Sediment Parameters of Northwest Black Sea Shelf and Slope: Implications for Transport of Heavy Metals and Radionuclides

In June 1990, sediment cores were obtained from several locations in the Northwest Black Sea shelf and slope by a joint US/USSR scientific team aboard the survey vessel R/V VODYANITSKY. the goal of this investigation was to determine the distribution and levels of radioactivity resulting from the Chernobyl 1986 nuclear accident. the sediment was characterized for texture, mineral composition, redox state, heavy metals, and radionuclides. Correlations emerging from these data reveal paths of dispersal and transport of materials from river sources to deposition sites on the shelf and slope. Kaolinite in the clay mineral suite clearly reflects a dispersal pattern originating in the Danube River and progressing in an easterly direction across the shelf. Sand-size gypsum and the elemental heavy metals Zn, Cu, Cr, and Pb (probable industrial source) as well as the elements Al and Mg (probable terrigenous source) also show a dispersal pattern from the Danube station location in an easterly direction across the shelf. the dispersal direction indicated by these materials is not in conflict with recent existing notions concerning the hydrology of the Northwest Black Sea. Barium anomalies at a midshelf location may be related to operations in the Lebada oil fields situated updrift. Heavy mineral dispersal reflect the Danube and -Crimean Provinces established for the shelf and relate to terrestrial source areas. in addition, the heavy mineral monazite correlates with the radioactive Th 232 found most abundantly in the Crimean Province. Local anomalies of Mn, Fe and U in the sediment at station locations are related to redox (Eh) conditions and other factors. Cs^134/137 data, reported by Curtis and Broadway (1991), correspond to transport and dispersal patterns implicit in the mineralogic, anthropogenic indicators, and sediment characteristics of the study area.     

Seasonal and pluri-annual variability of sediment accumulation and organic matter fluxes in the Northwestern Adriatic shelf and its relationship with the frontal system

Twenty eight short sediment cores, collected along six transects in two areas influenced by the frontal system formed by the Po River, were analysed for Th and Cs in order to improve our knowledge on short time scale sediment deposition, accumulation and mixing. Sedimentological and mineralogical parameters were also analysed._ The decreasing Cs activities and C/N values in surface sediments indicate a decreasing input of terrestrial material during the study period. Furthermore, low excess thorium activities and inventories at some sites, together with low sedimentary organic matter concentrations in the southern area, suggest that the productivity in summer 1997 was lower than in 1996. Temporal and spatial shifts of the front exert a strong influence on short time scale deposition of particulate matter in the northern area, while the front position is more stable in the southern area, influencing both seasonal and interannual deposition._ The comparison between apparent seasonal and pluri-annual accumulation rates suggests, for the northern area, a sedimentation pattern characterized by temporal deposition of material on to the sea floor, with periodical resuspension. The net apparent accumulation is 0.1-0.4 r g r cm r yr. The same occurs for the southern area, where values are higher, probably due to the longer persistence of the frontal system in the same area over the years. Here, both seasonal and pluri-annual deposition showed the same pattern, but seasonal values were two to three times higher with a net apparent accumulation rate of 0.3-0.8 r g r cm r yr. Organic carbon and nitrogen concentrations are generally less than 1.3 and 0.2% d.w., with lower values in the southern area. By contrast, mass fluxes showed higher values in the southern area, while the rate of removal over a pluri-annual time scale is generally high.     

Distribution,biomass and ecology of meso-zooplankton in the Northern Adriatic Sea

Two oceanographic cruises were carried out in the northern Adriatic Sea, from June, 1996 to February, 1997. Samples were collected using a BIONESS electronic multinet (204 samples on 54 stations) along inshore-offshore sections. Zooplankton abundance and biomass were estimated in relation to the variability of temperature, salinity and fluorescence. Spatial and vertical distribution patterns of the most important zooplankton groups were studied. During June, in the northern area, abundance and biomass of 2787 - 1735 r ind m and 29.3 - 26.7 r mg r m, respectively, were reported. The zooplankton community was constituted essentially by copepods and cladocerans. In the southern area, instead, an abundance of 4698 - 5978 r ind r m and a dry weight of 25.4 - 15.3 r mg r m were observed, with a reverse dominance ratio between these groups. In February, in the northern area the zooplankton community (1380 - 595 r ind r m and 19.6 - 9.9 r mg r m) was mainly constituted by copepods, larvae of invertebrates, appendicularians and cladocerans; in the southern area zooplankton average abundance was 969 - 493 r ind r m and 9.9 - 3.2 r mg r m being copepods, cladocerans, appendicularians and larvae of invertebrates. The zooplankton spatial distribution, in this period, did not show the classic inshore-offshore gradient. Spatial distribution and biomass values of zooplankton, in the northern Adriatic Sea, were strongly influenced by hydrological characteristics, allowed up to formulate a preliminary model about distribution, along the water column, of the different associations of species assemblages with regard to different water masses in the neritic system.     

Modelling the reworking effects of bioturbation on the incorporation of radionuclides into the sediment column: implications for the fate of particle-reactive radionuclides in Irish Sea sediments

A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a ¹³⁷Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data. The average biodiffusion coefficient, at 1.8 ± 0.9 cm² y⁻¹, is in good agreement with the values quoted by other workers on the bioturbation effects of this polychaete species. The corresponding value for the biotransport coefficient was found to be 0.9 ± 0.4 cm y⁻¹. The effects of non-local mixing were incorporated in a model to describe the temporal evolution of measured ⁹⁹Tc and ⁶⁰Co radionuclide sediment profiles in the eastern Irish Sea, influenced by radioactive waste discharged from the Sellafield reprocessing plant. Reworking conditions in the sediment column were simulated by considering an upper mixed layer, an exponentially decreasing diffusion coefficient, and appropriate biotransport coefficients to account for non-local mixing. The diffusion coefficients calculated from the ⁹⁹Tc and ⁶⁰Co cores were in the range 2-14 cm² y⁻¹, which are consistent with the values found by other workers in the same marine area, while the biotransport coefficients were similar to those obtained for a variety of macrobenthic organisms in controlled laboratories and field studies.     

Reprint of: ‘Heimat’ as a boundary object? Exploring the potentialities of a boundary object to instigate productive science-stakeholder interaction in North Frisia (Germany)

The North Frisian Wadden Sea represents one of the best researched natural regions in the world. Since the end of the 1980s, scientific research has been carried out to scientifically study, analyse and assess this intertidal coastal zone under the conceptual umbrella of ecosystem research. The outcome of this assessment materialised in the establishment of the Nationalpark Schleswig-Holsteinisches Wattenmeer. Its implementation caused considerable conflicts between coastal inhabitants, national park authorities and government officials. Arguments in these disputes revolved around the validity and relevance of scientific knowledge generated to assess and legitimately protect the tidelands and areas of the Waddensea. In summary, the whole implementation process was locally perceived as a politically endorsed top-down enforcement strategy only allowing scientific knowledge for decision-making purposes while local concerns and ‘knowledges’ were not included. To learn from these developments and past mistakes, we compare concepts of co-management, boundary work and boundary objects (BO) to theoretically and methodologically explore their potentials to generate shared meanings and instigate communication in the context of future managing purposes. Against this theoretical background, we propose the empirical show-case example of the German concept of ‘Heimat’ as a BO to assess its applicability to study place-based meanings and to illustrate it as a practice-oriented point of entry to initiate productive science-stakeholder interaction (SSI) in managing the North Frisian Wadden Sea.     

渤海区域生态补偿机制的研究

生态系统方法是保护和管理自然资源的新理念，得到世界各海洋大国的普遍关注和认可。生态系统方法要求运用生态补偿机制。构建海洋生态补偿机制的基本思路是：①根据海洋生态系统服务功能变化及其对利益相关者的影响界定补偿主体和补偿对象：②补偿途径以财政转移支付和环境资源税费为主；③遵循理论计算值与现有实践相结合的原则制定补偿标准。围绕影响渤海生态系统健康的关键是人类活动．提出了构建渤海区域生态补偿机制的初步设想。主要包括：改革现有“排污收费制度”。提高收费标准，增强制度的生态补偿效力。以减少陆源污染物排海；建立流域和海域之间的用水生态补偿机制。以增加入海淡水量；推广“退渔还湿”的生态补偿政策；加大资金投入．强化现有渔业生态补偿政策；以同区域内的土地价格为参照。对围海造地收取生态补偿金。     

Species of the Month: Anti-Whaling,Mediated Visibility,and the News

Paul Watson, founder of the Sea Shepherd Conservation Society and captain of anti-whaling ship the Steve Irwin, has emerged as one of the world's most visible environmental protesters. This essay, based in part on a long interview with Watson in Australia in 2009, analyzes his mediated visibility and thus capacity to participate in public debate by isolating various components of his strategic activities under four themes: mediated protest, symbolic power, media practices, and celebrity. It argues that Watson's visibility involves a complex flow of information and meanings across various “old” and “new” media form, but remains reliant on news media. Thus, despite his generally astute media practices and strategies, Watson's visibility is contingent on a set of professional practices and logics unlikely to provide sustained news access or long-term legitimacy to a political “outsider.”     

Productive science–policy interactions for sustainable coastal management: Conclusions from the Wadden Sea area

In this paper we synthesise the findings from the papers in this special issue on Organising productive science-policy interactions for sustainable coastal management. Lessons from the Wadden Sea. We first briefly discuss some relevant theoretical debates, and then present our main insights and lessons from the empirical evidence reported in the papers. We conclude the paper with suggestions for further research.     

HEAVY METAL DISTRIBUTION AND SPECIATION IN THE NORTHERN ADRIATIC SEA

In the present study the concentrations of cobalt, copper, iron, manganese, zinc were analysed and the speciation of copper and zinc performed, with a summer and winter sampling, for two areas in the Northern Adriatic Sea and crossing at the farthest zones of the Po river-sea water interface. Results show that when salinity increases the concentrations of all investigated metals (with the exception of cobalt) present some degree of biogeochemical cycling. Copper is the element whose dissolved phase has the highest importance in metal transport across the salinity gradient. Results of speciation analysis demonstrate that the presence of excess amounts (5-8 fold) of unbound ligands confers a buffering capacity for potential inputs of dissolved metals into the Northern Adriatic Sea. The speciation of both copper and zinc in the dissolved phase was dominated by organic complexation.