立井井壁破坏应力研究

应用利用弹性理论、温度应力场理论、热胀冷缩原理 ,对立井井壁破坏应力进行了较为精确的受力分析 ,给出了立井井壁应力分布规律的解析式。在整个理论的分析过程中 ,笔者着重分析了井壁应力中负摩擦力的影响 ,对负摩擦力引起的井壁应力进行了较为细致的计算 ,并通过具体算例进行了说明。笔者研究的结果 ,为井壁设计的理论提供了新的依据 ,同时对煤矿设计及煤矿工程应用有重要实用价值。     

高效离子色谱法检测F- 、CH3 COO- 、HCOO- 、Cl - 的方法研究

在对离子色谱分析的研究过程中,建立了以0.12mmol/L Na2CO3和0.15mmol/L Na2HCO3为淋洗液,12.5mmol/L H2SO4为微膜抑制器的再生液,用HPIC－AS3串联HPIC－AG3的色谱系统,一次进样50mL可在8min内检测出μg/L级的F^-、CH3COO^-、HCOO^-、Cl^-,方法简便、经济快捷。经实验,甲酸、乙酸的检出限分别为2.56μg/L和17.4μg/L,F^-、Cl^-为1.87μg/L和8.82μg/L;方法精密度的相对标准差在0．4％－2．0％范围,样品加标回收率在97．7％－103．5％之间,完全能够满足降水样品和大气样品中F^-、Cl^-和低碳有机酸（甲酸、乙酸）的分析要求。在同一系统中只需要增加淋洗液浓度,采用一级梯度洗淋亦可完成对同一样品中其他阴离子（NO3^-、SO4^2-、PO4^3-）的检测。     

崇明风景旅游区负氧离子监测影响因素及分析

收集2012年崇明某湿地公园、某森林公园和某湖景公园等风景旅游区的负氧离子浓度监测数据,分析并总结了季节天气、监测点位、风向和空气中PM10等因素对负氧离子浓度监测的影响。     

Thermodynamics,economics and systems thinking: What role for air capture of CO2?

Air capture has recently been advanced by several parties as a solution to the problem of constraining – and ultimately reducing – atmospheric CO₂ in response to climate change. However, there are significant barriers pertaining to scale, energy needs and cost, which will hugely challenge the effectiveness and practicality of air capture. This paper examines the thermodynamics, energetics and economics and politics of air capture. These compare unfavourably with alternative approaches to atmospheric greenhouse gas reduction. An analysis is made of the energy cost of the one favoured DAC technology for which experimental results are available in the open literature – temperature/vacuum swing adsorption, and of one point source capture technology – oxyfiring of refinery FCCUs. We also examine the engineering effort required to implement atmospheric capture on a scale at which it could significantly reduce atmospheric levels of CO₂; and questions are addressed regarding its practicability and appropriateness. The analysis demonstrates that air capture remains at best a peripheral activity, at worst a distraction, until point sources of greenhouse gas emissions such as power stations, industrial flue gases, shale gas wellheads, anaerobic digestion plants and landfill sites have been completely decarbonised. When these and so many other unaddressed factors are affecting our global climate, the pursuit air capture, the ultimate “end-of-pipe” solution, is inappropriate.     

甲胺磷生产废水处理工艺研究

试验研究确认,甲胺磷生产废水中有机磷化合物在100℃±2℃,74.66±1.33kPa、pH值为1左右的条件下,能有效地被酸解成无机磷化合物。     

Image rotation method for identification of NPW signals in the localization of pipeline leakage

Gas and oil are mainly transported through long-distance pipelines on land. Pipeline leaks lead to severe hazards to the environment and economy and even imperil human lives. Negative pressure wave (NPW)-based methods are fast and effective for leak monitoring and localization. The key problem for an NPW-based method is to determine the NPW and its arrival time, which is characterized by the knee point in the time domain signal. In this paper, an image rotation method is proposed based on the shape characteristic of the time domain signal induced by an NPW. Through image rotation, the knee point turns into the highest point, which is easy to detect. To verify the performance of the proposed method, leakage experiments were conducted on liquid and gas pipeline models. Previously developed FBG pipe fixture sensors were used to detect an NPW. These sensors were equidistantly installed on the pipeline, forming a sensor array. Based on the sensing array, a novel leak localization algorithm was used to compute the leakage position. The experimental results indicated that the image rotation method has good performance for identifying an NPW, even though many noise- and pressure-induced fluctuations exist in the signals. This method enables automated real-time monitoring and has potential for practical application.     

加速溶剂萃取-气相色谱-负化学离子化质谱法测定土壤中有机磷农药

用加速溶剂萃取法(ASE)萃取土壤中的有机磷农药,用气相色谱-负化学离子化质谱法(GC-NCI-MS)进行测定,并与气相色谱-电子轰击电离质谱法(GC-EI-MS)进行了对比。结果表明,EI法和NCI法均能满足目前的有机磷农药的分析需要。GC-EI-MS的适用范围比较广,操作比较简单;GC-NCI-MS在选择性和灵敏度等方面均具有较强优势。     

利用废旧铅膏制备负极板的性能研究

源自铅酸电池回收的再生铅已成为世界铅产量的主要来源,铅酸电池生产也占据了世界铅消耗的80％以上,促进废旧铅膏的处理并直接用于电池的制作研究.采用“湿法脱硫-煅烧”的技术路线处理负极铅膏得到氧化铅.考察了回收铅粉的理化特性,并依据其固有特性,优化了负极板的和膏、固化、化成工艺.得到的样品电池展现出与传统球磨铅粉同样优异的性能.     

Numerical and experimental study on the generation and propagation of negative wave in high-pressure gas pipeline leakage

Negative-wave-based leakage detection and localization technology has been widely used in the pipeline system to diminish leak loss and enhance environmental protection from hazardous leak events. However, the fluid mechanics behind the negative wave method has yet been disclosed. The objective of this paper is to investigate the generation and propagation of negative wave in high-pressure pipeline leakage. A three-dimensional computational fluid dynamic (CFD) study on the negative wave was carried out with large eddy simulation (LES) method. Experimentally validated simulation presented the transient wave generation at the leak onset and the comprehensive wave evolution afterwards. Negative wave was proven to be a kind of rarefaction acoustic waves induced by transient mass loss at the onset of leakage. Diffusion due to the density difference at wave fronts drives the negative wave propagation. Propagation of negative wave can be categorized into three states – semi-spherical wave, wave superposition and plane wave, based on different wave forms. The wave characteristics at different states were elucidated and the attenuation effects were discussed respectively. Finally, a non-dimensional correlation was proposed to predict the negative wave amplitude based on pipeline pressure and leak diameter.     

Integrated-signal-based leak location method for liquid pipelines

Leaks in pipelines can cause major incidents resulting in both human injuries and financial losses. Among the considerable leak detection and location methods, the Negative Pressure Wave (NPW) based method has been widely used in locating leaks in liquid pipelines. The NPW based method only monitors the pressure changes at two ends of a pipeline. But the pressure is apt to be fixed by the end equipment and the change of it induced by a small or slow leakage is too small to be detected, which limit the application of the NPW based method in these situations. This paper presents a novel leak location method based on integrated signal, which is a combination of the pressure and flow rate signals. The representation of the integrated signal is derived from the transient analysis of the leakage. For the change of the integrated signal induced by a leakage is larger than the pressure change and it is also unaffected by the end equipment, the proposed method can be used to detect and locate small or slow leakage in a pipeline and can also be used in pipelines which end pressures are fixed by some kinds of equipment. The validation of the proposed method also confirms its advantages.