冶金企业无组织排放颗粒物影响评价

以上海市某冶金企业为例,该厂有正常运行的冶炼炉13座,每年向大气中排放大量颗粒污染物.基于高斯倾斜烟羽模式,整理了2003年上海市全年的气象资料,运用气象概率矩阵法计算了该厂直排点源及无组织面源排放颗粒物的影响,得出了厂区内无组织排放颗粒物落地浓度等值线图.计算结果表明,厂区内颗粒物污染主要来自无组织面源,污染集中在厂区中心的污染源附近;直排点源对环境的影响较小,污染主要集中在下风向.     

Characterizing the source/sink behavior of double-layer building materials

A model is developed to predict the rate of mass transfer between a double-layer material and indoor air. The model allows non-uniform initial material-phase concentrations in each of the two layers and a transient influent gas-phase concentration to be considered. This model builds on a recently validated single-layer model and should prove useful in predicting the behavior of double-layer material assemblies. Many indoor furnishings and building structures are comprised of layers of different material. The approach taken here represents a first step in the development of a more generally applicable multi-layer model. An analytical solution to the double-layer model is obtained and a parametric analysis is performed illustrating the behavior of the model as a function of the primary model parameters. The paper concludes by examining the potential use of thin diffusion barriers to reduce material emission rates and a hypothetical example of emissions from an adhesive that is part of an adhesive/material assembly.     

Large outdoor chamber experiments and computer simulations: (I) Secondary organic aerosol formation from the oxidation of a mixture of d-limonene and α-pinene

This work merges kinetic models for α-pinene and d-limonene which were individually developed to predict secondary organic aerosol (SOA) formation from these compounds. Three major changes in the d-limonene and α-pinene combined mechanism were made. First, radical–radical reactions were integrated so that radicals formed from both individual mechanisms all reacted with each other. Second, all SOA model species from both compounds were used to calculate semi-volatile partitioning for new semi-volatiles formed in the gas phase. Third particle phase reactions for particle phase α-pinene and d-limonene aldehydes, carboxylic acids, etc. were integrated. Experiments with mixtures of α-pinene and d-limonene, nitric oxide (NO), nitrogen dioxide (NO₂), and diurnal natural sunlight were carried out in a dual 270 m³ outdoor Teflon film chamber located in Pittsboro, NC. The model closely simulated the behavior and timing for α-pinene, d-limonene, NO, NO₂, O₃ and SOA. Model sensitivities were tested with respect to effects of d-limonene/α-pinene ratios, initial hydrocarbon to NO_x (HC₀/NO_x) ratios, temperature, and light intensity. The results showed that SOA yield (Y_SOA) was very sensitive to initial d-limonene/α-pinene ratio and temperature. The model was also used to simulate remote atmospheric SOA conditions that hypothetically could result from diurnal emissions of α-pinene, d-limonene and NO_x. We observed that the volatility of the simulated SOA material on the aging aerosol decreased with time, and this was consistent with chamber observations. Of additional importance was that our simulation did not show a loss of SOA during the daytime and this was consistent with observed measurements.     

不同性质天然水中铜在虹鳟(Oncorhynchus mykiss)鳃表的形态及对虹鳟的毒性

测定了在差异很大的4种水样(京密引水渠、北京地下水、长江南京段和汤旺河)中铜对虹鳟(Oncorhynchusmykiss)的半致死浓度,同步分析了各类水样参数和鳃铜蓄积量.用生物配位模型计算了铜在水相的形态分布和在鱼鳃表面的吸附量.研究了铜的水相形态、鳃表吸附量和鱼鳃蓄积量及毒性的关系.结果表明,铜的毒性与水相游离铜含量并无线性关系,但与鳃组织蓄积量成正比.图6参10     

天然河流的二维等效扩散模型

通过对天然河流流带的拉伸或压缩处理，使之成为处处流速和水深均相等的理想河流，在此基础上建立了等效二维扩散模型。文中对建模方法和参数计算方法作了详细的介绍。     

卡拉胶与明胶包埋黄孢原毛平革菌的方法研究

用卡拉胶和明胶包埋固定黄孢原毛平革菌,建立以模式染料为标记的降解反应体系,以研究各种条件和因素对包埋效果的影响。试验表明,在卡拉胶包埋体系中,胶的产品来源、胶的浓度、溶液中的离子、菌量和交联时间等,都会影响包埋颗粒的强度、传质性能、稳定性及降解效率。在明胶包埋体系中,开孔明胶包埋小块的制备方法值得推荐。     

中国能源消费与温室气体排放预测分析

构造了中国18个部门的能源—经济—环境投入产出模型,分析了能源消耗系数的变动规律,对2020年我国能源消费量与温室气体排放量进行了预测。结果表明:我国2020年的能源消费总量为29.5亿t(标准煤),等于1990年的299％,1995年的229％;煤炭消费最为26亿t,石油消费量为4.1亿t,天然气消费量为1420亿m~3,水电6400亿kW·h;能源消费弹性系数为0.43左右;CO_2排放量为17.50亿t(碳当量)。     

Radiative dryness index and potential productivity of vegetation in China

The Chikugo Model is used to estimate radiative dryness indexes (RDI) and net primary productivity (NPP) of vegetation zones in China by calculating cli-matic parameters. That provides the water-heat equilibrium condition, potential primary production for natural vegetation in various vegetation zones, and their geographical distribution pattern. That could be used as the basis for study the effect of global climate change on ecosystems.     

城市空气质量数值预报方法研究

城市空气质量数值预报,在时空分辨率和预报客观性方面具有明显优势,是未来城市空气质量预报的主要发展方向。以济南市为例,探索建立了一套较为成熟的城市空气质量数值预报方法。该方法采用高分辨率对流层化学模式系统为预报模式基础,同时根据济南市特点对模式系统进行修正,取得了较好的预报效果。此外,该模式系统由于能够较为准确地模拟城市范围内污染物的时空分布,在城市空气污染防治规划方面具有较为广泛的应用前景。     

不安全动作与不安全物态的判定方法探讨

根据事故致因"2-4"模型,人的不安全动作与物的不安全状态是事故发生的直接原因,但国内外学者关于二者的判定方法并未形成共识。为了寻找不安全动作与不安全物态科学的判定方法,首先,通过文献研究,综述了国内外学者对不安全动作、不安全物态的分类及定义;其次,从理论层面论述了不安全动作、不安全物态的判定方法;最后,以一起重大瓦斯爆炸事故为例对不安全动作及不安全物态的判定方法进行实证分析。结果表明,基于事故致因"2-4"模型的不安全动作和不安全物态判定方法有效。