behavioral differences between populations of the native Pecos pupfish (Cyprinodon pecosensis) and their potential effects in facilitating or retarding hybridization with an introduced congener, the sheepshead minnow (C. variegatus). We quantified competitive interactions, establishment of territories, and mating success of several naturally occurring C. pecosensis populations and an artificially created laboratory population (control) against C. variegatus. Experiments were conducted in large outdoor tanks during the summer months when high temperatures favor breeding activity in pupfish. C. pecosensis populations differed in agonistic behavior, territoriality, and in mating success when competing against C. variegatus. Differences in the competitive ability of males from different C. pecosensis populations suggest that the rate of introgression with C. variegatus may vary, depending on the population of C. pecosensis it comes in contact with. Our results suggest that large, stable C. pecosensis populations may be relatively resistant to hybridization with C. variegatus. Interpopulation variation in male behavior, shaped by sexual selection, may be important in determining the incidence and rate of hybridization between the two congeners. Experimental studies are a powerful tool in elucidating behavioral processes, such as the action of intrasexual selection, that facilitate or retard the coalescence of lineages through initial hybridization and subsequent genetic introgression after secondary contact between allopatric species.Communicated by M. Abrahams