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151.
When plants are observed under a low dose of ozone, some physiological and metabolic shifts occur. Barring extreme injury such as tissue damage or stomata closure, most of these disruptive changes are likely to have been initiated at the level of gene expression. The belief is oxidative products formed in ozone exposed leaves, e.g. hydrogen peroxide, are responsible for much of the biochemical adjustments. The first line of defense is a range of antioxidants, such as ascorbate and glutathione, but if this defense is overwhelmed, subsequent actions occur, similar to systemic acquired resistance or general wounding. Yet there are seemingly unrelated metabolic responses which are also triggered, such as early senescence. We discuss here the current understanding of gene control and signal transduction/control in order to increase our comprehension of how ozone alters the basic metabolism of plants and how plants counteract or cope with ozone.  相似文献   
152.
硫化物水样的稳定性研究   总被引:1,自引:0,他引:1  
对硫化钠水样的制备及其稳定性进行了研究和讨论,找到一种长期稳定保存硫化钠标准溶液及硫化物标准样品的有效方法。  相似文献   
153.
硫化矿物中无机盐及重金属离子溶出的影响因素探讨   总被引:3,自引:0,他引:3  
基于浸泡试验,在不同的时间、温度、酸碱度、固液比等条件下研究硫化矿物中无机盐和重金属离子的溶出反应,得到影响该溶出反应的重要因素,为实际矿业生产过程中硫化矿物的堆放和处理提供了理论依据.  相似文献   
154.
Seasonal measurements of dimethylsulfide(DMS)in surface waters were carried out during 1993-1994 in the Jiaozhou Bay.A seasonal variation is observed for DMS concentrations in seawater,ranging from 0.6 to 8.97 nmol S/L with the highest values in spring.A factor of 4 was measured for DMS concentrations with mean concentrations of 5.85 nmol S/L or 6.58 nmol S/L in spring and 1.40nmol S/L in winter.A sea-to-air flux of DMS also showed a seasonal variation  相似文献   
155.
Amides, a series of significant atmospheric nitrogen-containing volatile organic compounds (VOCs), can participate in new particle formation (NPF) throught interacting with sulfuric acid (SA) and organic acids. In this study, we investigated the molecular interactions of formamide (FA), acetamide (AA), N-methylformamide (MF), propanamide (PA), N-methylacetamide (MA), and N,N-dimethylformamide (DMF) with SA, acetic acid (HAC), propanoic acid (PAC), oxalic acid (OA), and malonic acid (MOA). Global minimum of clusters were obtained through the association of the artificial bee colony (ABC) algorithm and density functional theory (DFT) calculations. The conformational analysis, thermochemical analysis, frequency analysis, and topological analysis were conducted to determine the interactions of hydrogen-bonded molecular clusters. The heterodimers formed a hepta or octa membered ring through four different types of hydrogen bonds, and the strength of the bonds are ranked in the following order: SOH???O > COH???O > NH???O > CH???O. We also evaluated the stability of the clusters and found that the stabilization effect of amides with SA is weaker than that of amines with SA but stronger than that of ammonia (NH3) with SA in the dimer formation of nucleation process. Additionally, the nucleation capacity of SA with amides is greater than that of organic acids with amides.  相似文献   
156.
To ensure the safety of drinking water, ozone (O3) has been extensively applied in drinking water treatment plants to further remove natural organic matter (NOM). However, the surface water and groundwater near the coastal areas often contain high concentrations of bromide ion (Br?). Considering the risk of bromate (BrO3?) formation in ozonation of the sand-filtered water, the inhibitory efficiencies of hydrogen peroxide (H2O2) and ammonia (NH3) on BrO3? formation during ozonation process were compared. The addition of H2O2 effectively inhibited BrO3? formation at an initial Br? concentration amended to 350 µg/L. The inhibition efficiencies reached 59.6 and 100% when the mass ratio of H2O2/O3 was 0.25 and > 0.5, respectively. The UV254 and total organic carbon (TOC) also decreased after adding H2O2, while the formation potential of trihalomethanes (THMsFP) increased especially in subsequent chlorination process at a low dose of H2O2. To control the formation of both BrO3? and THMs, a relatively large dose of O3 and a high ratio of H2O2/O3were generally needed. NH3 addition inhibited BrO3? formation when the background ammonia nitrogen (NH3N) concentration was low. There was no significant correlation between BrO3? inhibition efficiency and NH3 dose, and a small amount of NH3N (0.2 mg/L) could obviously inhibit BrO3? formation. The oxidation of NOM seemed unaffected by NH3 addition, and the structure of NOM reflected by synchronous fluorescence (SF) scanning remained almost unchanged before and after adding NH3. Considering the formation of BrO3? and THMs, the optimal dose of NH3 was suggested to be 0.5 mg/L.  相似文献   
157.
电Fenton法处理难降解有机物的研究进展   总被引:21,自引:1,他引:21  
评述了电Fenton法在水处理的中的应用状况及国内外研究现状,介绍了各种电Fenton法进行机理及存在的优缺点,并对其今后的发展趋势进行了阐述。  相似文献   
158.
臭氧氧化法处理城市污水厂出水的实验研究   总被引:3,自引:0,他引:3  
赵璇  苏欣捷 《上海环境科学》1999,18(11):497-498
为了开发污水的回用技术,对北京市某污水处理厂二处理后出水中含有的有机物进行了臭氧无催化氧化、臭氧碱催化氧化、臭氧/过氧化氢氧化和臭氧加过渡性金属离子/过氧化氢催化氧化工艺的实验研究。结果表明,自氧/过氧化氢氧化工艺达到了较好的效果,在H2O2=3mg/L时投加臭氧13mg/L,CODcr由45mg/L降至20mg/L。  相似文献   
159.
福建省梅仙式块状硫化物矿床   总被引:1,自引:0,他引:1  
梅仙式铅锌矿床是在大陆裂谷环境下形成的,有明显的块状硫化物矿床特征。矿化受震旦系龙北溪组绿片岩控制。矿体里似层状,与围岩产状一致。绿片岩原岩是一套含板内拉斑玄武岩的火山沉积建造。矿物组合和 Zn/Pb比值有分带性。层状矿体下盘有脉状、网脉状矿化和蚀变带。矿石有特征的结构构造。硫以幔源为主,铅是幔壳混合成因,矿液以海水成因为主.可能有少量雨水、岩浆水等渗入,反映物质的多来源和成矿受多种地质事件的叠加改造。本式矿床可与火山岩容矿型的加拿大新不伦瑞克省的块状硫化物矿床类比,也可作为广义华南型的一个亚型。  相似文献   
160.
针对H2S浓度为750~1500mg/m3的气体的液相催化氧化技术进行了动力学实验研究。配制了以铁基离子作为主催化剂的复合吸收净化溶液,同时加入稳定剂和表面活性剂提高催化剂在碱性吸收溶液的活性。分别考察了原料气中H2S、O2含量以及吸收液中催化剂离子浓度、温度等因素对吸收速率的影响;确定了较为理想的吸收操作条件并获得了较好的吸收净化效果;饱和吸收液易于再生,净化性能恢复良好,可重复使用。  相似文献   
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