微波消解法快速测定渗滤液化学需氧量

针对国标回流法测定化学需氧量消耗时间长,分析费用高等不足,研究了微波消解法测定垃圾渗滤液的试验方法.通过微波消解功率、消解时间、催化剂用量等试验,确定了微波消解测定渗滤液CODCr的最佳条件.该方法具有省时间、省试剂、准确度高等优点.     

提高企业信任度,改善安全生产人文环境

在安全规章制度中往往只规定下级的安全责任,并未对领导责任做出具体规定,缺乏权利义务的对等性,导致企业安全管理成一纸空文,落实不下去,存在着严重的形式主义.由于企业规章制度持续性和稳定性不足,存在朝令夕改的现象,导致企业在安全生产工作方面产生信任度危机,所以员工在安全生产过程中总是在揣测领导的真正意图以决定自己的行为.因此,提倡将企业内部纵向的信任研究引入到安全管理领域.     

工科学生工程安全素质培养的探索与实践

高等学校工科学生的社会职业定位是工程师,工程师的主要工作是从事工程的规划、设计、实施、运行和管理,其工程行为对工程安全具有至关重要的影响。随着现代工程向大型化、综合化和复杂化方向发展,工程安全已成为人类社会面临的重大问题,解决工程安全问题的根本途径之一是加强和改进高等工程教育,致力于提高工科学生的工程安全素质培养。对工科学生的工程安全素质培养,各高校可根据自己的专业优势和服务需求面而独具特色,以适应社会对工程安全人才多样性要求。湖南科技大学在工科学生的培养中,从培养目标的改革中加强了对工程安全素质的要求;从培养内容的改革中加强了对工程安全知识的传授;从培养方法的改革中加强了对工程安全技能的训练;各项改革中的措施在实践中取得令人满意的效果。     

北京山区公路地质灾害应急与防治对策

北京是地质灾害较严重的城市之一,具有灾种多、活动频繁、群发性强的特征。北京山区公路所遭受的地质灾害主要有滑坡、滑(崩)塌、泥石流、岩溶、采空地面塌陷等。为了防止山区公路地质灾害可能造成的危害,笔者通过对北京山区公路所遭受的地质灾害类型、发育特征、分布规律等特点及其所造成的危害进行分析、研究,提出了山区公路地质灾害应急与防治对策,以提高北京市的防灾减灾能力,减少和避免地质灾害造成的损失。     

泵串联水灭火系统在森林防火方面的应用

现阶段为了适应国际及国内防火形势,出现了以水灭火为主要形式的灭火方式,并且在实际灭火中体现出巨大的优势.其中泵串联水灭火就是一种很好的形式.林海集团设计了一套远距离接力水泵串联供水灭火系统,尝试以手抬水泵(消防泵)接力供水的方式,从有水源的地方经过消防泵的增压,通过消防水带输送到火场,为水灭火工作提供条件,以实现水灭火.     

石油化工生产火灾隐患及预防对策

石油化工企业自身的生产、设备等特点决定了这类企业存在着一些特有的火灾隐患,这些隐患给安全生产带来了极大的威胁.因此,正确剖析和认识石油化工企业特有的火灾隐患,积极采取预防对策是石油化工企业安全工作的一项重要内容.     

Modeling of n-butane ignition, combustion, and preflame oxidation in the 20-l vessel

The objective of the study reported herein is to simulate various physical and chemical phenomena accompanying fuel-rich n-butane–oxygen mixture preparation, ignition, preflame oxidation, and combustion in the standard 20-l explosion vessel, by applying mathematical models. Based on the computational fluid dynamics (CFD) simulations of the mixing process and natural convection of the ignition kernel, as well as on the analysis of the detailed reaction mechanism of n-butane oxidation, laminar flame propagation, and self-ignition, possible explanations for the phenomena observed experimentally have been suggested. The results of the study indicate that seemingly inflammable mixtures can become hazardous depending on the mixture preparation procedure and forced ignition timing.     

Time series in M dimensions: The one-dimensional case: Pollution in the Chicago Sanitary and Ship Canal

A nonstationary time-series model is used to examine the changes occurring at sampling stations on the Chicago Sanitary and Ship Canal. Using data from upstream sampling sites, downstream levels of dissolved oxygen, total dissolved solids, nitrates and nitrites, and ammonia are accurately predicted. The method is simple, insensitive to extreme values, and responsive to changes in the system.     

DESK TOP METHODOLOGY FOR MODELING BIOCHEMICAL OXYGEN DEMAND IN STREAMS1

: The modeling of dissolved oxygen in streams is a widely used technique, upon which a great deal of money has been spent. This paper concludes that the standard methods of DO modeling by computer are unnecessarily complex, and that for some purposes, they can be replaced without loss of accuracy by desk top BOD models. Taking as an example, a set of data used in DO modeling, it is shown (a) that the data are grossly inconsistent, (b) that simultaneous gathering of data introduces errors in streams of long travel time, (c) that much more data as to pollutant concentrations should have been obtained, and (d) that 24-hour DO data could have been dispensed with.     

Metabolic fate of the 14C-labeled herbicide clodinafop-propargyl in soil

The metabolic fate of ¹⁴C-phenyl-labeled herbicide clodinafop-propargyl (CfP) was studied for 28 days in lab assays using a soil from Germany (A_p horizon, silt loam, and cambisol). Mineralization amounted to 12.40% of applied ¹⁴C after 28 days showing a distinct lag phase until day 7 of incubation. Portions of radioactivity extractable by means of 0.01 M CaCl₂ solution (bioavailable fraction) decreased rapidly and were 4.41% after 28 days. Even immediately after application, only 57.31% were extracted with the aqueous solvent. Subsequent extraction using accelerated solvent extraction (ASE; acetonitrile/water 4:1, v/v) released 39.91% of applied ¹⁴C with day 0 and 26.16% with day 28 of incubation from the samples. Non-extractable portions of radioactivity thus, increased with time amounting to 11.99% (day 0) and 65.00% (day 28). A remarkable increase was observed between 14 and 28 days correlating with the distinct increase of mineralization. No correlation was found throughout incubation with general microbial activity as determined by DMSO reduction. Analysis of the CaCl₂ and ASE extracts by radio-TLC, radio-HPLC and GC/MS revealed that CfP was rapidly cleaved to free acid clodinafop (Cf), which was further (bio-) transformed; DT₅₀ values (based on radio-TLC detection of the parent compound) were far below 1 day (CfP) and about 7 days (Cf). TLC analysis pointed to 2-(4-hydroxyphenoxy)-propionic acid as further metabolite. Due to fractionation of non-extractable residues, most of the ¹⁴C was associated with fulvic and humic acids, portions in humin fractions and non-humics were moderate and low, respectively. Using a special strategy, which included pre-incubation of the soil with CfP and then mineralization of ¹⁴C-CfP as criterion, a microorganism was isolated from the soil examined. The microorganism grew using CfP as sole carbon source with concomitant evolution of ¹⁴CO₂. The bacterium was characterized by growth on commonly used carbon sources and by 16S rDNA sequence analysis. The sequence exhibited high similarity with that of Rhodococcus wratislaviensis (99.56%; DSM 44107, NCIMB 13082).