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51.
Báez AP Torres Mdel C García RM Padilla HG 《Environmental science and pollution research international》2002,9(4):230-233
A great number of studies on the ambient levels of formaldehyde and other carbonyls in the urban rural and maritime atmospheres have been published because of their chemical and toxicological characteristics, and adverse health effects. Due to their toxicological effects, it was considered necessary to measure these compounds at different sites in the metropolitan area of Mexico City, and to calculate the total rate of photolytic constants and the photolytic lifetime of formaldehyde and acetaldehyde. Four sites were chosen. Sampling was carried out at different seasons and atmospheric conditions. The results indicated that formaldehyde was the most abundant carbonyl, followed by acetone and acetaldehyde. Data sets obtained from the 4 sites were chosen to calculate the total rate of photolysis and the photolytic lifetime for formaldehyde and acetaldehyde. Maximum photolytic rate values were obtained at the maximum actinic fluxes, as was to be expected. 相似文献
52.
Anantharaman Chandrasekar C. Russell Philbrick Richard Clark Bruce Doddridge Panos Georgopoulos 《Environmental Fluid Mechanics》2003,3(4):305-329
This study presents a large-eddy simulation (LES) study of the convective boundary layer on August 1, 1999 over Philadelphia, PA during a summer ozone episode. The study is an evaluation of the Colorado State University's Regional Atmospheric Modeling System Version 4.3 (RAMS4.3) with the LES option using Northeast Oxidant and Particulate Study (NE-OPS) data. Simulations were performed with different imposed sensible heat fluxes at the ground surface. The model was initialized with the atmospheric sounding data collected at Philadelphia at 1230 UTC and model integrations continued till 2130 UTC. The resulting mean profiles of temperature and humidity obtained from the LES model were compared with atmospheric soundings, tethered balloon and aircraft data collected during the NE-OPS 1999 field campaign. Also the model-derived vertical profiles of virtual temperature were compared with NE-OPS Radio Acoustic Sounder System (RASS) data while the humidity profiles were compared with NE-OPS lidar data. The comparison of the radiosonde data with the LES model predictions suggests that the growth of the mixing layer is reasonably well simulated by the model. Overall, the agreement of temperature predictions of the LES model with the radiosonde observations is good. The model appears to underestimate humidity values for the case of higher imposed sensible heat flux. However, the humidity values in the mixing layer agree quite well with radiosonde observations for the case of lower imposed sensible heat flux. The model-predicted temperature and humidity profiles are in reasonable agreement with the tethered balloon data except for some small overestimation of temperature at lower layers and some underestimation of humidity values. However, the humidity profiles as simulated by the model agree quite well with the tethered balloon data for the case of lower imposed sensible heat flux. The model-predicted virtual temperature profile is also in better agreement with RASS data for the case of lower imposed sensible heat flux. The model-predicted temperature profile further agrees quite well with aircraft data for the case of lower imposed heat flux. However, the relative humidity values predicted by the model are lower compared with the aircraft data. The model-predicted humidity profiles are only in partial agreement with the lidar data. The results of this study suggest that the explicitly resolved energetic eddies seem to provide the correct forcing necessary to produce good agreement with observations for the case of an imposed sensible heat flux of 0.1 K m s–1 at the surface. 相似文献
53.
通过使用德国TriOS公司生产的RAMSES-ACC-UV/VIS光谱仪,在2016—2017年对西藏四个地区(拉萨、林芝、阿里和定日)进行了阶段性的太阳光谱(波长280—950 nm)实地观测。初步研究了西藏四个地区地面太阳光谱强度、光谱曲线特征以及光谱随时间的变化等,结果显示在本次观测期间,2017年7月21日(晴天)当地正午(北京时间13点58分)拉萨晴天光谱在476.6 nm波长处出现强度最高,峰值达到2.05 W?m~(-2)?nm~(-1)。同时对比了观测期间拉萨与定日、拉萨与林芝的当地正午晴天太阳光谱特征,对比结果表明:定日光谱强度高于拉萨,拉萨光谱强度高于林芝。定日光谱曲线平滑程度高于拉萨,拉萨光谱曲线平滑程度高于林芝,主要由水汽、氧气吸收造成。 相似文献
54.
55.
We previously demonstrated that Cyanobacteria-derived microcystin-LR (MCLR) is able to induce cognitive dysfunction, but the mechanism is not understood. Long-term potential (LTP) in hippocampus is regarded as an important cellular mechanism of learning and memory. Here, the aim of this study was to evaluate the role of MCLR in LTP of hippocampal dentate gyrus (DG) by in vivo electrophysiological recording. We found that MCLR could suppress the induction of LTP in rat hippocampus, whereas simultaneous inhibition of glycogen synthase kinase-3β (GSK-3β) by LiCl or SB216763 attenuated the LTP impairments by MCLR. Furthermore, a decrease of the phosphorylated level at Ser9 of GSK-3β was observed by western blotting after intracerebroventricular (ICV) injection of MCLR, indicating GSK-3β was activated by MCLR. In addition, we showed that ICV administration of MCLR slightly stimulated activity of protein phosphatases (PPs) in the brain, which might activate GSK-3β via dephosphorylation of Ser9 site. Taken together, these findings demonstrated that GSK-3β plays a crucial role in regulating MCLR-induced cognitive deficit. 相似文献
56.
The Seine River is a highly artificialised catchment in Europe, comprising both productive agricultural areas and intense industrial and commercial activity. Due to its strategic importance, monitoring programs in the river started as early as the 1970s. The present study compiles and analyses this valuable data set (1970–2014), thoroughly describing the riverine section downstream of Paris and the estuary. We identify long-term trends and shifting patterns in nutrients and oxygen, and pay special attention to the river’s evolution after the year 2000, when the European Water Framework Directive came into force. The study has a manifest management perspective, and the results are discussed on the basis of the environmental quality standards proposed in current environmental regulations. The data show that water quality has improved remarkably over the past two decades, with sharp reductions of ammonium and phosphate and a progressive increase of dissolved oxygen levels. The amelioration is prominent in the estuary, where summer anoxic episodes have nearly disappeared. As a result, these three parameters are nowadays in good or very good condition throughout the year. The successful abatement of point sources contrasts, however, with the low effectiveness of the measures provided for the control of nutrients from diffuse sources. Nitrate concentration has increased by 150% since the early 1980s, and only very recently has the upward trend been reversed. Bold agri-environmental management measures are required if we are to prevent chronic pollution problems and truly restore the good ecological status of rivers. 相似文献
57.
Junxia Li Zipeng Dong Yiyu Li Junmei Yang Xingang Liu Liang Yuan Yan Yin Zhanqing Li Peiren Li Gang Ren Lijun Jin Runjun Li 《环境科学学报(英文版)》2015,27(8):44-56
Vertical distributions of aerosol optical properties based on aircraft measurements over the Loess Plateau were measured for the first time during a summertime aircraft campaign, 2013 in Shanxi, China. Data from four flights were analyzed. The vertical distributions of aerosol optical properties including aerosol scattering coefficients (σsc), absorption coefficients (σab), Angström exponent (α), single scattering albedo (ω), backscattering ratio (βsc), aerosol mass scattering proficiency (Qsc) and aerosol surface scattering proficiency (Qsc′) were obtained. The mean statistical values of σsc were 77.45 Mm− 1 (at 450 nm), 50.72 Mm− 1 (at 550 nm), and 32.02 Mm− 1 (at 700 nm). The mean value of σab was 7.62 Mm− 1 (at 550 nm). The mean values of α, βsc and ω were 1.93, 0.15, and 0.91, respectively. Aerosol concentration decreased with altitude. Most effective diameters (ED) of aerosols were less than 0.8 μm. The vertical profiles of σsc,, α, βsc, Qsc and Qsc′ showed that the aerosol scattering properties at lower levels contributed the most to the total aerosol radiative forcing. Both α and βsc had relatively large values, suggesting that most aerosols in the observational region were small particles. The mean values of σsc, α, βsc, Qsc, Qsc′, σab and ω at different height ranges showed that most of the parameters decreased with altitude. The forty-eight hour backward trajectories of air masses during the observation days indicated that the majority of aerosols in the lower level contributed the most to the total aerosol loading, and most of these particles originated from local or regional pollution emissions. 相似文献
58.
Validation of Urban Emission Inventories 总被引:1,自引:0,他引:1
Clemens Mensink 《Environmental monitoring and assessment》2000,65(1-2):31-39
Two emission validation methods are presented. The first method focuses on the precision of the emission factors and the accuracy of modelled traffic flows. Emission factors derived from the COPERT II methodology are compared with on-board emission measurements and modelled traffic flow rates are compared with observations. The second validation method focuses on the completeness of the inventory, i.e. coverage of all sources. The method compares measured pollutant fluxes in the urban plume with the downwind transported and dispersed emissions integrated over plume width and mixing height. Both methods seem to indicate that traffic emission factors used in the urban emission inventories show large uncertainties. Besides the lack of measurement precision this is mainly induced by external influence factors like driving behaviour and vehicle maintenance. 相似文献
59.
Lee H. MacDonald 《Journal of the American Water Resources Association》1993,29(3):357-368
ABSTRACT: Recent assessments have emphasized the lack of a field and laboratory component in hydrologic education at the university level. Consequences of this lack include: (1) an unwarranted faith in published data; (2) lack of appreciation for the spatial and temporal variability of most hydrologic processes; (3) lack of appreciation for the difficulty of collecting good quality field data; (4) an inability to design and execute projects to collect field data; (5) a lack of field experience which can be applied when confronted with different problems or new environments; (6) an inability to evaluate published materials or models against “field reality;” (7) an excessive reliance on, and trust in, theoretical or conceptual models; and (8) reduced potential for lifelong learning through observation and analysis. Field courses need not be costly or difficult, but the instructor must be willing to adapt to the uncertainty and problems associated with field measurements. A recently updated course on watershed measurements at Colorado State University illustrates the type of field courses which can be developed if there is the necessary commitment and flexibility. The lack of a current text can be overcome by assembling selected portions of existing government documents, and a sample bibliography is included. 相似文献
60.
David O. Cook James W. Demenkow Priya J. Wickramaratne John T. Hannigan 《Journal of the American Water Resources Association》1978,14(2):440-453
ABSTRACT: The town of Jamestown, Rhode Island, located on Conanicut Island in Narragansett Bay, is constructing a secondary treatment plant in order to comply with NPDES regulations. Twelve candidate sites for the plant and marine outfall were initially proposed, and ability to meet State water quality standards at these sites was evaluated using an EPA buoyant plume model. A final outfall site, Taylor Point, was selected by the Town from among the sites considered acceptable. Taylor Point was then subjected to field hydrographic studies including drogue tracking, current recordings, and tracer dye surveys. Results of the measurement program served as input to a two-dimensional effluent dispersion model which predicted excess BOD, coliform, and suspended solids resulting from effluent discharge off Taylor Point. The model predictions demonstrated that State water quality standards can be maintained outside the initial discharge plume. 相似文献