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161.
Qing Xie Jingwen Chen Jianping Shao Changer Chen Hongxia Zhao Ce Hao 《Chemosphere》2009,76(11):1486-1490
Photolysis of deca-bromodiphenyl ether (BDE-209) was investigated in tetrahydrofuran, dichloromethane, isopropanol, acetone, ethanol, methanol, acetonitrile and dimethylsulfoxide. Noticeable differences of the photolytic rates and quantum yields were found in the diverse solvents. Different to the previous deductions, hydrogen donating efficiency and electron donating efficiency of solvents were not the decisive factors for the photolytic rate in this study, which was proved by the fast photolysis of BDE-209 in CCl4, a solvent without hydrogen and difficult to donate electrons. Besides hydrogen addition process, intermolecular polymerization might occur during the photolysis. Density functional theory (DFT) calculation was performed to understand the molecular properties of BDE-209 in different solvents. The lowest singlet vertical excitation energy (Eex) and the average formal charge on Br () of BDE-209, reflecting the difficulty for the excitation of BDE-209 and for the departing of Br atom, respectively, were changed by the reaction fields formed by the different solvents. Eex and linearly correlated with the photolytic activity (log k). This study is helpful to better understand the photolytic behavior of BDE-209 in different media. 相似文献
162.
Effects of acute γ-irradiation on the aquatic microbial microcosm in comparison with chemicals 总被引:1,自引:1,他引:0
Shoichi Fuma Nobuyoshi Ishii Hiroshi Takeda Kiriko Miyamoto Kei Yanagisawa Kazutaka Doi Isao Kawaguchi Nobuyuki Tanaka Yuhei Inamori Gennady G. Polikarpov 《Journal of environmental radioactivity》2009,100(12):1027-1033
Effects of acute γ-irradiation were investigated in the aquatic microcosm consisting of green algae (Chlorella sp. and Scenedesmus sp.) and a blue–green alga (Tolypothrix sp.) as producers; an oligochaete (Aeolosoma hemprichi), rotifers (Lecane sp. and Philodina sp.) and a ciliate protozoan (Cyclidium glaucoma) as consumers; and more than four species of bacteria as decomposers. At 100 Gy, populations were not affected in any taxa. At 500–5000 Gy, one or three taxa died out and populations of two or three taxa decreased over time, while that of Tolypothrix sp. increased. This Tolypothrix sp. increase was likely an indirect effect due to interspecies interactions. The principal response curve analysis revealed that the main trend of the effects was a dose-dependent population decrease. For a better understanding of radiation risks in aquatic microbial communities, effect doses of γ-rays compared with copper, herbicides and detergents were evaluated using the radiochemoecological conceptual model and the effect index for microcosm. 相似文献
163.
论绿色信贷政策实施效果的评估 总被引:2,自引:0,他引:2
“绿色信贷”是将环保调控手段通过金融杠杆来具体实现的一项环境经济政策。政策的实施效果需要通过一套科学有效的评估体系来保证。从绿色信贷政策实施效果评估制度的建立理念出发,对参与评估的主体、评估的程序、评估管理系统进行论证。 相似文献
164.
165.
在分析交通噪声影响因素的基础上,对乌鲁木齐市近十年控制交通噪声污染的措施和效果进行了探讨。 相似文献
166.
167.
Berghahn R Mohr S Feibicke M Meinecke S Sperfeld E 《Environmental science and pollution research international》2007,14(3):190-193
Goal, Scope and Background One of the advantages of long-term mesocosm experiments as compared to short-term standard toxicity tests in the laboratory
is the potential for detecting secondary effects due to the interaction of species and recovery with biomass of macrophytes
being an important endpoint. However, generating biomass data by harvesting is often laborious, time-consuming, costly and
restricted to the end of the experiment. Moreover, valuable information may get lost, in particular in single application
studies, since maximal primary effects and secondary effects or recovery occur per se at different times. Potamogeton natans was used as an example in order to test whether number and area of floating leaves can be reliably measured and be used as
intermediate and final endpoints in mesocosm effect studies.
Methods Digital photos, which were taken of the water surface in the course of an indoor pond mesocosm study on herbicide effects,
were subjected to image analysis. The results were compared to wet weight and ash-free dry weight of Potamogeton at the end of the herbicide study.
Results and Discussion Both number and area of floating leaves indicated the same herbicide effects as wet weight and ash-free dry weight of Potamogeton. Error introduced by the different work steps is small and can be further minimised by a number of method improvements.
Recommendations and Perspectives In indoor mesocosm studies, errors due to the perspective adjustment may be circumvented by taking the photos perpendicular
to the water surface. Correction for lens aberration, identical light conditions and the use of fluorescence images are considered
promising. Field applications are proposed. 相似文献
168.
169.
在明确FMEA分析方法意义的基础上,本文对某装备进行故障模式及影响分析,并得出相应结论,以有助于该装备的研制与使用。 相似文献
170.
The aim of this work is (1) to discuss approaches and tools to set management goals using operational indicators for coastal management (i.e., indicators that are easy to measure, understand and predict) and validated predictive models and (2) to discuss remedial strategies for sustainable coastal management regarding water quality and the abundance of fish, waterfowl and large aquatic plants. These approaches are exemplified using data from Ringkøbing Fjord, Denmark, which has undergone two major regime shifts during the last decades. This work discusses the changes taken place during the period from 1980 to 2004 (when there are good empirical data). For Ringkøbing Fjord, which is a very shallow, well-oxygenated lagoon dominated by resuspension processes, we have targeted on the following operational indicators, which are meant to reflect seasonal median values for the entire defined coastal area (the ecosystem scale) and not conditions at individual sites or data from shorter time periods: Secchi depth (as a standard measure of water clarity) and chlorophyll-a concentrations (as a key measure of algal biomass). The operational indicators are regulated by a set of standard abiotic factors, such as salinity, suspended particulate matter (SPM), nutrient concentrations (N and P), coastal morphometry and water exchange. Such relationships are quantified using well-tested, general quantitative models, which illustrate how these indicators are interrelated and how they reflect fundamental aspects of coastal ecosystems. We demonstrate that the regime shift in the lagoon can be modelled and quantitatively explained and is related to changes in salinity and nutrient inflow. A very important threshold is linked to increased salinities in the lagoon. For example, when the mean annual salinity is higher than about 9.5‰, large numbers of saltwater species of clams can survive and influence the structure and function of the ecosystem in profound ways. The model also illustrates the dynamic response to changes in nutrient loading. We have presented several management strategies with the goal of keeping the Secchi depth at 2 m, which would stimulate the growth of higher aquatic plants, which are fundamental for fish production and bird abundance in the lagoon. Given the fact that the Secchi depth depends on many variable factors (temperature, TP-inflow from land, salinity, changes in biomasses of macrophytes and clams, which are accounted for in these simulations), our results indicate that in practice it will likely be very difficult to reach that goal. However, it would be realistic to maintain a Secchi depth of 1.5 m if the variability in salinity is minimized and the mean salinity is kept at about 10.2‰. 相似文献