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101.
某金属冶炼厂周围居民人发的6种元素含量特征 总被引:3,自引:1,他引:2
为研究金属冶炼对人体健康的危害水平,利用原子吸收分光光度计和AFS-930型原子荧光光度计对浙江富阳郊区某金属冶炼厂周围部分人发的6种元素Cu、2n、Pb、Cd、As、Se含量进行了测定.结果表明,研究区居民人发样品中具有较高含量,其中Cu、Zn、Pb和Cd最高含量分别达312、513、700和7.41 μg·g-1, As和Se最高量达10.08和0.85 μg·g-1.人发中Cu、Zn、Pb、Cd、As含量呈明显相关关系,这在一定程度上反映了人发中元素污染程度的相似来源可能是小高炉冶炼.不同年龄的人发元素含量分析表明,40岁以上人发中Cu、Pb、Cd、As平均含量高于40岁以下约2倍;不同性别的人发元素含量分析表明, Cu、Zn、Cd、Se没有多大差别, Pb和As表现为男性略高于女性,但是经统计检验各元素在年龄和性别差异上均不显著. 相似文献
102.
Abimbola AF Kehinde-Phillips OO Olatunji AS 《Environmental geochemistry and health》2007,29(2):163-167
The aim of this study was to assess the heavy metal content of the dust generated by the Sagamu cement factory and its attendant
health hazards on the immediate environment, especially on the inhabitants of the area. A total of 25 samples were collected
and analyzed using inductively coupled plasma-optical emission spectrometry. Records of medical ailments associated with heavy
metal toxicity were also compiled from the Obafemi Awolowo Teaching Hospital situated in the town.The results for some of
the selected heavy metals showed the following pattern: limestone: Cd (n.d.-1.7 ppm), Pb (42–48 ppm), Cu (3.0–11 ppm), Zn
(7.0–53 ppm) and Ni (3.0–8.0 ppm); shale: Cd (0.3–1.1 ppm), Pb (17–22 ppm), Cu (2.0–11 ppm), Zn (17–147 ppm) and Ni (3.0–18 ppm);
dusts: Cd (0.5–0.7 ppm), Pb (32–52 ppm), Cu (2–16 ppm), Zn (5–152 ppm) and Ni (2–17 ppm); soils: Cd (0.5–1.1 ppm), Pb (28–49 ppm),
Cu (22–35 ppm), Zn (43–69 ppm) and Ni (13.0–17 ppm). High levels of heavy metals were found in the rocks and soils. We propose
that the high levels of metals in the dust and soil were acquired from the raw materials used by the cement factory and from
active industrial discharge from this same factory. Medical records and the current health situation of the local residents
in the study area reveal that there have been increases in the prevalence of diseases linked to heavy metal toxicity in the
environment, especially those related to dust generation. 相似文献
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106.
采用生物滴滤工艺对某药厂硫代纯化车间的高浓度丙酮废气进行中试规模的处理运行。现场风量在3000~4000 m^3/h范围波动,丙酮质量浓度在0~2278 mg/m^3范围波动。在39 d的运行期间,丙酮的平均脱除效率为78%,最高可达100%;系统的平均单位去除负荷为139.2 g/(h·m^3),最高可达482.1 g/(h·m^3)。在高浓度高波动的进气工况条件下,单位生物矿化量可以保持相对稳定的水平,波动范围为11.5~27.3 g/(h·m^3),生物系统的稳定性和鲁棒性较好。循环液COD与进气负荷具有一定的相关性。 相似文献
107.
M. Farghaly F. Mahdy H. Taha U. Fathy 《Journal of environmental science and health. Part. B》2013,48(6):655-662
Sound whole-seed faba beans were treated with (methyl-14C) fenitrothion [O, O-dimethyl-O-(3-methyl-4-nitrophenyl) phosphorothioate] at 5 and 10 mg insecticide/kg seeds, a dose normally used in practice. During the 30 weeks of storage period, the penetration and distribution of insecticide residues were studied. The amount of surface residues, internal residues and bound insecticide residues was estimated. Surface residues were found to decrease with the increase in time of storage, whereas internal residues showed a gradual increase with time apparently not dose dependent. Grain-bound residues increased with time and reached to its maximum (14–18%) after 24 weeks of storage. Chromatographic analysis of the internal extracts revealed the presence of the parent compound together with three main metabolites which were found in both free and conjugated form. Feeding mice for 90 days with a diet mixed with total internal fenitrothion residues in stored faba beans led to a reduction in body weight gain, and an appreciable decrease in cholinesterase activity of 32% for plasma and 15% for red blood cells (RBCS) after two months of experiment. Also, a significant decrease was showed in both total protein and albumin concentration at the end of feeding period (90 days). Liver and kidney function, as well as lipid profile of treated mice significantly increased at the end of feeding period. After a one-month recovery period, all the examined blood parameters returned to about the control values except blood urea and serum triglyceride. 相似文献
108.
Feo ML Eljarrat E Manaca MN Dobaño C Barcelo D Sunyer J Alonso PL Menendez C Grimalt JO 《Environment international》2012,38(1):67-72
Presence of pyrethroid insecticides in human breast milk and in thatch wall material of dwellings from Southern Africa subtropical area (Manhiça, Mozambique) was investigated to assess potential pyrethroid route of human exposure. Human breast milk samples were collected during 2002 when pyrethroids were widely used as insecticides for mosquito bed nets in Mozambique for malaria control. The median concentration value of total pyrethroids ranged between 87 and 1200 ng/g lw, with λ-cyhalothrin being the most predominant pyrethroid in human breast milk contributing for 35% of the total amount. Moreover, and for the first time, an isomer-specific enrichment was found in human breast milk, showing a selective isomeric accumulation or metabolism in the human body. Based on the calculated pyrethroid concentrations in human breast milk, the daily ingestion rate of pyrethroid was estimated. The nursing infant dietary intake ranged from 0.67 to 9.0 μg (kg of body weight)− 1 day− 1. In addition, thatch materials collected after the reintegration of dichlorodiphenyltrichloroethene (DDT) as insecticide residual spraying (IRS) in Mozambique, showed the presence of pyrethroids with concentration values ranging between 6.9 and 700 ng/g dw. In thatch material as well as in human breast milk, pyrethroid contamination was mainly attributed to the agriculture usage of this insecticide knowing that agriculture represent the 80% of the economy in Mozambique. However, a possible usage of this insecticide as IRS in Mozambique cannot be excluded despite their low efficiency for malaria control. The continued use of these compounds (both for agriculture and malaria prevention) and the ingestion rates calculated from the breast milk concentrations indicate that these insecticides cannot be overlooked for the assessment of the lactation risks of breastfeeding infants from the Manhiça region. 相似文献
109.
Susceptibility of epigeic earthworm Eisenia fetida to agricultural application of six insecticides 总被引:1,自引:0,他引:1
Ecotoxicological risks of agricultural application of six insecticides to soil organisms were evaluated by acute toxicity tests under laboratory condition following OECD guidelines using the epigeic earthworm Eisenia fetida as the test organism. The organochlorine insecticide endosulfan (LC50 - 0.002 mg kg−1) and the carbamate insecticides aldicarb (LC50 - 9.42 mg kg−1) and carbaryl (LC50 - 14.81 mg kg−1) were found ecologically most dangerous because LC50 values of these insecticides were lower than the respective recommended agricultural dose (RAD). Although E. fetida was found highly susceptible to the pyrethroid insecticide cypermethrin (LC50 - 0.054 mg kg−1), the value was higher than its RAD. The organophosphate insecticides chlorpyrifos (LC50 - 28.58 mg kg−1), and monocrotophos (LC50 - 39.75 mg kg−1) were found less toxic and ecologically safe because the LC50 values were much higher than their respective RAD. 相似文献
110.