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361.
The main object of the study was the development of a long-term efficient and inexpensive in-situ immobilization technology for uranium (U) and arsenic (As) in smaller and decentralized groundwater discharges from abandoned mining processing sites. Therefore, corrosion of grey cast iron (gcFe) and nano-scale iron particles (naFe) as well as hydrogen stimulated autotrophic sulphate reduction (aSR) were investigated. Two column experiments with sulphate reducing bacterias (SRB) (biotic gcFe , biotic naFe) and one abiotic gcFe-column experiment were performed. In the biotic naFe column, no particle translocation was observed and a temporary but intensive naFe corrosion indicated by a decrease in E(h), a pH increase and H(2) evolution. Decreasing sulphate concentrations and (34)S enrichment in the column effluent indicated aSR. Fe(II) retention could be explained by siderite and consequently FeS precipitation by geochemical modeling (PhreeqC). U and As were completely immobilised within the biotic naFe column. In the biotic gcFe column, particle entrapment in open pore spaces resulted in a heterogeneous distribution of Fe-enriched zones and an increase in permeability due to preferential flow. However, Fe(II) concentrations in the effluent indicated a constant and lasting gcFe corrosion. An efficient immobilization was found for As, but not for U. 相似文献
362.
Uranium removal from groundwater via in situ biostimulation: Field-scale modeling of transport and biological processes 总被引:1,自引:0,他引:1
Yabusaki SB Fang Y Long PE Resch CT Peacock AD Komlos J Jaffe PR Morrison SJ Dayvault RD White DC Anderson RT 《Journal of contaminant hydrology》2007,93(1-4):216-235
During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes. 相似文献
363.
364.
YAEL MANDELIK†‡ TAMAR DAYAN VLADIMIR CHIKATUNOV VASILIY KRAVCHENKO 《Conservation biology》2007,21(6):1506-1515
Abstract: A promising shortcut for quantifying species patterns is to use genera and families as surrogates of species. At large spatial scales, concurrence between patterns of richness, rarity, and composition of species and higher taxa is generally high. Only a few researchers, however, have examined this relationship at the local scale, which is frequently the relevant scale in land-use conflicts. We investigated the reliability of the higher-taxon approach in assessing patterns of species richness, rarity, and composition at the local scale. We studied diversity patterns of three commonly used surrogate taxa: vascular plants, ground-dwelling beetles, and moths. We conducted year-round field surveys for these taxa in the Jerusalem Mountains and the Judean foothills, Israel. Richness and composition of species were highly correlated with richness and composition of genera for all taxa. At the family level, correlations with richness and composition of species were much lower. Excluding monotypic genera and families did not affect these relations. Rarity representation based on higher taxa varied considerably depending on the taxon, and rarity scale and was weaker compared with richness and composition representation. Cumulative richness curves of species and genera showed similar patterns, leveling off at equivalent sampling efforts. Genus-level assessments were a reliable surrogate for local patterns of species richness, rarity, and composition, but family-level assessments performed poorly. The advantage of using coarse taxonomic scales in local diversity surveys is that it may decrease identification time and the need for experts, but it will not reduce sampling effort. 相似文献
365.
The small-rodent populations of five collective gardens have been studied. The example of one of the populations has been used to monitor the annual cycle of population size. The species composition and animal number depends on the biotope, climatic conditions, and the anthropogenic load. The ratios between species in the gardens and neighboring biotopes differ from each other, with different species being dominant. It is assumed that small mammals use garden plots as refugia. 相似文献
366.
367.
Laura Sokka Riina Antikainen Pekka E. Kauppi 《Resources, Conservation and Recycling》2007,50(4):475-488
Waste reduction was recognised as the main goal of waste management policy in the EU in the 1990s. Although knowledge of past waste generation is essential for effective waste reduction policy there are no comprehensive statistics on the past development of municipal solid waste (MSW) production. MSW management is currently under turmoil in many EU countries as the requirements of the EC landfill directive (1999/31/EC) are set into force. In this study, the production and composition of MSW in Finland between 1960 and 2002 is presented using historical data. The impact of population, affluence and technology on MSW production are analysed using the IPAT equation and three scenarios are constructed until year 2020. The results are compared with national future targets on MSW production. Production of MSW increased in Finland until 1990, declined to year 1997, increased to 2000 and then declined again. The share of organic and plastic waste increased over the study period while the share of paper and cardboard declined. The results suggest that so far national targets on MSW reduction have been set fairly low. Moreover, our scenarios depict a wide range of future MSW production, even though the time horizon is not longer than 15 years into the future. In order to narrow this range, continuous improvement of the statistics of MSW is essential. 相似文献
368.
Ghauch A Turnar C Fachinger C Rima J Charef A Suptil J Martin-Bouyer M 《Chemosphere》2000,40(12):1327-1333
Diffuse reflectance spectroscopy can be successfully used for the quantitative determination of small amounts of pollutants like metals. The remission function was found to be linearly proportional to the concentration, when we applied the Kubelka–Munk equation. The color reactions of Cu(II), Co(II), and Ni(II) with dithiooxamide, were realised on filter paper. Reaction between Fe(III) and ammonium thiocyanate was realized on filter paper and gelatine matrix. All measurements were accomplished with a laboratory-constructed reflectometer. We have obtained a calibration curve by plotting the optical density of reflectance AR vs log of the mol l−1 concentration. Limits of detection at the 10−4 M level were estimated for all the compounds. Linear dynamic range extend over one order of magnitude and shows the potential of device for the quantitative analysis of environmental pollutants. 相似文献
369.
Using a time-varying stochastic frontier model, this paper examines the technical efficiency of firms in the iron and steel industry to try to identify the factors contributing to the industry's efficiency growth. Industry observers and policymakers tend to cite most frequently three possible sources of efficiency growth: privatization; economies of scale; and vintage of equipment. Our study corroborates these factors. Based on our findings, which pertain to 52 iron and steel firms over the period of 1978–1997, privatization is likely to improve the efficiency of iron and steel firms to a great extent as evidenced in various industries. This study also provides systematic evidence that iron and steel production shows economies of scale. In addition, newer vintages of equipment are found to be closely correlated with higher levels of efficiency. This clearly indicates that investment in new plants and equipments is critical in pursuit of efficiency in the iron and steel industry. 相似文献
370.
Willem van Hees 《Journal of the American Water Resources Association》1977,13(2):215-230
ABSTRACT: A number of aspects of the discharging of non-oily wastewaters by transiting ships are treated in this overview paper. In the introduction, options to discharging (the use of holding tank, on board treatment) and the impact of changing regulations are discussed. Assessment of the effects of sewage discharges on coastal waters required that data, at first not available, be generated. An account is given of the characterization of Navy shipboard wastewaters and of experiments involving sewage discharges at sea, measurements of water quality before, during and after an amphibious operation, and fore and aft of transitting Navy ships. A better understanding of sewage dilution after discharge led to the verification of a method for controlled discharging of sewage (and other wastewaters). This method permits limiting the coliform bacteria count in the ship's wake to values below acceptable limits. The final sections contain information on long range effects of ships’sewage discharges, obtained in studies by the U.S. Navy and others, as well as public health considerations. 相似文献