全文获取类型
收费全文 | 444篇 |
免费 | 66篇 |
国内免费 | 127篇 |
专业分类
安全科学 | 74篇 |
废物处理 | 39篇 |
环保管理 | 42篇 |
综合类 | 314篇 |
基础理论 | 62篇 |
污染及防治 | 56篇 |
评价与监测 | 40篇 |
社会与环境 | 5篇 |
灾害及防治 | 5篇 |
出版年
2024年 | 2篇 |
2023年 | 6篇 |
2022年 | 12篇 |
2021年 | 19篇 |
2020年 | 10篇 |
2019年 | 10篇 |
2018年 | 11篇 |
2017年 | 18篇 |
2016年 | 22篇 |
2015年 | 23篇 |
2014年 | 31篇 |
2013年 | 32篇 |
2012年 | 39篇 |
2011年 | 54篇 |
2010年 | 32篇 |
2009年 | 36篇 |
2008年 | 22篇 |
2007年 | 32篇 |
2006年 | 29篇 |
2005年 | 20篇 |
2004年 | 27篇 |
2003年 | 19篇 |
2002年 | 21篇 |
2001年 | 17篇 |
2000年 | 22篇 |
1999年 | 15篇 |
1998年 | 13篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1986年 | 1篇 |
1977年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有637条查询结果,搜索用时 328 毫秒
411.
In this investigation, the adsorption measure of linezolid antibiotic onto MgO nanoparticles and ZnO–MgO nanocomposites were performed. The adsorbents were characterized by different techniques such as XRD, SEM, TEM and BET. The parameters influence such as the pH, adsorbent dosage and temperature was tested and evaluated by Box–Behnken Design combined with response surface methodology. Performing adsorption tests at optimal conditions set as 0.5 g L−1 of adsorbent, pH 10 and 308 K make admit to obtain high adsorption turnover (123.45 and 140.28 mg g−1 for MgO nanoparticles and ZnO–MgO nanocomposites, respectively). A good compromise between predicted and experimental data in this research was observed. The experimental equilibrium data fitting to Langmuir, Freundlich, Tempkin and Dubinin–Radushkevich models indicate that the Langmuir model is a best model for evaluation of adsorption behavior. Kinetic evaluation of experimental data indicated that the adsorption operations followed well pseudo-second-order models. The adsorption capacity of ZnO–MgO nanocomposites is higher than MgO nanoparticles that because of the ZnO–MgO nanocomposites have high specific surface area. 相似文献
412.
Novel Al-doped carbon nanotubes with adsorption and coagulation promotion for organic pollutant removal 总被引:1,自引:0,他引:1
Al-doped carbon nanotubes (Al-doped CNTs) were prepared as a multifunctional integrated material of adsorbent and coagulant aid for organic pollutant removal from aqueous solution. It was observed that aluminum species were dispersed homogeneously on the surface of CNTs, and mainly anchored onto defect structures of the CNTs. The introduction of aluminium efficiently improved adsorption ability for methyl orange (MO) onto the CNTs, and maximum adsorption capacity calculated from the Langmuir isotherm model can reach 69.7 mg/g. The MO adsorption kinetics can be better described by the pseudo-second-order and pore diffusion kinetic models, and the diffusion of MO anions into pores of the Al-doped CNT adsorbent should be the rate-determining step. Thermodynamic analyses indicated that the adsorption of MO onto Al-CNTs-2.0 was endothermic and spontaneous. Moreover, adsorption capacity for MO on the Al-doped CNTs was evidently dependent on the CNT dose, solution pH and adsorbent dose. From the perspective of low-cost and multifunctional, suspension obtained during the Al-doped CNT adsorbent preparation, was tested as coagulant to remove humic acid (HA). A significant observation is that the suspension exhibited an excellent coagulation performance for HA, because abundant aluminous polymer and Al-doped CNTs existed in the suspension. 相似文献
413.
目的为了减少制碱设备在碱液蒸发浓缩阶段发生的严重腐蚀。方法采用静浸泡、电化学稳态极化测试技术、光学显微镜和扫描电镜(SEM)观察,以及XRD,XPS腐蚀产物分析等试验方法,研究几种材料(26-1,30-2,18-8Ti和Ni)在高温高浓碱液中的腐蚀行为。结果在150℃、50%Na OH的碱液中,加入NaClO_3会使18-8Ti的耐蚀性提高,却使镍的耐蚀性降低。只有碱液中NaClO_3含量适量时(如0.15%NaClO_3),才能使26-1和30-2和耐蚀性提高,NaClO_3含量过多或过少,均使26-1和30-2耐蚀性降低。结论 Cl–的加入能够降低镍和18-8Ti和耐蚀性,而使30-2的耐蚀性提高,与18-8Ti相比,26-1和30-2的耐蚀性有着显著的提高。 相似文献
414.
通过对贵州省电解锰行业生产废水循环模式的调查,针对水质、水量特征进行改造:电解锰生产冷却循环水的强制排污水可降级作为电解产品和阴极板的冲洗水使用,处理后的含铬锰废水可作为制液氨水和电解清槽用水。进行以上优化后,电解锰生产废水闭路循环是可以实现的。 相似文献
415.
416.
含有害金属废水溶液的中和沉淀净化过程受诸多因素的影响,其中,最重要的有溶液中金属的价态和形态,溶液的离子强度,沉淀物的组成,结构和表面效应等,本文对上述问题作了较全面的理论分析。 相似文献
417.
本文根据酵母废液的水质特点,采用了常温升流式厌氧污泥床处理工艺,即温度在26.8-28.0℃,进水COD为7129-9823mg·l^-1时,达到CDO去除率66.0-71.0%,同时,沼气产率为2.4-3.0L·l^-1·d^-1,沼气中烷含量为61.5-69.1%。该法耗能小,沼气可回收,经济效果明显。 相似文献
418.
Many numerical computer codes used to simulate multi-species reactive transport and biodegradation have been developed in recent years. Such numerical codes must be validated by comparison of the numerical solutions with an analytical solution. In this paper, a method for deriving analytical solutions of the partial differential equations describing multiple species multi-dimensional transport with first-order sequential reactions is presented. Although others have developed specific solutions of multi-species transport equations, here a more general analytical approach, capable of describing any number of reactive species in multiple dimensions is derived. A substitution method is used to transform the multi-species reactive transport problem to one that can be solved using previously published single-species solutions for various initial and boundary conditions. One- and three-dimensional examples are presented to illustrate the steps involved in extending single-species solutions to a four-species system with sequential first-order reactions. 相似文献
419.
Gibbsite calcined at 400°C (GB400) was prepared, and its ability to adsorb rhodium(III) was investigated. Optimal pH, effect of contact time, temperature, adsorption isotherms, and recovery percentage were evaluated. The optimal pH was 6.3. The adsorption equilibrium was achieved within 24 h. The adsorption rate was found to be of pseudo-first order. The experimental data were fitted to both the Freundlich (r = 0.90–0.93) and Langmuir (r = 0.94–0.96) equations. The amount of rhodium(III) adsorbed decreased with increasing temperature. Rhodium(III) being adsorbed from phosphate or sulfate plating solution was recovered using hydrochloric acid and sodium hydroxide solutions at 1, 10, and 100 mmol L?1. 相似文献
420.