Heterogeneous uptake of nitrogen dioxide on Chinese mineral dust

Mineral dust is one of the major aerosols in the atmosphere. To assess its impact on trace atmospheric gases, in this work we present a laboratory study of the effect of temperature on the heterogeneous reaction of NO₂ on the surface of ambient Chinese dust over the temperature range from 258 to 313 K. The results suggest that nitrogen dioxide could mainly be adsorbed on these types of Chinese mineral dust reversibly with little temperature dependence. Similar to a previous study on NO₂ uptake on mineral aerosols, the uptake coefficients are mainly on the order of 10^− 6 for the Chinese dust, when BET areas are taken into account. HONO was observed as a product, and its formation and decomposition on Chinese mineral dust during the uptake processes were also studied. The complete dataset from this study was compiled with previous literature determinations. Atmospheric implications of the heterogeneous reaction between NO₂ and mineral dust are also discussed, in an effort to understand this important heterogeneous process.     

Assessment of potential soybean cadmium excluder cultivars at different concentrations of Cd in soils

The selection of cadmium-excluding cultivars has been used to minimize the transfer of cadmium into the human food chain. In this experiment, five Chinese soybean plants were grown in three soils with different concentrations of Cd (0.15, 0.75 and 1.12 mg/kg). Variations in uptake, enrichment, and translocation of Cd among these soybean cultivars were studied. The results indicated that the concentration of Cd in seeds that grew at 1.12 mg/kg Cd in soils exceeded the permitted maximum levels in soybeans. Therefore, our results indicated that even some soybean cultivars grown on soils with permitted levels of Cd might accumulate higher concentrations of Cd in seeds that are hazardous to human health. The seeds of these five cultivars were further assessed for interactions between Cd and other mineral nutrient elements such as Ca, Cu, Fe, Mg, Mn and Zn. High Cd concentration in soil was found to inhibit the uptake of Mn. Furthermore, Fe and Zn accumulations were found to be enhanced in the seeds of all of the five soybean cultivars in response to high Cd concentration. Cultivar Tiefeng 31 was found to fit the criteria for a Cd-excluding cultivar under different concentrations of Cd in soils.     

Knudsen cell and smog chamber study of the heterogeneous uptake of sulfur dioxide on Chinese mineral dust

The heterogeneous uptake processes of sulfur dioxide on two types of Chinese mineral dust（Inner Mongolia desert dust and Xinjiang sierozem） were investigated using both Knudsen cell and smog chamber system. The temperature dependence of the uptake coefficients was studied over a range from 253 to 313 K using the Knudsen cell reactor, the initial uptake coefficients decreased with the increasing of temperature for these two mineral dust samples, whereas the steady state uptake coefficients of the Xinjiang sierozem increased with the temperature increasing, and these temperature dependence functions were obtained for the first time. In the smog chamber experiments at room temperature, the steady state uptake coefficients of SO2 decreased evidently with the increasing of sulfur dioxide initial concentration from 1.72 × 1012 to 6.15 × 1012mol/cm3. Humid air had effect on the steady state uptake coefficients of SO2 onto Inner Mongolia desert dust.Consequences about the understanding of the uptake processes onto mineral dust samples and the environmental implication were also discussed.     

The derivation of radionuclide transfer parameters for and dose-rates to an adult ringed seal (Phoca hispida) in an Arctic environment

Radionuclide transfer parameters and dose-rates for an adult ringed seal from Svalbard have been determined based on empirical and estimated tissue activity concentrations and detailed dietary and habitat information. Whole-body equivalent concentration factors determined for anthropogenic radionuclides ranged from 10(1) ((90)Sr) to 10(2) ((137)Cs, (238)Pu and (239,240)Pu), while natural radionuclides ranged from 10(2) ((210)Pb) to 10(4) ((210)Po). Employing a dietary composition of 40% fish, 40% zooplankton and 20% benthic invertebrates, a whole-body biological half-life of 29 days was derived for (137)Cs. A total dose-rate of approximately 0.19microGyh(-1) (1.7mGya(-1)) was derived for an adult ringed seal; this dose-rate is virtually entirely attributable to the internal components of (210)Po and (40)K. The dose-rates associated with the presence of anthropogenically derived radionuclides in the present assessment fall many orders of magnitude below the dose-rates at which any biological effects would be expected.     

Shortfalls in minerals investments

The international minerals industry continues to have a substantial investment shortfall. The widening exploration and mineral development gaps, not only in the lesser developed countries but also in the developed nations, are sowing the seeds for future mineral supply disruptions and conflicts. Mutuality of interests demands concerted initiatives, individual as well as collective, to reverse the investment trends established by international mineral finance and the multinational corporations in order to pave the way for secure mineral supplies in the future at acceptable prices.     

A Complex Systems Model Approach to Quantified Mineral Resource Appraisal

For federal and state land management agencies, mineral resource appraisal has evolved from value-based to outcome-based procedures wherein the consequences of resource development are compared with those of other management options. Complex systems modeling is proposed as a general framework in which to build models that can evaluate outcomes. Three frequently used methods of mineral resource appraisal (subjective probabilistic estimates, weights of evidence modeling, and fuzzy logic modeling) are discussed to obtain insight into methods of incorporating complexity into mineral resource appraisal models. Fuzzy logic and weights of evidence are most easily utilized in complex systems models. A fundamental product of new appraisals is the production of reusable, accessible databases and methodologies so that appraisals can easily be repeated with new or refined data. The data are representations of complex systems and must be so regarded if all of their information content is to be utilized.The proposed generalized model framework is applicable to mineral assessment and other geoscience problems. We begin with a (fuzzy) cognitive map using (+1,0,–1) values for the links and evaluate the map for various scenarios to obtain a ranking of the importance of various links. Fieldwork and modeling studies identify important links and help identify unanticipated links. Next, the links are given membership functions in accordance with the data. Finally, processes are associated with the links; ideally, the controlling physical and chemical events and equations are found for each link. After calibration and testing, this complex systems model is used for predictions under various scenarios. Published on line     

The resource curse

Countries that possess rich mineral deposits, it is widely assumed, are fortunate. Such deposits are assets, part of a country's natural capital. Mining is the key that converts dormant mineral wealth into schools, homes, ports, and other forms of capital that directly contribute to economic development. Over the past two decades, however, a more negative view of mining has emerged that questions the positive relationship between mineral extraction and economic development. The impetus for the alternative view came from empirical studies suggesting that countries where mining is important have not grown as rapidly as other countries. More recent studies have explored the possible reasons behind the disappointing performance of many mineral producing countries. While the central point of contention between the conventional and alternative views — namely, whether or not mining usually promotes economic development — remains unresolved, there is widespread agreement that rich mineral deposits provide developing countries with opportunities, which in some instances have been used wisely to promote development, and in other instances have been misused, hurting development. The consensus on this issue is important, for it means that one uniform policy toward all mining in the developing world is not desirable, despite the recent suggestions by some to the contrary. The appropriate public policy question is not should we or should we not promote mining in the developing countries, but rather where should we encourage it and how can we ensure that it contributes as much as possible to economic development and poverty alleviation.     

Japan's develop-for-import policy

Much of the world's remaining mineral resources lie within the underdeveloped nations of the Third World. The current crisis of confidence characterized in international investment and trade in extractive resources has become detrimental to both the resource-rich developing countries and the resource-hungry industrialized countries. Japan is one nation that has developed a strategy to foster mutual trust and to restore confidence in the international extractive industries. This paper examines Japan's develop-for-import policy, ‘kaihatsu yunso’, and its design, implementation and effects on securing foreign resources supplies.     

Respirometric Monitoring for the Determination of Effective Height and Reaction Rate Constant in Up-Flow Autotrophic Denitrification Reactor Packed with Sulfur

A novel technology for the removal of nitrogen from wastewater, autotrophic denitrification process with sulfur particle, has been developed. A respirometer was employed for the monitoring of nitrogen gas produced in the reactor. It was found that the autotrophic denitrification studied by gas production rate and nitrate depletion rate followed a first order reaction from the relationship. The reaction rate constant based on effective volume, k_N was ranged from 2.67 to 3.07 h^–1. The effective height was around 23.8 and 50% of the total height for 11.8 and 5.9 h of packed bed contact time, respectively. It was assumed that the reaction rate constants were similar in each experimental condition, PBCT = 11.9 and 5.9 h because there was little gradient of biomass concentration within 50% of the total height. The respirometry was found to be a simple and fast way to monitor the denitrification process. The method was especially useful for the determination of kinetic parameters.     

兰江流域水文动力参数变化与兰江防洪

本文根据钱塘江重要干流兰江的地面蓄水累计曲线SPER、流域入渗曲线Holton公式参数(入渗率f、稳定入渗率fc、入渗比例系数k)、Maskingum指数(流水河段传播时间k、楔蓄系数x)、水位与水量等近30年的抽样数据,分析了兰江流域河槽导流环境、植被条件、土地性质、气象因素的变化,指出了该河段近年来洪水频发的原因,提出了治理建议.